全文获取类型
收费全文 | 12301篇 |
免费 | 1049篇 |
国内免费 | 1084篇 |
专业分类
化学 | 8414篇 |
晶体学 | 180篇 |
力学 | 484篇 |
综合类 | 261篇 |
数学 | 1253篇 |
物理学 | 3842篇 |
出版年
2024年 | 11篇 |
2023年 | 74篇 |
2022年 | 254篇 |
2021年 | 347篇 |
2020年 | 268篇 |
2019年 | 269篇 |
2018年 | 253篇 |
2017年 | 300篇 |
2016年 | 383篇 |
2015年 | 408篇 |
2014年 | 532篇 |
2013年 | 825篇 |
2012年 | 972篇 |
2011年 | 1074篇 |
2010年 | 715篇 |
2009年 | 654篇 |
2008年 | 928篇 |
2007年 | 842篇 |
2006年 | 769篇 |
2005年 | 707篇 |
2004年 | 590篇 |
2003年 | 461篇 |
2002年 | 486篇 |
2001年 | 381篇 |
2000年 | 341篇 |
1999年 | 239篇 |
1998年 | 113篇 |
1997年 | 121篇 |
1996年 | 134篇 |
1995年 | 107篇 |
1994年 | 107篇 |
1993年 | 96篇 |
1992年 | 87篇 |
1991年 | 76篇 |
1990年 | 68篇 |
1989年 | 56篇 |
1988年 | 45篇 |
1987年 | 33篇 |
1986年 | 19篇 |
1985年 | 43篇 |
1984年 | 26篇 |
1983年 | 23篇 |
1982年 | 26篇 |
1981年 | 19篇 |
1980年 | 22篇 |
1979年 | 23篇 |
1978年 | 16篇 |
1977年 | 10篇 |
1976年 | 13篇 |
1975年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
61.
62.
用HFR方法对CaⅨ-KrⅩⅩⅤ离子3s2,3s3p,3s3d,3p2组态能级结构进行了理论计算.在已有实验研究的基础上,通过分析离子能级沿等电子序列的变化规律,运用最小二乘拟合方法预言计算了GeⅩⅪ-SeⅩⅩⅢ离子3s2,3s3p,3s3d,3p2组态14条精细结构能级值.在此基础上,进一步计算了GeⅩⅪ-SeⅩⅩⅢ离子3s2-3s3p,3s3p-3s3d和3s3p-3p2跃迁的23条谱线波长和相应的振子强度.计算结果与已有的实验值十分吻合,波长的最大不确定度为0.008 nm. 相似文献
63.
Kyung Hwa Hong Jong Lyoul Park In Hwan Sul Ji Ho Youk Tae Jin Kang 《Journal of Polymer Science.Polymer Physics》2006,44(17):2468-2474
Polyvinyl alcohol (PVA) nanofibers containing Ag nanoparticles were prepared by electrospinning PVA/silver nitrate (AgNO3) aqueous solutions, followed by short heat treatment, and their antimicrobial activity was investigated for wound dressing applications. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for the preparation of wound dressing nanofibers. After heat treatment at 155 °C for 3 min, the PVA/AgNO3 nanofibers became insoluble, while the Ag+ ions therein were reduced so as to produce a large number of Ag nanoparticles situated preferentially on their surface. The residual Ag+ ions were reduced by subsequent UV irradiation for 3 h. The average diameter of the Ag nanoparticles after the heat treatment was 5.9 nm and this value increased slightly to 6.3 nm after UV irradiation. It was found that most of the Ag+ ions were reduced by the simple heat treatment. The PVA nanofibers containing Ag nanoparticles showed very strong antimicrobial activity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2468–2474, 2006 相似文献
64.
S. Park T. U. Kampen T. Kachel P. Bressler W. Braun D. R. T. Zahn 《Applied Surface Science》2002,190(1-4):376-381
The interaction of Ag and In with a thin film of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) was studied by near-edge X-ray absorption fine structure (NEXAFS). Upon Ag deposition on a PTCDA film of 20 nm thickness the relative intensities and lineshapes, as well as the angular dependence of the spectra remains unchanged, illustrating the formation of a chemically unreactive Ag/PTCDA interface. On the other hand, the adsorption of 0.3 nm In strongly decreases the intensity of the π* resonances in C and O K-edge NEXAFS spectra. This is attributed to a strong charge transfer between In and PTCDA, leading to a redistribution of the charge in the molecule. However, the absence of a strong shift or new features and negligible dependence of peak intensities corresponding to π* resonances on the In thickness indicate that the interaction between In and PTCDA is not accompanied by a covalent bond formation. 相似文献
65.
在40—700cm-1波数和4.2—300K温度范围内研究了不同组份液相外延n型CaAs1-xPx样品的红外反射谱。对反射谱进行了赝谐振子拟合与K-K关系计算。从而获得了有关描述CaAs1-xPx样品的光学声子模、等离子体激元、LO声子-等离子体激元耦合模的重要物理参量及红外光学常数信息。基于这些计算结果,提出了双导带谷并计及与X能谷相联系的施主能级模型,用它解释等离子体激元频率和实验观察的三支主要的耦合模的温度变化规律。
关键词: 相似文献
66.
在“阳”加速器上进行了直径分别为10, 15, 20 μm, 交叉角为32°,45°,60°的钼(Mo)丝X-pinch实验。“阳”加速器产生的电流峰值约520 kA,上升时间80 ns。实验中通过X射线功率谱仪和纳秒分幅相机等仪器对Mo丝X-pinch辐射特性进行了诊断。实验表明:Mo丝X-pinch过程中会出现多次X射线爆发,箍缩过程中产生的热点辐射出能量超过3 keV的X射线,探测到的最小热点直径小于30 μm。 相似文献
67.
激光穿透焊的三维数值模拟 总被引:1,自引:0,他引:1
本文对激光穿透焊进行了三维数值模拟,除考虑焊接速度影响外,还研究了Marangoni对流对熔池流动与传热的影响。将三维数值模拟结果与相应的二维模拟结果进行了比较,结果表明,Marangoni对流对熔池的形成有很大的影响,因此不可忽略。本文还给出了估计激光穿透焊中蒸气孔尺寸与焊接热效率的方法。 相似文献
68.
In this paper, the nonfragile control problem for synchronization of a class of chaotic dynamical systems with controller gain variations is studied. Using the Lyapunov method and LMI (linear matrix inequality) technique, a criterion for the existence of the nonfragile controller for synchronization is derived in terms of LMI. To show the effectiveness of the proposed method, the control problem is applied to Genesio chaotic system. 相似文献
69.
D. P. Kozlenko S. E. Kichanov S. Lee J. -G. Park V. P. Glazkov B. N. Savenko 《JETP Letters》2006,83(8):346-350
The effect of a high pressure (up to 6 GPa) on the crystal and magnetic structure of the hexagonal manganite LuMnO3 is studied by neutron diffraction in the temperature range 10–295 K. It is found that, as the pressure increases, the ordered magnetic moment of Mn ions at T = 10 K decreases noticeably from 2.48 (0 GPa) to 1.98 μB (6 GPa). This decrease is due to an enhancement of the geometrical frustration effects on the triangular lattice. At the same time, the symmetry of the triangular antiferromagnetic state (the irreducible representation Γ2) remains unchanged. A correlation is revealed between the distortion parameter of the triangular lattice formed by Mn ions and the symmetry of the antiferromagnetic state of hexagonal manganites RMnO3. Based on this correlation, a generalized magnetic phase diagram of these compounds is constructed. The obtained phase diagram provides an explanation for the changes observed in the magnetic state of hexagonal manganites caused by high pressure and chemical substitution. 相似文献
70.
影响海洋微藻生产麻痹性贝类毒素的重要生态因素 总被引:1,自引:0,他引:1
麻痹性贝类毒素是有害赤潮海洋微藻生产的重要毒素种类,本文综述了影响该类毒素的主要生态因素有光,温度,盐度和营养盐4类;弱光对毒素合成有抑制作用。低温下PSP毒素产量高,通过对营养盐吸收机制的离子效应,盐度可影响毒素的生命合成,不同种类和株系对N、P限制的反应有极大差异。 相似文献