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91.
J.C. Selover Marianne Marsi David W. Parker J.A. Gladysz 《Journal of organometallic chemistry》1981,206(3):317-329
A series of kinetically unstable mononuclear anionic formyl complexes have been prepared by the action of Li(C2H5)3BH on neutral metal carbonyl precursors. One of these, Li+[(CO)4Mn(COC6H5)(CHO)]?, is shown to decompose by a hydride transfer disproportionation mechanism involving the by-product (C2H5)3B. 相似文献
92.
Techniques have been developed which permit the direct analysis of optical purity in α-deuterated amines and carboxylic acids. 相似文献
93.
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95.
J.L. Osborne C.A. Barnes R.W. Kavanagh R.M. Kremer G.J. Mathews J.L. Zyskind P.D. Parker A.J. Howard 《Nuclear Physics A》1984,419(1):115-132
Cross sections for the 3He(α, γ)7Be reaction have been measured at several energies from Ec.m. = 165 to 1169 keV by counting prompt γ-rays from a windowless, differentially pumped, recirculating, 3He gas target. The cross-section factor S34(Ec.m.) and branching ratio γ1/γ0 were determined at each energy. Cross sections were also measured at Ec.m. = 947 and 1255 keV by counting the γ-rays from the 7Be produced in a 3He gas cell with a Ni entrance foil. Combining the results of these two independent experiments yields a zero-energy intercept for the cross-section factor of S34(0) = 0.53 ± 0.03 keV · b. The relationship between these measurements and several theoretical calculations, and the import of the extrapolated cross section for the solar-neutrino problem are discussed. 相似文献
96.
The analysis of the interaction of threose 4-phosphate and 2-deoxyerythrose 4-phosphate with 3-deoxy-D-arabino-heptulosonate 7-phosphate synthase (DAH7PS) reveals previously unrecognised mechanistic differences between the DAH7PS-catalysed reaction and that catalysed by the closely related enzyme, 3-deoxy-D-manno-octulosonate 8-phosphate synthase (KDO8PS). 相似文献
97.
98.
Parker KJ Taylor LS Gracewski S Rubens DJ 《The Journal of the Acoustical Society of America》2005,117(5):2705-2712
A number of different approaches have been developed to estimate and image the elastic properties of tissue. The biomechanical properties of tissues are vitally linked to function and pathology, but cannot be directly assessed by conventional ultrasound, MRI, CT, or nuclear imaging. Research developments have introduced new approaches, using either MRI or ultrasound to image the tissue response to some stimulus. A wide range of stimuli has been evaluated, including heat, water jets, vibration shear waves, compression, and quasistatic compression, using single or multiple steps or low-frequency (<10 Hz) cyclic excitation. These may seem to be greatly dissimilar, and appear to produce distinctly different types of information and images. However, our purpose in this tutorial is to review the major classes of excitation stimuli, and then to demonstrate that they produce responses that fall within a common spectrum of elastic behavior. Within this spectrum, the major classes of excitation include step compression, cyclic quasistatic compression, harmonic shear wave excitation, and transient shear wave excitation. The information they reveal about the unknown elastic distribution within an imaging region of interest are shown to be fundamentally related because the tissue responses are governed by the same equation. Examples use simple geometry to emphasize the common nature of the approaches. 相似文献
99.
Fincke JR Lanier NE Batha SH Hueckstaedt RM Magelssen GR Rothman SD Parker KW Horsfield CJ 《Physical review letters》2004,93(11):115003
Strongly shocked cylindrically convergent implosions were conducted on the OMEGA laser. The directly driven targets consist of a low-density foam core and an embedded aluminum shell covered by an epoxy ablator. The outer surface of the aluminum shell has imposed single-mode perturbations with wave numbers k=0.08, 0.25, and 0.7 (rad/microm) and initial amplitudes eta(0)/lambda=0.013, 0.04 and 0.11. The perturbation growth rate is found to scale with k and, in our convergent geometry, no evidence of saturation for eta/lambda as large as 5 is observed. 相似文献
100.
Fernandez Ocaña M Neubert H Przyborowska A Parker R Bramley P Halket J Patel R 《The Analyst》2004,129(2):111-115
The epidemic of bovine spongiform encephalopathy (BSE) is thought to have resulted from feeding scrapie-infected sheep to cattle. This has led to a ban of feeding animals with "processed animal protein"(PAP). We report a novel approach for the mass spectrometric detection of PAP contamination in animal feedstuffs by detecting gelatine, a derivative of the major animal protein collagen. A method was developed to hydrolyse gelatine standards with hydrochloric acid, followed by detection of the derived hydrolytic peptides at m/z 828, 915, 957 and 1044 by matrix-assisted laser desorption/ionisation time-of-flight mass spectrometry (MALDI-TOF MS) and liquid chromatography electrospray ionisation mass spectrometry (LC-ESI-MS-MS). The marker peptides can be detected at concentrations of 100 ng ml(-1) gelatine in water with MALDI. The procedure was adapted to obtain a suitable peptide map of gelatine extracted from spiked feed. The ratio of signal area of the gelatine-derived peptide at m/z 1044 to the internal standard at m/z 556 is shown to relate to the total amount of gelatine present in the sample. 相似文献