Optical and acoustic study of nucleation and growth of bubbles at a liquid-solid interface induced by nanosecond-pulsed-laser heating

The dynamics of liquid-vapor phase-change in the nanosecond time-scale induced by pulsed-laser heating of a liquid on a solid sample is studied by means of optical reflectance and scattering measurements, and the piezoelectric detection technique. The liquids studied include water, ethanol, methanol, IsoproPropyl Alcohol (IPA), and mixtures of water and IPA. The threshold fluence for nucleation is determined with high accuracy using the optical and acoustic signals. Heat diffusion calculations performed for the threshold fluences indicate that the liquids are sufficiently superheated before nucleation sets on. The transient optical reflectance signal is analyzed by an effective-medium theory to provide bubble-growth kinetics, so that the bubble-growth velocity for the test liquids could be estimated. In addition, it is observed that, following the thermally induced nucleation, repetitive acoustic cavitation at the surface of the solid sample occurs, with a time interval related to the speed of sound in the liquid.     

A model for the plane to plane variations in catalytic activity seen during nitric oxide decomposition on platinum

Previous work has shown that the reactivity of platinum for nitric oxide decomposition varies significantly with the geometry of the exposed surface of the platinum. Here, the available data are compared to the predictions of a model, which is based on conservation of orbital symmetry and a simplified picture of the band structure of the surface. The model predicts that the (100) face of platinum should be more active than either the (111) or the (110). The (410) should be more active still. These predictions agree with recent experiment. The model makes several other predictions which need to be tested experimentally. These results suggest that symmetry conservation methods, similar to the ones developed by Woodward and Hoffmann for organic reactions, could yield many valuable insights into the relative activity of various catalyst structures.     

The M/G/1 retrial queue with bernoulli schedule

We consider anM/G/1 retrial queue with infinite waiting space in which arriving customers who find the server busy join either (a) the retrial group with probabilityp in order to seek service again after a random amount of time, or (b) the infinite waiting space with probabilityq(=1–p) where they wait to be served. The joint generating function of the numbers of customers in the two groups is derived by using the supplementary variable method. It is shown that our results are consistent with known results whenp=0 orp=1.     

A central limit theorem for generalized multilinear forms

Let X₁, …, X_n be independent random variables and define for each finite subset I {1, …, n} the σ-algebra = σ{X_i : i ε I}. In this paper -measurable random variables W_I are considered, subject to the centering condition E(W_I ) = 0 a.s. unless I J. A central limit theorem is proven for d-homogeneous sums W(n) = Σ_{I = d}W_I, with var W(n) = 1, where the summation extends over all (_n^d) subsets I {1, …, n} of size I = d, under the condition that the normed fourth moment of W(n) tends to 3. Under some extra conditions the condition is also necessary.