全文获取类型
收费全文 | 113篇 |
免费 | 17篇 |
国内免费 | 22篇 |
专业分类
化学 | 73篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 15篇 |
物理学 | 58篇 |
出版年
2022年 | 2篇 |
2021年 | 1篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 3篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 6篇 |
2011年 | 7篇 |
2010年 | 3篇 |
2009年 | 7篇 |
2008年 | 5篇 |
2007年 | 3篇 |
2006年 | 6篇 |
2005年 | 3篇 |
2004年 | 10篇 |
2003年 | 9篇 |
2002年 | 12篇 |
2001年 | 7篇 |
2000年 | 10篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 5篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1986年 | 4篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1979年 | 2篇 |
排序方式: 共有152条查询结果,搜索用时 31 毫秒
11.
利用溶液聚合和成酰胺反应合成了多功能梳状两亲性共聚物,聚(甲基丙烯酸-co-甲基丙烯酸十八酯)-(乙醇胺-乙二胺叶酸)(PSM-EE-FA).用红外光谱(FTIR),核磁共振(1H-NMR)及凝胶渗透色谱(GPC)表征了该聚合物的结构及分子量分布.实验结果证明合成了该聚合物,其数均分子量(Mn)为28600,多分散性为1.375.用该两亲梳状聚合物包覆油溶性CdSe/ZnS量子点,通过相转移作用,得到水溶性靶向量子点(PSM-EE-FA-QDs).该水溶性量子点溶液具有较好的稳定性.通过紫外-可见(UV-Vis)及荧光发射光谱分析对该量子点的光学性质进行研究.结果表明,PSM-EE-FA-QDs的紫外-可见光谱及荧光发射光谱峰形与原量子点基本一致.由于量子点表面聚合物层的形成,峰位发生少量红移.该量子点水溶液的荧光强度是原量子点氯仿溶液的98%,荧光产率是原量子点氯仿溶液的95%.动态光散射(DLS)及透射电镜(TEM)测试结果表明水溶性量子点分布均匀.合成的水溶性量子点不但光学性能稳定,而且聚合物及水溶性量子点的合成方法较为简便. 相似文献
12.
13.
14.
以LCD为目标的自动定焦判据选择 总被引:2,自引:0,他引:2
在光学综合自动测量中 ,使用液晶显示屏作为分划板可以大大简化结构 ,提高效率 ,真正地实现自动测量。由于液晶显示具有对比度低、噪声大等特点 ,所以根据液晶的这些特点以及图像处理和CCD信号接收的特点选择两种适用的判据进行了分析和试验比较 ,并给出了结果。结果表明 ,这两种判别函数都适用于以液晶显示屏为目标和用图像处理方法进行光学参数测量的系统 ,其中锐度判别函数更优于信息熵判别函数 ,前者具有更好的抗干扰性和稳定性 ,而且其判定结果更接近目视清晰度判别 相似文献
15.
MOHAMED SAÏDI 《Compositio Mathematica》1997,107(3):319-338
Let R be a discrete complete valuation ring, with algebraically closedresidue field. Let X be a semi-stable R-curve, with smooth generic fibre. In this paper we study tame coverings of X. 相似文献
16.
Mesoporous Silica Nanoparticles Decorated with Carbosilane Dendrons as New Non‐viral Oligonucleotide Delivery Carriers
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ángel Martínez Dr. Elena Fuentes‐Paniagua Dr. Alejandro Baeza Dr. Javier Sánchez‐Nieves Dr. Mónica Cicuéndez Dr. Rafael Gómez Dr. F. Javier de la Mata Dr. Blanca González Prof. María Vallet‐Regí 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(44):15651-15666
A novel nanosystem based on mesoporous silica nanoparticles covered with carbosilane dendrons grafted on the external surface of the nanoparticles is reported. This system is able to transport single‐stranded oligonucleotide into cells, avoiding an electrostatic repulsion between the cell membrane and the negatively charged nucleic acids thanks to the cationic charge provided by the dendron coating under physiological conditions. Moreover, the presence of the highly ordered pore network inside the silica matrix would make possible to allocate other therapeutic agents within the mesopores with the aim of achieving a double delivery. First, carbosilane dendrons of second and third generation possessing ammonium or tertiary amine groups as peripheral functional groups were prepared. Hence, different strategies were tested in order to obtain their suitable grafting on the outer surface of the nanoparticles. As nucleic acid model, a single‐stranded DNA oligonucleotide tagged with a fluorescent Cy3 moiety was used to evaluate the DNA adsorption capacity. The hybrid material functionalised with the third generation of a neutral dendron showed excellent DNA binding properties. Finally, the cytotoxicity as well as the capability to deliver DNA into cells, was tested in vitro by using a human osteoblast‐like cell line, achieving good levels of internalisation of the vector DNA/carbosilane dendron‐functionalised material without affecting the cellular viability. 相似文献
17.
Digital compensation of pressure sensors in the time domain 总被引:1,自引:0,他引:1
This contribution presents an innovative technique to determine the transfer function of pneumatic and fast-response pressure
probes. The dynamic response is determined experimentally with pressure step-tests. In the case of conventional instrumentation
fast-opening valves or balloon explosions are used. For the fast-response pressure sensors, shock tube tests are performed.
The response of the probe is fitted in the time domain with the response of an m-order linear system. This numerical system is then used to correct the lag and dynamic error of the measurement chain.
Received: 27 November 2000 / Accepted: 4 July 2001 相似文献
18.
Banerjee D Paniagua JC Mugnaini V Veciana J Feintuch A Pons M Goldfarb D 《Physical chemistry chemical physics : PCCP》2011,13(41):18626-18637
Water soluble perchlorinated trityl (PTM) radicals were found to be effective 95 GHz DNP (dynamic nuclear polarization) polarizers in ex situ (dissolution) (13)C DNP (Gabellieri et al., Angew Chem., Int. Ed. 2010, 49, 3360). The degree of the nuclear polarization obtained was reported to be dependent on the position of the chlorine substituents on the trityl skeleton. In addition, on the basis of the DNP frequency sweeps it was suggested that the (13)C NMR signal enhancement is mediated by the Cl nuclei. To understand the DNP mechanism of the PTM radicals we have explored the 95 GHz EPR characteristics of these radicals that are relevant to their performance as DNP polarizers. The EPR spectra of the radicals revealed axially symmetric g-tensors. A comparison of the spectra with the (13)C DNP frequency sweeps showed that although the solid effect mechanism is operational the DNP frequency sweeps reveal some extra width suggesting that contributions from EPR forbidden transitions involving (35,37)Cl nuclear flips are likely. This was substantiated experimentally by ELDOR (electron-electron double resonance) detected NMR measurements, which map the EPR forbidden transitions, and ELDOR experiments that follow the depolarization of the electron spin upon irradiation of the forbidden EPR transitions. DFT (density functional theory) calculations helped to assign the observed transitions and provided the relevant spin Hamiltonian parameters. These results show that the (35,37)Cl hyperfine and nuclear quadrupolar interactions cause a considerable nuclear state mixing at 95 GHz thus facilitating the polarization of the Cl nuclei upon microwave irradiation. Overlap of Cl nuclear frequencies and the (13)C Larmor frequency further facilitates the polarization of the (13)C nuclei by spin diffusion. Calculation of the (13)C DNP frequency sweep based on the Cl nuclear polarization showed that it does lead to an increase in the width of the spectra, improving the agreement with the experimental sweeps, thus supporting the existence of a new heteronuclear assisted DNP mechanism. 相似文献
19.
J.P. Solano V. Pinilla G. Paniagua S. Lavagnoli T. Yasa 《International Journal of Heat and Fluid Flow》2011,32(5):1036-1046
This paper reports the external convective heat transfer in an innovative low-pressure vane, designed with a multi-splitter configuration. Three aerodynamic airfoils are positioned in between larger structural vanes, replacing struts presently used in current aero-engines, which results in superior aerodynamic performance. Static pressure and heat flux measurements were carried out in the large compression tube facility of the von Karman Institute, using pneumatic taps and single-layered thin film gauges respectively. The steady and unsteady heat transfer distributions were obtained at representative conditions of modern aero-engines, with M2,is close to unity and a Reynolds number of approximately 106. This facility is specially suited to control the gas-to-wall temperature ratio that drives transition mechanisms. The heat transfer across the multi-splittered passages is confronted with correlations on ducts to further characterize the boundary layer status. The data will be used to guide code developers by verifying their boundary layer transition models, and designers by showing the areas of the vane where heat transfer is most sensitive to the off-design conditions. 相似文献
20.