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11.
Haihong Fang Binyuan Hu Lingshen Wang Rongli Lu Cui Yang 《Frontiers of Chemistry in China》2008,3(2):193-197
Nanometer MgO was prepared via a sol-gel auto-combustion technique using magnesium nitrate as raw material and citric acid
as chelating agent. IR spectra of the dried gel were used to investigate the structure of the precursors. By studying the
different TG curves of magnesium citrate gel prepared by different methods, we found that a combustion process occurred and
the nitrate ions acted as an oxidant in the combustion process. TEM photographs of synthesized powders from the sol-gel auto-combustion
showed that the crystallites were uniform in size. In addition, the XRD pattern of this sample showed that the particle size
was 8.9 nm. The BET curves, in turn, showed that the specific surface of the sample was 26.34 m2/g. The mechanism of the frothing process in restraining agglomeration is discussed.
__________
Translated from Journal of East China Normal University (Natural Science), 2007, (2): 52–57 [译自: 华东师范大学学报(自然科学版)] 相似文献
12.
Shiyue Fang 《Tetrahedron letters》2004,45(43):7987-7990
A reversible biotinylation phosphoramidite was synthesized and incorporated onto the 5′-end of an oligoribonucleotide on a solid phase synthesizer. After cleavage and deprotection, the crude synthetic oligomer mixture was incubated with NeutrAvidin® coated microspheres, and the failure sequences removed by washing with a buffer followed by treating the microspheres with tetrabutylammonium fluoride to give a high quality unmodified full-length oligoribonucleotide. 相似文献
13.
潘建敏 《浙江大学学报(理学版)》1997,24(2):108-114
本文探讨了随机删失场合半参数回归模型的参数估计问题.考虑半参数回归模型Y =X}}3 + g(T)十。,其中(X,T)’为取值于Kp X [0,1〕上的随机向量,月为1'维未知参数向量,8为定义于【0.1]上的未知函数,。为随机误差,Ee = 0 . Eez = az }。未知,且(X ,T)与。独立,).被一个与之独立的随机变量V所截.此时仅能观察到:Z=min(Y,V),o=1(Y簇V),参数I3,az的估计量禽及公 z可综合非参数的权函数估计法与参数的最小二乘估计方法得到.本文对核函数的情形得到了念及ar z的精确收敛速度即重对数律. 相似文献
14.
15.
Guey‐Sheng Liou Sheng‐Huei Hsiao Yi‐Kai Fang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(21):6466-6483
Two new phenyl‐ and naphthyl‐substituted rigid‐rod aromatic dicarboxylic acid monomers, 2,2′‐diphenylbiphenyl‐4,4′‐dicarboxylic acid ( 4 ) and 2,2′‐di(1‐naphthyl)biphenyl‐4,4′‐dicarboxylic acid ( 5 ), were synthesized by the Suzuki coupling reaction of 2,2′‐diiodobiphenyl‐4,4′‐dicarboxylic acid dimethyl ester with benzeneboronic acid and naphthaleneboronic acid, respectively, followed by alkaline hydrolysis of the ester groups. Four new polyhydrazides were prepared from the dicarboxylic acids 4 and 5 with terephthalic dihydrazide (TPH) and isophthalic dihydrazide (IPH), respectively, via the Yamazaki phosphorylation reaction. These polyhydrazides were amorphous and readily soluble in many organic solvents. Differential scanning calorimetry (DSC) indicated that these hydrazide polymers had glass transition temperatures in the range of 187–234 °C and could be thermally cyclodehydrated into the corresponding oxadiazole polymers in the range of 300–400 °C. The resulting poly(1,3,4‐oxadiazole)s exhibited Tg's in the range of 252–283 °C, 10% weight‐loss temperature in excess of 470 °C, and char yield at 800 °C in nitrogen higher than 54%. These organo‐soluble polyhydrazides and poly(1,3,4‐oxadiazole)s exhibited UV–Vis absorption maximum at 262–296 and 264–342 nm in NMP solution, and their photoluminescence spectra showed maximum bands around 414–445 and 404–453 nm, respectively, with quantum yield up to 38%. The electron‐transporting properties were examined by electrochemical methods. Cyclic voltammograms of the poly(1,3,4‐oxadiazole) films cast onto an indium‐tin oxide (ITO)‐coated glass substrate exhibited reversible reduction redox with Eonset at ?1.37 to ?1.57 V versus Ag/AgCl in dry N,N‐dimethylformamide solution. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6466–6483, 2006 相似文献
16.
The mass spectra of eight nitrosamines have been recorded, with excitation by chemical ionization (CI) and electron impact (EI). Comparison of the intensities of the base peaks under CI and El conditions gives intensity ratios in the range 1.4-1.9 for low resolution measurements and up to 10 for high resolution measurements, confirming the enhanced sensitivity available in the CI mode. 相似文献
17.
A number of 6(5H)-phenanthridinones have been conveniently prepared from 9-oxofluorenes through the Schmidt reaction. It has been found that all amino and nitro 9-oxofluorenes thus far tried gave substituted 6(5H)-phenanthridinones with the amino or nitro group situated in the benzene ring attached to the nitrogen of the lactam group. UV and IR spectral data are presented for these compounds. 相似文献
18.
A gas chromatographic method for monitoring diacetyl guanfubase A in plasma is described. The procedure involved a single solvent extraction of drug from rabbit plasma into ethyl acetate with guanfubase A as an internal standard. The extract was analyzed subsequently on a gas chromatograph equipped with a hydrogen flame ionization detector. The recovery was 86.43% +/- 6.90% (+/- SD); the RSD of within-day and between-day was 2.81%-5.26% and 5.22%-8.24%, respectively; the regression line was linear over the concentration range of 25-200 micrograms/mL, the limit of detection was 10 micrograms/mL. No endogeneous interference was found in chromatograms of the biological samples. This method was applied to the pharmacokinetic study of diacetyl guanfubase A in rabbits. 相似文献
19.
Pan Ziqiang Fan Shengen Cong Huiling 《Journal of Radioanalytical and Nuclear Chemistry》1996,206(2):239-249
The exposure dose status on radioisotope production and application in China has been assessed in the paper. The average annual occupational exposure dose received by workers in the radioisotope production is about one tenth of the annual dose limit in normal situation. It is less than one twentieth for workers in the radioisotope applications. However, the annual collective dose for the latter is higher than the former by one oder of magnitude due to the larger number of workers in the application field. Although the output of radioisotopes increased doubly in 1980's as compared with 1970's, the increase on the annual collective dose was not obvious. For exposure to the public,131I for example, the collective dose in the radioisotope production decreased by one to two orders of magnitude and the releasing factor reduced by two orders of magnitude. Therefore, the exposure dose received by workers in radioisotope production and application is lower in normal situation. However, the facts worth paying attention to are that there were many events and accidents which happened in the radioisotope applications, especially at the irradiation facilities. The probability of fatal accident was as high as 10–3 per irradiator year. In order to improve the radiation safety situation, it is imperative to conduct the safety assessment for irradiation facilities, to enhance management of the radioactive wastes and spent sources and to establish the experience feedback system. 相似文献
20.