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91.
A gas chromatographic method for monitoring diacetyl guanfubase A in plasma is described. The procedure involved a single solvent extraction of drug from rabbit plasma into ethyl acetate with guanfubase A as an internal standard. The extract was analyzed subsequently on a gas chromatograph equipped with a hydrogen flame ionization detector. The recovery was 86.43% +/- 6.90% (+/- SD); the RSD of within-day and between-day was 2.81%-5.26% and 5.22%-8.24%, respectively; the regression line was linear over the concentration range of 25-200 micrograms/mL, the limit of detection was 10 micrograms/mL. No endogeneous interference was found in chromatograms of the biological samples. This method was applied to the pharmacokinetic study of diacetyl guanfubase A in rabbits. 相似文献
92.
A novel diterpene derivative, 5-methyl-5-(4,8,12-trimethyl-tridecyl)-dihydro-furan-2-one (1) and a new chromone, 5-hydroxy-7-methoxy-3-methyl-chromen-4-one (2), along with a known compound, phytol (3) have been isolated from the aerial parts of Hypericum perforatum. Their structures were established on the basis of spectroscopic analysis and by comparison with published values. 相似文献
93.
Yuming Dong Yuqiang Ding Weifu Dong Cheng Yang Xuefeng Liu Ye Fan Jing Wang Qingwei Pan 《大学化学》1986,35(10):71-76
Based on the development prospect of cosmetics industry, the advantage of light industry characteristic and the foundation of applied chemistry in Jiangnan University, a systematic upgrading of applied chemistry was carried out through "emerging engineering education (3E)" project "upgrade and practice of chemistry-related majors of local and/or trade university responding to the social developments" supported by the Ministry of Education. On the basis of investigation and analysis, the orientation and training goal of applied chemistry were updated first, and then the curriculum system was determined and the curriculum construction is strengthened, so as to achieve more distinctive characteristics, more solid foundation and more comprehensive quality. In view of the new requirements of the 3E for talent training, some practices have been formed in the aspects of multi-disciplinary integration, multi-angle coordination and close integration to industry. Contributing the development of cosmetics industry and seizing the commanding point of science and technology from the perspective of talent training, will play a unique role in human social progress. 相似文献
94.
Pan Ziqiang Fan Shengen Cong Huiling 《Journal of Radioanalytical and Nuclear Chemistry》1996,206(2):239-249
The exposure dose status on radioisotope production and application in China has been assessed in the paper. The average annual occupational exposure dose received by workers in the radioisotope production is about one tenth of the annual dose limit in normal situation. It is less than one twentieth for workers in the radioisotope applications. However, the annual collective dose for the latter is higher than the former by one oder of magnitude due to the larger number of workers in the application field. Although the output of radioisotopes increased doubly in 1980's as compared with 1970's, the increase on the annual collective dose was not obvious. For exposure to the public,131I for example, the collective dose in the radioisotope production decreased by one to two orders of magnitude and the releasing factor reduced by two orders of magnitude. Therefore, the exposure dose received by workers in radioisotope production and application is lower in normal situation. However, the facts worth paying attention to are that there were many events and accidents which happened in the radioisotope applications, especially at the irradiation facilities. The probability of fatal accident was as high as 10–3 per irradiator year. In order to improve the radiation safety situation, it is imperative to conduct the safety assessment for irradiation facilities, to enhance management of the radioactive wastes and spent sources and to establish the experience feedback system. 相似文献
95.
在进行有机氯化物分子内非键合相互作用的热化学研究中, 为了排除分子间的相互作用, 需要准确的标准蒸发焓或升华焓, 以便把凝聚态的标准生成焓转变为气态的数据。文献中多氯代烷烃的蒸发焓数据不多, 其中由直接量热法得到的准确数据更少, 因此我们测量了一些多氯代烷烃的标准蒸发焓, 并对其规律作了一些探讨。 相似文献
96.
Gelders GG Bijnens L Loosveld AM Vidts A Delcour JA 《Journal of chromatography. A》2003,992(1-2):75-83
Low levels of high-molecular-mass dextrins in starch hydrolysates can be detected by high-performance anion-exchange chromatography with pulsed amperometric detection in spite of their low responses by dialysis of the starch hydrolysate and fractionation of the resulting adialysate with ethanol (final concentration 30-80% at 6 degrees C). In doing so, dextrin fractions with a relatively narrow molecular mass distribution were obtained. 相似文献
97.
Liu J Pan D Tseng Y Hopfinger AJ 《Journal of chemical information and computer sciences》2003,43(6):2170-2179
A training set of 55 antifungal p450 analogue inhibitors was used to construct receptor-independent four-dimensional quantitative structure-activity relationship (RI 4D-QSAR) models. Ten different alignments were used to build the models, and one alignment yields a significantly better model than the other alignments. Two different methodologies were used to measure the similarity of the best 4D-QSAR models of each alignment. One method compares the residual of fit between pairs of models using the cross-correlation coefficient of their residuals of fit as a similarity measure. The other method compares the spatial distributions of the IPE types (3D-pharmacophores) of pairs of 4D-QSAR models from different alignments. Optimum models from several different alignments have nearly the same correlation coefficients, r(2), and cross-validation correlation coefficients, xv-r(2), yet the 3D-pharmacophores of these models are very different from one another. The highest 3D-pharmacophore similarity correlation coefficient between any pair of 4D-QSAR models from the 10 alignments considered is only 0.216. However, the best 4D-QSAR models of each alignment do contain some proximate common pharmacorphore sites. A test set of 10 compounds was used to validate the predictivity of the best 4D-QSAR models of each alignment. The "best" model from the 10 alignments has the highest predictivity. The inferred active sites mapped out by the 4D-QSAR models suggest that hydrogen bond interactions are not prevalent when this class of P450 analogue inhibitors binds to the receptor active site. This feature of the 4D-QSAR models is in agreement with the crystal structure results that indicate no ligand-receptor hydrogen bonds are formed. 相似文献
98.
本文研究带有五次项的非线性Schrödinger方程初边值问题的有限差分法,其中方程中二阶偏导数项的系数、五次项的系数及初值满足下面的条件(1.6).针对此问题,我们研究了一个守恒差分格式,在条件(1.6)下,差分解的$L^{\infty}$模先验估计被得到.在此基础上,我们得到了差分解最优$L^2$模的误差估计. 相似文献
99.
Bello-Cruz Yunier Li Guoyin Nghia Tran Thai An 《Journal of Optimization Theory and Applications》2022,194(1):167-190
Journal of Optimization Theory and Applications - In the previous paper Bello-Cruz et al. (J Optim Theory Appl 188:378–401, 2021), we showed that the quadratic growth condition plays a key... 相似文献
100.
A Review of Results on Axially Symmetric Navier-Stokes Equations,with Addendum by X. Pan and Q. Zhang 下载免费PDF全文
Qi Zhang & Xinghong Pan 《分析论及其应用》2022,38(3):243-296
In this paper, we give a brief survey of recent results on axially symmetric
Navier-Stokes equations (ASNS) in the following categories: regularity criterion, Liouville property for ancient solutions, decay and vanishing of stationary solutions. Some
discussions also touch on the full 3 dimensional equations. Two results, closing of the
scaling gap for ASNS and vanishing of homogeneous D solutions in 3 dimensional
slabs will be described in more detail.In the addendum, two new results in the 3rd category will also be presented, which
are generalizations of recently published results by the author and coauthors. 相似文献