全文获取类型
收费全文 | 147篇 |
免费 | 5篇 |
国内免费 | 1篇 |
专业分类
化学 | 118篇 |
晶体学 | 2篇 |
数学 | 11篇 |
物理学 | 22篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 9篇 |
2021年 | 4篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 11篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 12篇 |
2012年 | 10篇 |
2011年 | 11篇 |
2010年 | 9篇 |
2009年 | 11篇 |
2008年 | 7篇 |
2007年 | 7篇 |
2006年 | 7篇 |
2005年 | 7篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1989年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有153条查询结果,搜索用时 15 毫秒
91.
Functional principal component analysis is the preliminary step to represent the data in a lower dimensional space and to
capture the main modes of variability of the data by means of small number of components which are linear combinations of
original variables. Sensitivity of the variance and the covariance functions to irregular observations make this method vulnerable
to outliers and may not capture the variation of the regular observations. In this study, we propose a robust functional principal
component analysis to find the linear combinations of the original variables that contain most of the information, even if
there are outliers and to flag functional outliers. We demonstrate the performance of the proposed method on an extensive
simulation study and two datasets from chemometrics and environment. 相似文献
92.
Tucker's lemma is a combinatorial analog of the Borsuk–Ulam theorem and the case was proposed by Tucker in 1945. Numerous generalizations and applications of the lemma have appeared since then. In 2006 Meunier proved the lemma in its full generality in his PhD thesis. There are generalizations and extensions of the Borsuk–Ulam theorem that do not yet have combinatorial analogs. In this note, we give a combinatorial analog of a result of Freeman J. Dyson and show that our result is equivalent to Dyson's theorem. As with Tucker's lemma, we hope that this will lead to generalizations and applications and ultimately a combinatorial analog of Yang's theorem of which both Borsuk–Ulam and Dyson are special cases. 相似文献
93.
94.
Subhankar Kundu Bahadur Sk Pragyan Pallavi Arkaprabha Giri Abhijit Patra 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(25):5557-5582
White light emitting (WLE) materials are of increasing interest owing to their promising applications in artificial lighting, display devices, molecular sensors, and switches. In this context, organic WLE materials cater to the interest of the scientific community owing to their promising features like color purity, long-term stability, solution processability, cost-effectiveness, and low toxicity. The typical method for the generation of white light is to combine three primary (red, green, and blue) or the two complementary (e.g., yellow and blue or red and cyan) emissive units covering the whole visible spectral window (400–800 nm). The judicious choice of molecular building blocks and connecting them through either strong covalent bonds or assembling through weak noncovalent interactions are the key to achieve enhanced emission spanning the entire visible region. In the present review article, molecular engineering approaches for the development of all-organic WLE materials are analyzed in view of different photophysical processes like fluorescence resonance energy transfer (FRET), excited-state intramolecular proton transfer (ESIPT), charge transfer (CT), monomer-excimer emission, triplet-state harvesting, etc. The key aspect of tuning the molecular fluorescence under the influence of pH, heat, and host–guest interactions is also discussed. The white light emission obtained from small organic molecules to supramolecular assemblies is presented, including polymers, micelles, and also employing covalent organic frameworks. The state-of-the-art knowledge in the field of organic WLE materials, challenges, and future scope are delineated. 相似文献
95.
Pallavi Singhal Dr. Hirendra N. Ghosh 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(11):4405-4412
Ultrafast thermalized and hot‐hole‐transfer processes have been investigated in CdSe quantum dot (QD)/catechol composite systems in which hole transfer from photoexcited QDs to the catechols is thermodynamically favorable. A series of catechol derivatives were selected with different electron‐donating and ‐withdrawing groups, and the effect of these groups on hole transfer and charge recombination (CR) dynamics has been investigated. The hole‐transfer time was determined using the fluorescence upconversion technique and found to be 2–10 ps depending on the molecular structure of the catechol derivatives. The hot‐hole‐transfer process was followed after monitoring 2S luminescence of CdSe QDs. Interestingly, hot‐hole extraction was observed only in the CdSe/3‐methoxycatechol (3‐OCH3) composite system owing to the higher electron‐donating property of the 3‐methoxy group. To confirm the extraction of the hot hole and to monitor the CR reaction in CdSe QD/catechol composite systems, ultrafast transient absorption studies have been carried out. Ultrafast transient‐absorption studies show that the bleach recovery kinetics of CdSe QD at the 2S excitonic position is much faster in the presence of 3‐OCH3. This faster bleach recovery at the 2S position in CdSe/3‐OCH3 suggests hot‐hole transfer from CdSe QD to 3‐OCH3. CR dynamics in CdSe QD/catechol composite systems was followed by monitoring the excitonic bleach at the 1S position and was found to decrease with free energy of the CR reaction. 相似文献
96.
Sanjay Jadhav Arjun KumbharSantosh Kamble Pallavi MoreRajashri Salunkhe 《Comptes Rendus Chimie》2013,16(11):957-961
A gel-entrapped base has been fabricated by using agarose (biopolymer), and tested in the Suzuki–Miyaura cross-coupling reaction in 95% ethanol. The developed environmentally benign polymer-supported base has low leaching and high stability for the Suzuki–Miyaura cross-coupling reaction to give high yield with green credit. 相似文献
97.
98.
We report for the first time, the synthesis and X-ray diffraction studies of single crystals of BeF(2). The crystals were obtained during the sublimation of amorphous BeF(2) under static reduced pressure. BeF(2) crystallizes in the chiral trigonal space group P3(1)21. A single-crystal X-ray diffraction study on these crystals shows that each of the Be atoms is bonded to four F atoms, and each of the F atoms is bonded to two Be atoms with associated Be-F bond distances of 1.5420(13) and 1.5471(13) ?, showing an almost regular tetrahedron. The infrared spectrum of these crystals recorded at room temperature shows distinct peaks around 770 and 410 cm(-1). 相似文献
99.
Core-modified porphyrins have been explored as the second-generation photosensitizers due to their excellent photophysical properties. IY69 [(5-phenyl-10,15-bis(4-carboxylatomethoxyphenyl)-20-(2-thienyl)-21,23-dithiaporphyrin] was developed from the structure optimization guided by in vitro phototoxicity, showing potent activity (IC(50)=80 nm, broadband at 5 J cm(-2), R3230AC cells). The present study demonstrates in vivo photodynamic therapy (PDT) efficacy of IY69 using a murine tumor model (colon 26 cells on BALB/c mice) and 690 nm diode laser. In vitro phototoxicity of IY69 with the diode laser was compared with that with broadband light against colon 26 cells. Attenuation of the laser light by tissue samples was determined to estimate actual power density at targets. Biodistribution in various organs 24, 48, 72 h after i.p. administration was determined. Even though IY69 phototoxicity with the diode laser was less effective than that with the broadband light, the diode laser was quite effective in vitro (IC(50)=0.1 μm, 10 J cm(-2), colon 26 cells). Concentration and light dose-dependent phototoxicity was observed. A significant light attenuation of 95% and 99% was observed by skin and 3 mm muscle with skin. IY69 PDT showed significant damage on tumor and delay in tumor growth in a dose-dependent manner. 相似文献
100.
Thul P Gupta VP Mishra S Tandon P 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(3):1090-1096
A systematic study has been conducted on the geometrical and electronic structure, heliomeric conformations of a series of 8-oxa[5]helicenes based on density functional theory (DFT) computations. A complete vibrational analysis has also been attempted for one of the 8-oxa[5]helicenes (molecule 5) on the basis of experimental infrared spectra in the far and mid infrared regions (60-3100 cm(-1)) and density functional theory computations using B3LYP/6-31G** method characteristic bands of the molecule identified. The approximate mean plane angle between the terminal rings A and E in the presently studied molecules are found to have values between 48.64° and 59.46°. This angle is much larger than the corresponding angle between the terminal rings in benzo[c]phenanthrene (~27°) and partially reduced benzo[c]phenanthrene (34.6-46.0°) and indicates that the presence of oxygen-containing six-membered ring provides a greater helicity to the molecules. Detailed quantum chemical study on molecule 4 shows the existence of two enantiomeric forms M- and P- of almost equal energy separated by a potential barrier of 15.55 kcal/mol. It is expected that similar 8-oxa[5]helicines (molecules 3, 5 and 6) may also exist in two enantiomeric forms. 相似文献