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113.
J. B. Alexander Ross William R. Laws John Clark Sutherland Angeliki Buku Panayotis G. Katsoyannis Irving L. Schwartz Herman R. Wyssbrod 《Photochemistry and photobiology》1986,44(3):365-370
A linked-function approach to fluorescence decay data analysis is presented that permits complex systems to be resolved from a single decay curve. The method involves linking fluorescence decay parameters based on a relationship established by independent physical measurements. As an example, by correlating the fluorescence data with 1 H-NMR results, the complex fluorescence decay kinetics of tyrosine analogs and single tyrosyl residues in simple polypeptides can be explained by ground-state rotameric populations of the phenol ring about the Cα-Cβ bond. 相似文献
114.
Charalabos Camoutsis Panayotis Catsoulacos G. Salem A. Terzis S. E. Filippakis 《Journal of heterocyclic chemistry》1981,18(7):1405-1407
Substituted-3-benzylidenebenzo[b]thiophen-2-ones have been synthesized. 5,6-Dimethoxybenzo[b]-thiophen-2-(3H)one with aniline and triethyl orthoformate gives the 3-anilinomethylene compound, which can be hydrolysed to give the corresponding 3-hydroxymethylene derivative. Dimethoxybenzo[b]thieno[2,3-b]-quinoline has been synthesized. 相似文献
115.
The 1081 species cyclohexane-oxidation elementary reaction mechanism of Silke et al. (DOI: 10.1021/jp067592d ) is reduced in the number of species by a factor using the local self-similarity tabulation (LS2T) method. Reduced-species mechanisms of both 20 (R20) and 15 (R15) species are created in the high-pressure combustion regime typical of diesel engines. To evaluate the performance of R20 and R15 against the elementary kinetics, simulations are performed for cyclohexane/air mixtures at initial temperatures of 1150, 900, 750, and 680 K and constant pressures of 20 and 40 bar for a variety of equivalence ratios (, 1.0, and 2 for 1150 and 900 K; for 750 K; for 680 K). Very good agreement between R20 and R15 with the elementary kinetics mechanism is demonstrated at 1150 and 900 K for which the self-similarity is very well obeyed; however, only fair agreement is obtained at 750 and 680 K, a fact which is traced to the less faithful adherence to the self-similarity due to the one order of magnitude increase in ignition time over the range 750-680 K. These results are found to be quasi-independent of the tabulation grid. Future work is proposed to improve the reduction in the cold-ignition, high-pressure regime. 相似文献
116.
Thierry M. Faure Panayotis Adrianos François Lusseyran Luc Pastur 《Experiments in fluids》2007,42(2):169-184
The interaction between a laminar boundary layer and an open cavity is investigated experimentally for medium range Reynolds
numbers. Flow visualizations are carried out for three different observation directions in order to understand the spatial
development of dynamical structures. In particular, synchronized visualizations in two parallel planes picture the transverse
development of the flow. The study is conducted by changing the cavity aspect ratio, the Reynolds number and therefore the
flow patterns inside the cavity. The issue is to emphasize the 3-D development of the flow. In particular, we show that the
dynamical structures are not due to secondary shear layer instabilities. 相似文献
117.
V. V. Shilov V. V. Shevchenko P. Pissis A. Kyritsis Yu. P. Gomza S. D. Nesin N. S. Klimenko 《Solid State Ionics》1999,120(1-4):43-50
Thermal transitions, morphology and electric conductivity of polyurethanes that contain acid (COOH) groups bound to their polyether (poly(tetramethylene oxide)) chains and hard urethane segments of various length have been studied by means of calorimetry, wide- and small-angle X-ray scattering and a.c. conductivity in wide range of frequencies (0.1 Hz–1 MHz) and temperature (−100 to 100°C). It was shown that the polyurethanes are basically microphase-separated systems whose polyether-rich matrix contain from 20 to 25% of the hard urethane fragments. The protonic conductivity of the materials decreases with decreasing the polyether phase in the system. 相似文献
118.
119.
Panayotis Panayotaros 《Physics letters. A》2010,374(38):3912-3919
We study the continuation of breather solutions of the discrete NLS equation as the intersite coupling parameter is varied. Considering the case of a finite one-dimensional lattice of N sites, we show the existence of N branches of breathers that persist for arbitrary coupling, thus connecting normal modes of the linear system to breathers of the uncoupled, anticontinuous limit system. The proof is based on global bifurcation theory, applied to the continuation from the weakly nonlinear regime. As the coupling parameter varies these solutions generally change their stability, and we detect parameter regions where trajectories starting near unstable breathers appear to reach equipartition of power. 相似文献
120.
Maganas D Krzystek J Ferentinos E Whyte AM Robertson N Psycharis V Terzis A Neese F Kyritsis P 《Inorganic chemistry》2012,51(13):7218-7231
In this work, magnetometry and high-frequency and -field electron paramagnetic resonance spectroscopy (HFEPR) have been employed in order to determine the spin Hamiltonian (SH) parameters of the non-Kramers, S = 1, pseudooctahedral trans-[Ni(II){(OPPh(2))(EPPh(2))N}(2)(sol)(2)] (E = S, Se; sol = DMF, THF) complexes. X-ray crystallographic studies on these compounds revealed a highly anisotropic NiO(4)E(2) coordination environment, as well as subtle structural differences, owing to the nature of the Ni(II)-coordinated solvent molecule or ligand E atoms. The effects of these structural characteristics on the magnetic properties of the complexes were investigated. The accurately HFEPR-determined SH zero-field-splitting (zfs) D and E parameters, along with the structural data, provided the basis for a systematic density functional theory (DFT) and multiconfigurational ab initio computational analysis, aimed at further elucidating the electronic structure of the complexes. DFT methods yielded only qualitatively useful data. However, already entry level ab initio methods yielded good results for the investigated magnetic properties, provided that the property calculations are taken beyond a second-order treatment of the spin-orbit coupling (SOC) interaction. This was achieved by quasi-degenerate perturbation theory, in conjunction with state-averaged complete active space self-consistent-field calculations. The accuracy in the calculated D parameters improves upon recovering dynamic correlation with multiconfigurational ab initio methods, such as the second-order N-electron valence perturbation theory NEVPT2, the difference dedicated configuration interaction, and the spectroscopy-oriented configuration interaction. The calculations showed that the magnitude of D (~3-7 cm(-1)) in these complexes is mainly dominated by multiple SOC contributions, the origin of which was analyzed in detail. In addition, the observed largely rhombic regime (E/D = 0.16-0.33) is attributed to the highly distorted metal coordination sphere. Of special importance is the insight by this work on the zfs effects of Se coordination to Ni(II). Overall, a combined experimental and theoretical methodology is provided, as a means to probe the electronic structure of octahedral Ni(II) complexes. 相似文献