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101.
Rosa M. Rodriguez-Jasso Solange I. Mussatto Lorenzo Pastrana Cristóbal N. Aguilar José A. Teixeira 《Chemical Papers》2014,68(2):203-209
Sulphated polysaccharides (SP) were extracted from Fucus vesiculosus seaweed by using two different hydrothermal processes: microwave-assisted extraction (MAE) and autohydrolysis (AH). The extraction yields, chemical composition, and antioxidant activity of the polysaccharides extracted were determined and compared. Although both processes afforded SP with similar yields (18.2 mass % and 16.5 mass %, for MAE and AH, respectively) and l-fucose as the main monosaccharide, the heterogeneous structure of the polysaccharide recovered was significantly affected by the AH process. The SP obtained by MAE contained 53.8 mole % of fucose, 35.3 mole % of xylose, and 10.8 mole % of galactose; while the SP obtained by AH was composed of 76.8 mole % of fucose and 23.2 mole % of galactose. Both samples presented comparable values of antioxidant activity by the di(phenyl)-(2,4,6-trinitrophenyl)iminoazanium (2,2-diphenyl-1-picrylhydrazyl, DPPH), 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS), and lipid oxidation inhibition methods, but the polysaccharide obtained by AH exhibited a higher antioxidant potential by the differential pulse voltammetry technique. This study demonstrates that the chemical composition and antioxidant activity of SP obtained from F. vesiculosus vary according to the process used for their extraction. However, the SP obtained by MAE or AH both have the potential for use as natural antioxidants in industrial applications. 相似文献
102.
Giacomo Picci Matthew T. Mulvee Claudia Caltagirone Vito Lippolis Antonio Frontera Rosa M. Gomila Jonathan W. Steed 《Molecules (Basel, Switzerland)》2022,27(4)
Three novel bis-urea fluorescent low-molecular-weight gelators (LMWGs) based on the tetraethyl diphenylmethane spacer—namely, L1, L2, and L3, bearing indole, dansyl, and quinoline units as fluorogenic fragments, respectively, are able to form gel in different solvents. L2 and L3 gel in apolar solvents such as chlorobenzene and nitrobenzene. Gelator L1 is able to gel in the polar solvent mixture DMSO/H2O (H2O 15% v/v). This allowed the study of gel formation in the presence of anions as a third component. An interesting anion-dependent gel formation was observed with fluoride and benzoate inhibiting the gelation process and H2PO4−, thus causing a delay of 24 h in the gel formation. The interaction of L1 with the anions in solution was clarified by 1H-NMR titrations and the differences in the cooperativity of the two types of NH H-bond donor groups (one indole NH and two urea NHs) on L1 when binding BzO− or H2PO4− were taken into account to explain the inhibition of the gelation in the presence of BzO−. DFT calculations corroborate this hypothesis and, more importantly, demonstrate considering a trimeric model of the L1 gel that BzO− favours its disruption into monomers inhibiting the gel formation. 相似文献
103.
Branca RT Jenista ER Warren WS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,209(2):347-351
Intermolecular dipolar interactions between proton and carbon spins can be used to indirectly detect carbon spectra with high sensitivity. In this communication, we present a modified sequence that, in addition to the high sensitivity of heteronuclear intermolecular multiple quantum coherence (iMQC) experiments, retains the line narrowing capability characteristic of homonuclear zero-quantum coherences. We demonstrate that this sequence can be used to obtain high resolution (13)C spectra in the presence of magnetic field inhomogeneities, both for thermal and hyperpolarized samples, and discuss applications to water-hyperpolarized carbon imaging. 相似文献
104.
A statistical model of homopolymer DNA, coupling internal base-pair states (unbroken or broken) and external thermal chain fluctuations, is exactly solved using transfer kernel techniques. The dependence on temperature and DNA length of the fraction of denaturation bubbles and their correlation length is deduced. The thermal denaturation transition emerges naturally when the chain fluctuations are integrated out and is driven by the difference in bending (entropy dominated) free energy between broken and unbroken segments. Conformational properties of DNA, such as persistence length and mean-square-radius, are also explicitly calculated, leading, e.g., to a coherent explanation for the experimentally observed thermal viscosity transition. 相似文献
105.
Ferretti A Baldacchini C Calzolari A Di Felice R Ruini A Molinari E Betti MG 《Physical review letters》2007,99(4):046802
By combining experimental and theoretical approaches, we study the adsorption of pentacene on copper as a model for the coupling between aromatic molecules and metal surfaces. Our results for the interface electronic structure are not compatible with a purely physisorption picture, which is conventionally employed for such systems. Nay, we demonstrate electronic mixing between molecular orbitals and metal electronic states. 相似文献
106.
Two-phase turbulent flows with the dispersed phase in the form of small, spherical particles are increasingly often computed with the large-eddy simulation (LES) of the carrier fluid phase, coupled to the Lagrangian tracking of particles. To enable further model development for LES with inertial particles subject to gravity, we consider direct numerical simulations of homogeneous isotropic turbulence with a large-scale forcing. Simulation results, both without filtering and in the a priori LES setting, are reported and discussed. A full (i.e. a posteriori) LES is also performed with the spectral eddy viscosity. Effects of gravity on the dispersed phase include changes in the average settling velocity due to preferential sweeping, impact on the radial distribution function and radial relative velocity, as well as direction-dependent modification of the particle velocity variance. The filtering of the fluid velocity, performed in spectral space, is shown to have a non-trivial impact on these quantities. 相似文献
107.
108.
Rosa M. Miró-Roig 《Rendiconti del Circolo Matematico di Palermo》1938,62(1):153-164
The goal of this paper is to demonstrate that all non-singular rational normal scrolls \(S(a_0,\ldots ,a_k)\subseteq \mathbb P ^N\), \(N =\sum _{i=0}^k(a_i)+k\), (unless \(\mathbb P ^{k+1}=S(0,\ldots ,0,1)\), the rational normal curve \(S(a)\) in \(\mathbb P ^a\), the quadric surface \(S(1,1)\) in \(\mathbb P ^3\) and the cubic scroll \(S(1,2)\) in \(\mathbb P ^4\)) support families of arbitrarily large rank and dimension of simple Ulrich (and hence indecomposable ACM) vector bundles. Therefore, they are all of wild representation type unless \(\mathbb P ^{k+1}\), \(S(a)\), \(S(1,1)\) and \(S(1,2)\) which are of finite representation type. 相似文献
109.
M. Papa G. Cardella A. Di Pietro S. L. Li A. Musumarra G. Pappalardo F. Rizzo A. De Rosa G. Inglima M. La Commara D. Pierroutsakou M. Romoli 《Zeitschrift für Physik A Hadrons and Nuclei》1995,353(2):205-212
The properties of the strong fluctuations observed in the excitation functions of Dissipative Binary Heavy Ion Collisions (DBHIC) have been studied for the system28Si+28Si in the energy range 150 MeV ≤E lab ≤ 156 MeV with 150 keV step laboratory incident energy, by angular distributions and excitation functions measurements. Experimental results are compared to the the recently developed Partially Overlapping Molecular Level Model (POMLM). The parameters of the model have been determined with reasonable accuracy by describing all the quantities characterizing the fluctuations in the excitation functions i.e.: Average Angular Distributions, Energy Autocorrelation Functions, Variances, Angular Correlation Coefficients. The results of the analysis strongly support the idea of a process proceeding through the formation of an highly excited “nuclear molecule”. Experimental data collected at the most forward angles show the effects of strong excitation of a few final channels. 相似文献
110.
De La Rosa Nathaly Kristiansson Per Nilsson E. J. Charlotta Ros Linus Pallon Jan Skogby Henrik 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(1):253-259
Journal of Radioanalytical and Nuclear Chemistry - Proton-induced reaction (p,α) is one type of nuclear reaction analysis (NRA) suitable especially for light element quantification.... 相似文献