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181.
182.
Alain Tressaud Jean Louis Soubeyroux Jean Michel Dance René Sabatier Paul Hagenmuller Barbara M. Wanklyn 《Solid State Communications》1981,37(6):479-484
The nature of the magnetic interactions in the chain compound Rb2FeF5 has been investigated using neutron diffraction and magnetic measurements under high applied fields. Rb2FeF5 orders antiferromagnetically at TN = 8.0 ± 0.5 K; the magnetic structure is of the AZ + GX mode and the moment of the Fe3+ ion extrapoled to 0K is 3.5 ± 0.2 μB, this low value being due to zero-point spin reduction. Within a chain the Fe3+ ions are antiferromagnetically coupled with an exchange constant of J/k = ?8.8 K. A spin-flop behavior has been observed and interpreted on the basis of the molecular field theory. The critical field was found to be HC = 65 kOe at 1.7 K. 相似文献
183.
André Lichnerowicz 《Letters in Mathematical Physics》1979,3(6):495-502
The twisted products play an important role in Quantum Mechanics [1, 2]. We introduce here a distinction between Vey *ν-products and strong Vey *ν-products and prove that each *ν-product is equivalent to a Vey *ν-product. If b
3(W)=0, the symplectic manifold (W, F) admits strong Vey *ν-products. If b
2(W)=0, all *ν-products are equivalent as well as the Vey Lie algebras. In the general case, we characterize the formal Lie algebras which
are generated by a *ν-product and we prove that the existence of a *ν-product is equivalent to the existence of a formal Lie algebra infinitesimally equivalent to a Vey Lie algebra at the first
order. 相似文献
184.
Let Ω be a vector space over a finite field with q elements. Let G denote the general linear group of automorphisms of Ω and let us consider the left regular representation
associated with the natural action of G on the set X of linear subspaces of Ω. In this paper we study a natural basis B of the algebra EndG(L
2(X)) of intertwining maps on L
2(X). By using a Laplacian operator on Grassmann graphs, we identify the kernels in B as solutions of a basic hypergeometric difference equation. This provides two expressions for these kernels. One in terms
of the q-Hahn polynomials and the other by means of a Rodrigues type formula. Finally, we obtain a useful product formula for the
mappings in B. We give two different proofs. One uses the theory of classical hypergeometric polynomials and the other is supported by
a characterization of spherical functions in finite symmetric spaces. Both proofs require the use of certain associated Radon
transforms. 相似文献
185.
José G. Llavona 《Mediterranean Journal of Mathematics》2006,3(2):259-271
This paper is a survey of approximation results and methods by smooth functions in Banach spaces. The topics considered in
the paper are the following: approximation by polynomials by Ck-functions using the method of smooth partitions of unity, approximation by the fine topology, analytic approximation and
regularization in Banach spaces using the infimal convolution method. 相似文献
186.
René Michel 《Extremes》2007,10(3):83-107
The investigation of multivariate generalized Pareto distributions (GPDs) has begun only recently. For further progress with
these distributions simulation methods are an important part. We describe several methods of simulating GPDs, beginning with
an efficient method for the logistic GPD. The algorithm is based on the Shi transformation, which was already used for the
simulation of multivariate extreme value distributions (EVDs) of logistic type. In the sequel another algorithm is presented
simulating a broader class of GPDs. Due to its numerical complexity it is only practicably applicable in low dimensions. A
method is given to generate unconditional GPD random vectors from conditionally GPD distributed random vectors. A short application
of the simulation methods in the analysis of a real hydrological data set concludes the article. The simulation algorithms
are available on the author’s home page .
相似文献
187.
Jihad René Albani 《Journal of fluorescence》2009,19(6):1061-1071
We measured fluorescence lifetimes of L-Tryptophan dissolved in de-ionized water and in ethanol in the absence and the presence
of high progesterone concentrations. The hormone absorbs between 220 and 280 with a peak around 250 nm, while its absorption
is equal to zero beyond 280 nm. Tryptophan excitation spectrum recorded in presence of progesterone shows that the So → 1La transition is completely abolished while the So
→
1Lb transition is not affected. Emission of L-tryptophan in water occurs with two fluorescence lifetimes, 0.40 and 2.8 ns. In
ethanol, three fluorescence lifetimes equal to around 0.2, 1.8 and 4.8 ns were observed. Addition of progesterone to the medium
does not affect any of the fluorescence lifetimes indicating clearly that both transitions could induce tryptophan excitation
and that recorded fluorescence lifetimes could be assigned to sub-structures generated in the excited state. 相似文献
188.
Background
Marlin-1 is a microtubule binding protein that associates specifically with the GABAB1 subunit in neurons and with members of the Janus kinase family in lymphoid cells. In addition, it binds the molecular motor kinesin-I and nucleic acids, preferentially single stranded RNA. Marlin-1 is expressed mainly in the central nervous system but little is known regarding its cellular and subcellular distribution in the brain. 相似文献189.
Gaspar Ana B. Ksenofontov Vadim Spiering Hartmut Reiman Sergey Real José A. Gütlich Philipp 《Hyperfine Interactions》2002,144(1-4):297-306
This article reports on the study of the interplay between magnetic coupling and spin transition in 2,2′-bipyrimidine (bpym)-bridged
iron(II) dinuclear compounds. Coexistence of both phenomena has been observed in [Fe(bpym)(NCS)2]2bpym, [Fe(bpym)(NCSe)2]2bpym and [Fe(bt)(NCS)2]2bpym (bpym = 2,2′-bipyrimidine, bt = 2,2′-bithiazoline) by the action of external physical factors namely pressure or electromagnetic
radiation. Competition between magnetic exchange and spin crossover has been studied in [Fe(bpym)(NCS)2]2bpym at 6.3 kbar. LIESST experiments carried out in [Fe(bpym)(NCSe)2]2bpym and [Fe(bt)(NCS)2]2bpym at 4.2 K have shown that is possible to achieve dinuclear molecules with different spin states in this class of compounds.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
190.
Heise H Sakellariou D Meriles CA Moulé A Pines A 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2002,156(1):146-151
In a recent publication we presented a method to obtain highly resolved NMR spectra in the presence of an inhomogeneous B(0) field with the help of a matched RF gradient. If RF gradient pulses are combined with "ideal" 90 degrees pulses to form inhomogeneous z rotation pulses, the line broadening caused by the B(0) gradient can be refocused, while the full chemical shift information is maintained. This approach is of potential use for NMR spectroscopy in an inhomogeneous magnetic field produced by an "ex-situ" surface spectrometer. In this contribution, we extend this method toward two-dimensional spectroscopy with high resolution in one or both dimensions. Line narrowing in the indirect dimension can be achieved by two types of nutation echoes, thus leading to depth-sensitive NMR spectra with full chemical shift information. If the nutation echo in the indirect dimension is combined with a stroboscopic acquisition using inhomogeneous z-rotation pulses, highly resolved two-dimensional correlation spectra can be obtained in matched field gradients. Finally, we demonstrate that an INEPT coherence transfer from proton to carbon spins is possible in inhomogeneous B(0) fields. Thus, it is possible to obtain one-dimensional (13)C NMR spectra with increased sensitivity and two-dimensional HETCOR spectra in the presence of B(0) gradients of 0.4 mT/cm. These schemes may be of some value for ex-situ NMR analysis of materials and biological systems. 相似文献