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51.
Polytypism in GaAs nanowires: determination of the interplanar spacing of wurtzite GaAs by X‐ray diffraction
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Martin Köhl Philipp Schroth Andrey A. Minkevich Jean‐Wolfgang Hornung Emmanouil Dimakis Claudio Somaschini Lutz Geelhaar Timo Aschenbrenner Sergey Lazarev Daniil Grigoriev Ullrich Pietsch Tilo Baumbach 《Journal of synchrotron radiation》2015,22(1):67-75
In GaAs nanowires grown along the cubic [111]c direction, zinc blende and wurtzite arrangements have been observed in their stacking sequence, since the energetic barriers for nucleation are typically of similar order of magnitude. It is known that the interplanar spacing of the (111)c Ga (or As) planes in the zinc blende polytype varies slightly from the wurtzite polytype. However, different values have been reported in the literature. Here, the ratio of the interplanar spacing of these polytypes is extracted based on X‐ray diffraction measurements for thin GaAs nanowires with a mean diameter of 18–25 nm. The measurements are performed with a nano‐focused beam which facilitates the separation of the scattering of nanowires and of parasitic growth. The interplanar spacing of the (111)c Ga (or As) planes in the wurtzite arrangement in GaAs nanowires is observed to be 0.66% ± 0.02% larger than in the zinc blende arrangement. 相似文献
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Spiros Mouzakitis George Karamolegkos Emmanouil Ntanos John Psarras 《Journal of Optimization Theory and Applications》2013,158(1):274-283
In this paper, a multi-criteria method is presented for the evaluation and ranking of a selected set of companies as investment opportunities in aid of the relevant decision-analysis process of business angels. The multi-criteria methodology is based on the PROMETHEE method, which is further extended to deal with fuzzy input data in order to address the data imprecision and uncertainty of the decision process. The paper concludes by suggesting a web-based system implementation of the proposed methodology, which will significantly enhance modern business angels networks. 相似文献
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Spiros Kostopoulos Konstantinos Sidiropoulos Dimitris Glotsos Emmanouil Athanasiadis Konstantina Boutsikou Eleftherios Lavdas Georgia Oikonomou Ioannis V. Fezoulidis Marianna Vlychou Michael Hantes Dionisis Cavouras 《Magnetic resonance imaging》2013
The aim was to design a pattern-recognition (PR) system for discriminating between normal and pathological knee articular cartilage of the medial femoral (MFC) and tibial condyles (MTC). The data set comprised segmented regions of interest (ROIs) from coronal and sagittal 3-T magnetic resonance images of the MFC and MTC cartilage of young patients, 28 with abnormality-free knee and 16 with pathological findings. The PR system was designed employing the probabilistic neural network classifier, textural features from the segmented ROIs and the leave-one-out evaluation method, while the PR system's precision to “unseen” data was assessed by employing the external cross-validation method. Optimal system design was accomplished on a consumer graphics processing unit (GPU) using Compute Unified Device Architecture parallel programming. PR system design on the GPU required about 3.5 min against 15 h on a CPU-based system. Highest classification accuracies for the MFC and MTC cartilages were 93.2% and 95.5%, and accuracies to “unseen” data were 89% and 86%, respectively. The proposed PR system is housed in a PC, equipped with a consumer GPU, and it may be easily retrained when new verified data are incorporated in its repository and may be of value as a second-opinion tool in a clinical environment. 相似文献
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Emmanouil Milakis 《偏微分方程通讯》2013,38(8):1227-1252
We obtain local C α, C 1,α, and C 2,α regularity results up to the boundary for viscosity solutions of fully nonlinear uniformly elliptic second order equations with Neumann boundary conditions. 相似文献
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Emmanouil E. Zachariadis Christos D. Tarantilis Chris T. Kiranoudis 《European Journal of Operational Research》2010
This paper deals with a routing problem variant which considers customers to simultaneously require delivery and pick-up services. The examined problem is referred to as the Vehicle Routing Problem with Simultaneous Pick-ups and Deliveries (VRPSPD). VRPSPD is an NP-hard combinatorial optimization problem, practical large-scale instances of which cannot be solved by exact solution methodologies within acceptable computational times. Our interest was therefore focused on metaheuristic solution approaches. In specific, we introduce an Adaptive Memory (AM) algorithmic framework which collects and combines promising solution features to generate high-quality solutions. The proposed strategy employs an innovative memory mechanism to systematically maximize the amount of routing information extracted from the AM, in order to drive the search towards diverse regions of the solution space. Our metaheuristic development was tested on numerous VRPSPD instances involving from 50 to 400 customers. It proved to be rather effective and efficient, as it produced high-quality solutions, requiring limited computational effort. Furthermore, it managed to produce several new best solutions. 相似文献
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Dr. Emmanouil Zacharioudakis Poonam Agarwal Dr. Alexandra Bartoli Nathan Abell Lavaniya Kunalingam Dr. Valérie Bergoglio Dr. Blerta Xhemalce Dr. Kyle M. Miller Dr. Raphaël Rodriguez 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(23):6583-6587
Cisplatin derivatives can form various types of DNA lesions (DNA-Pt) and trigger pleiotropic DNA damage responses. Here, we report a strategy to visualize DNA-Pt with high resolution, taking advantage of a novel azide-containing derivative of cisplatin we named APPA, a cellular pre-extraction protocol and the labeling of DNA-Pt by means of click chemistry in cells. Our investigation revealed that pretreating cells with the histone deacetylase (HDAC) inhibitor SAHA led to detectable clusters of DNA-Pt that colocalized with the ubiquitin ligase RAD18 and the replication protein PCNA. Consistent with activation of translesion synthesis (TLS) under these conditions, SAHA and cisplatin cotreatment promoted focal accumulation of the low-fidelity polymerase Polη that also colocalized with PCNA. Remarkably, these cotreatments synergistically triggered mono-ubiquitination of PCNA and apoptosis in a RAD18-dependent manner. Our data provide evidence for a role of chromatin in regulating genome targeting with cisplatin derivatives and associated cellular responses. 相似文献
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Emmanouil D. Tsochatzis Urania Menkissoglu-Spiroudi Dimitrios G. Karpouzas Maria Papageorgiou 《International journal of environmental analytical chemistry》2013,93(5):548-560
Rice crop is mainly cultivated in large river basins which constitute unique ecosystems and their ecological quality is invaluable. However, the high loads of pesticides used in rice cultivation contribute to the contamination of the water resources in such rice-cultivated regions. To regularly monitor the quality of such water resources there is a need for a rapid and sensitive multi-residue analytical method. This study presents the development and validation of a new analytical method for the simultaneous determination of most rice pesticides including penoxsulam, tricyclazole, propanil and its main metabolite 3,4-dichloroaniline, azoxystrobin, molinate, profoxydim and deltamethrin. A solid-phase extraction (SPE) procedure followed by high performance liquid chromatography (HPLC) with diode array detection (DAD) was used. A C18 RP column operated at 30°C was utilised and the analytes were separated with a mobile phase of acetonitrile/water mixture in a linear gradient. Clean-up of water samples and isolation of pesticides was performed on SPE Bakerbond octadecyl cartridges and an ethyl acetate-dichlomethane mixture (9?:?1 v/v, 2?mL) was used for elution. Method validation was performed by means of intra-day (n?=?5) and inter-day accuracy and precision (n?=?8), sensitivity and linearity. The relative recoveries of the pesticides in paddy water samples were acceptable (80.6–110.2%) and the relative standard deviation (RSD%) ranged from 1.9 to 7.6%. Limits of detection (LOD) and limits of quantification (LOQ) varied from 0.1 to 0.8?ng?mL?1 and 0.25 to 2.0?ng?mL?1 respectively, depending on the analyte. The method was subsequently applied for the determination of pesticide residues in paddy and canal water samples. Tricyclazole was the most frequently detected pesticide at the highest concentrations, while herbicides were less frequently detected and at lower concentrations. The method described could be a valuable tool for regular monitoring of surface water systems in rice-cultivated basins. 相似文献
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Emmanouil Fousteris Petroula A. Tarantili Evangelos Karavas Dimitrios Bikiaris 《Journal of Thermal Analysis and Calorimetry》2013,113(3):1037-1047
Poly(vinyl pyrrolidone) (PVP)/poloxamer-188 blends were used as appropriate carriers for the preparation of solid dispersions by hot melt extrusion using aripiprazole (ARIP) as a poor water-soluble model drug. The physical state of ARIP in solid dispersions and its dissolution characteristics were tested for different drug contents and various PVP-to-poloxamer ratios. From TG analysis it was found that all materials were stable at the tested extrusion temperature conditions (110–120 °C) while amorphous drug dispersions were prepared in all cases, due to the miscibility of the polymer matrix with ARIP drug. Furthermore, hydrogen bonds were identified between ARIP (>N–H) and PVP (>C=O) using FT-IR analysis. Finally, ARIP dissolution rate from SDs was pH dependant and increased as the drug content decreased. 相似文献