Solid phase extraction of chromium(VI) from aqueous solutions by adsorption of its diphenylcarbazide complex on a mixed bed adsorbent (acid activated montmorillonite-silica gel) column

A novel approach has been developed for the solid phase extraction of chromium(VI) based on the adsorption of its diphenylcarbazide complex on a mixture of acid activated montmorillonite (AAM)-silica gel column. The effect of various parameters such as acidity, stability of the column, sample volume, interfering ions, etc., were studied in detail. The adsorbed complex could be easily eluted using polyethylene glycol-sulfuric acid mixture and the concentration of chromium has been determined using visible spectrophotometry. The calibration graph was linear in the range 0-1microgmL(-1) chromium(VI) with a detection limit of 6microgL(-1). A highest preconcentration factor of 25 could be obtained for 250mL sample volume using glass wool as support for the mixed bed adsorbent. Chromium(VI) could be effectively separated from other ions such as nickel, copper, zinc, chloride, sulfate, nitrate, etc., and the method has been successfully applied to study the recovery of chromium in electroplating waste water and spiked water samples.     

Ruthenium(III) catalyzed oxidation of paracetamol by chloramine-T in aqueous alkaline medium – A kinetic and mechanistic pathway

The kinetic study of ruthenium(III) chloride catalyzed oxidation of paracetamol by N-chloro-p-toluene sulfonamide (chloramine-T) in the alkaline medium has been performed. The reaction exhibits second order nature and the effect of the catalyst indicates the occurrence of uncatalyzed reaction simultaneously. Rate is decelerated by hydroxide ions. A plausible reaction mechanism has been suggested and the rate law is derived to account for such experiential observations. The activation parameters have been calculated. No evidence of the participation of free radicals is observed.