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31.
Jorge E. P. Monteagudo Geraldo L. Rochocz Paulo L. C. Lage Krishnaswamy Rajagopal 《Fluid Phase Equilibria》2001,190(1-2):1-13
The computation of phase equilibrium for semicontinuous mixtures results in a set of algebraic-functional equations which are commonly solved using the pseudocomponent approach or reducing the order of the functional equations to a set of algebraic equations by means of a Petrov–Galerkin approach. Both approaches can be taken as particular cases of the method of weighed residuals. In order to perform stability analysis of phase equilibrium, the classical tangent plane criterion algorithms can be used as the first approach. There is a lack of functional formulation for the stability criterion in the literature. In some special cases, such as mixtures containing continuous families of heavy-components, a new formulation of the tangent plane criterion is required. In the present work, functional extensions of the Gibbs tangent plane criterion are described. The use of the proposed criteria was exemplified by calculating solid–liquid phase equilibrium of a crude oil containing asphaltenes on titration with a precipitating agent, n-pentane. 相似文献
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The monomeric title compound features a distorted octahedral tin (IV) centre within a C2Cl2N2 donor set with two cis Cl atoms and two trans benzyl groups. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
34.
Krishnaswamy R Rathee V Sood AK 《Langmuir : the ACS journal of surfaces and colloids》2008,24(20):11770-11777
The aggregation properties of an antibiotic membrane-active peptide alamethicin at the air-water interface have been studied using interfacial rheology and fluorescence microscopy techniques. Fluorescence microscopy of alamethicin monolayers revealed a coexistence of liquid expanded (LE) and solid phases at the surface concentrations studied. Interfacial oscillatory shear measurements on alamethicin monolayers indicate that its viscoelastic properties are determined by the area fraction of the solid domains. The role of zwitterionic phospholipids dioleoylphosphatidyl choline (DOPC) and dioleoylphosphatidyl ethanolamine (DOPE) on the peptide aggregation behavior was also investigated. Fluorescence microscopy of alamethicin/phospholipid monolayers revealed an intermediate phase (I) in addition to the solid and LE phase. In mixed monolayers of phospholipid (L)/alamethicin (P), with increase in L/P, the monolayer transforms from a viscoelastic to a viscous fluid with the increase in area fraction of the intermediate phase. Further, a homogeneous mixing of alamethicin/lipid molecules is observed at L/P > 4. Our studies also confirm that the viscoelasticity of alamethicin/phospholipid monolayers is closely related to the alamethicin/phospholipid interactions at the air-water interface. 相似文献
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Krishnaswamy R Majumdar S Ganapathy R Agarwal VV Sood AK Rao CN 《Langmuir : the ACS journal of surfaces and colloids》2007,23(6):3084-3087
We report the interfacial properties of monolayers of Ag nanoparticles 10-50 nm in diameter formed at the toluene-water interface under steady as well as oscillatory shear. Strain amplitude sweep measurements carried out on the film reveal a shear thickening peak in the loss moduli (G") at large amplitudes followed by a power law decay of the storage (G') and loss moduli with exponents in the ratio 2:1. In the frequency sweep measurements at low frequencies, the storage modulus remains nearly independent of the angular frequency, whereas G" reveals a power law dependence with a negative slope, a behavior reminiscent of soft glassy systems. Under steady shear, a finite yield stress is observed in the limit of shear rate .gamma going to zero. However, for .gamma > 1 s-1, the shear stress increases gradually. In addition, a significant deviation from the Cox-Merz rule confirms that the monolayer of Ag nanoparticles at the toluene-water interface forms a soft two-dimensional colloidal glass. 相似文献
37.
Nivedita Rathnakar Desai Krishnaswamy Gurunathan Parameshwar Adimule Suchetan Aruna Kumar Doyjide Basappa Shivalingegowda Naveen Neratur Krishnappagowda Lokanath Swamy Sreenivasa 《Research on Chemical Intermediates》2017,43(11):6131-6154
The present work reports the synthesis of novel 2-(4-(4-substitutedphenylsulfonyl) piperazin-1-yl) quinolone-3-carbaldehyde derivatives, namely, 2-(4-tosylpiperazin-1-yl)quinoline-3-carbaldehyde (4a), 2-(4-(4-nitrophenylsulfonyl)piperazin-1-yl)quinoline-3-carbaldehyde (4b) and 2-(4-(4-tert-butylphenylsulfonyl) piperazin-1-yl)quinoline-3-carbaldehyde (4c). These compounds have been characterized by FT-IR, 1H-NMR, 13C-NMR and LCMS. Further, the structures of compounds 4b and 4c have been elucidated by single crystal X-ray diffraction studies. The asymmetric unit of 4b contains two molecules (A and B) and that of 4c contains one. The piperazine ring in both the molecules 4b and 4c has chair conformation and the aldehyde group is twisted with respect to the quinoline group, respectively, by 13.3 (3)°, 18.2 (3)° and 11.2 (3)° in Molecule A & B of 4b and 4c due to the bulky piperazinyl group present in the ortho position. The crystal structures of both features interactions of the type C-H…O, C-H…πaryl and πaryl… πaryl, leading to a three-dimensional (3D) supramolecular architecture in 4b and a one-dimensional (1D) architecture in 4c. The various intermolecular interactions exhibited in 4b and 4c are well supported by Hirshfeld surface and fingerprint plots analysis. Further, the three compounds were evaluated for their in-silico antimicrobial activity. In-silico molecular docking studies were carried out in order to know the binding modes of the synthesized compounds with DNA Gyrase A and N-myristoyltranferase as target proteins for antibacterial and antifungal docking studies, respectively. 相似文献
38.
Intramolecular Cyclization of Carbonate and Thiocarbonate Derivatives of myo‐Inositol in the Solid State: Implications for Acyl Group Transfer Reactions in Molecular Crystals 下载免费PDF全文
Majid I. Tamboli Dr. Mysore S. Shashidhar Dr. Rajesh G. Gonnade Dr. Shobhana Krishnaswamy 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(39):13676-13682
Racemic 4‐O‐phenoxycarbonyl and 4‐O‐phenoxythiocarbonyl derivatives of myo‐inositol orthoformate undergo thermal intramolecular cyclization in the solid state to yield the corresponding 4,6‐bridged carbonates and thiocarbonates, respectively. The thermal cyclization also occurs in the solution and molten states, but less efficiently, suggesting that these cyclization reactions are aided by molecular pre‐organization, although not strictly topochemically controlled. Crystal structures of two carbonates and a thiocarbonate clearly revealed that the relative orientation of the electrophile and the nucleophile in the crystal lattice facilitates the intramolecular cyclization reaction and forbids the intermolecular reaction. The correlation observed between the chemical reactivity and the non‐covalent interactions in the crystal of the reactants provides a way to estimate the chemical stability of analogous molecules in the solid state. 相似文献
39.
Shobhana Krishnaswamy Madhuri T. Patil Mysore S. Shashidhar 《Acta Crystallographica. Section C, Structural Chemistry》2011,67(11):o435-o438
The conversion of myo‐inositol to epi‐inositol can be achieved by the hydride reduction of an intermediate epi‐inosose derived from myo‐inositol. (−)‐epi‐Inosose, (I), crystallized in the monoclinic space group P21, with two independent molecules in the asymmetric unit [Hosomi et al. (2000). Acta Cryst. C 56 , e584–e585]. On the other hand, (2RS,3SR,5SR,6SR)‐epi‐inosose, C6H10O6, (II), crystallized in the orthorhombic space group Pca21. Interestingly, the conformation of the molecules in the two structures is nearly the same, the only difference being the orientation of the C‐3 and C‐4 hydroxy H atoms. As a result, the molecular organization achieved mainly through strong O—H...O hydrogen bonding in the racemic and homochiral lattices is similar. The compound also follows Wallach's rule, in that the racemic crystals are denser than the optically active form. 相似文献
40.
Shi Jin Peter Minev Krishnaswamy Nandakumar 《International Journal of Computational Fluid Dynamics》2013,27(5):427-437
Particulate flow is of great importance from both the scientific and engineering points of view. Owing to the complexity of particle-flow interactions, direct numerical simulations (DNS) of inertial particulate flow with finite-size particles have been limited to a very small number of particles, while the industrial applications involve larger numbers with many orders of magnitude. This article presents a parallel implementation of a fictitious domain method for the DNS of particulate flows. The method is thoroughly tested and its parallel performance on distributed memory clusters is evaluated on a large-scale problem. Finally, we present the results for the separation of 21,336 particles of two different densities in a viscous fluid. Although there is still a significant gap between DNS and the industrial applications, the present algorithm allows to simulate significantly large number of particles so that a meaningful statistical analysis can be performed. This will help in the development of new closure relations for the averaged models of multiphase flows. 相似文献