全文获取类型
收费全文 | 2726篇 |
免费 | 96篇 |
国内免费 | 7篇 |
专业分类
化学 | 1711篇 |
晶体学 | 125篇 |
力学 | 85篇 |
数学 | 264篇 |
物理学 | 644篇 |
出版年
2023年 | 19篇 |
2022年 | 50篇 |
2021年 | 50篇 |
2020年 | 45篇 |
2019年 | 55篇 |
2018年 | 58篇 |
2017年 | 47篇 |
2016年 | 88篇 |
2015年 | 78篇 |
2014年 | 87篇 |
2013年 | 241篇 |
2012年 | 141篇 |
2011年 | 140篇 |
2010年 | 113篇 |
2009年 | 109篇 |
2008年 | 125篇 |
2007年 | 115篇 |
2006年 | 91篇 |
2005年 | 94篇 |
2004年 | 81篇 |
2003年 | 64篇 |
2002年 | 76篇 |
2001年 | 34篇 |
2000年 | 25篇 |
1999年 | 27篇 |
1998年 | 16篇 |
1997年 | 21篇 |
1996年 | 31篇 |
1995年 | 27篇 |
1994年 | 18篇 |
1993年 | 30篇 |
1992年 | 30篇 |
1991年 | 32篇 |
1990年 | 28篇 |
1989年 | 38篇 |
1988年 | 26篇 |
1987年 | 25篇 |
1986年 | 30篇 |
1985年 | 28篇 |
1984年 | 33篇 |
1983年 | 25篇 |
1982年 | 25篇 |
1981年 | 30篇 |
1980年 | 26篇 |
1979年 | 25篇 |
1978年 | 15篇 |
1977年 | 32篇 |
1976年 | 16篇 |
1975年 | 21篇 |
1974年 | 20篇 |
排序方式: 共有2829条查询结果,搜索用时 15 毫秒
61.
62.
63.
Vijayakumar Uppar Sandeep Chandrashekharappa Chandan Shivamallu Sushma P Shiva Prasad Kollur Joaquín Ortega-Castro Juan Frau Norma Flores-Holguín Atiyaparveen I. Basarikatti Mallikarjun Chougala Mrudula Mohan M Govindappa Banuprakash Jayadev Katharigatta N. Venugopala Belakatte P. Nandeshwarappa Ravindra Veerapur Abdulaziz A. Al-Kheraif Abdallah M. Elgorban Asad Syed Kiran K. Mudnakudu-Nagaraju Basavaraj Padmashali Daniel Glossman-Mitnik 《Molecules (Basel, Switzerland)》2021,26(9)
64.
[reaction: see text] A wide range of substituted isoquinolines were synthesized via a highly efficient nickel-catalyzed annulation of the tert-butyl imines of 2-iodobenzaldehydes and various alkynes; examination of the regiochemistry of isoquinolines synthesized indicates that there are two different alkyne insertion pathways for the catalytic reactions. 相似文献
65.
Nerium odorum, Linn. (Apocynaceae) is an important evergreen shrub. It is heat, salinity and drought tolerant. Plants with milky sap have medicinal value, mainly cardenolides, flavonoids and terpenes. It is used for wastewater purification and for restoration of riparian woodlands. In view of these facts, the study was conducted for micropropagation of N. odorum. Murashige and Skoog (MS) media supplemented with different concentrations (0.5–10.0 mg/l) of 1-naphthaleneacetic acid (NAA), 2,4-dichlorophenoxyacetic acid (2,4-D), 6-benzylaminopurine (BAP) and kinetin (Kin) were used singly and in combinations. Among all the growth hormones, 2,4-D was the best for callus induction (75 % in stem and 79 % in leaf) and in combination 2,4-D and BAP (78 % in stem and 81 % in leaf). The day of callus induction started from the 19th to the 37th day. This variation is due to the differences in culture conditions and the age of explants. The fresh and dry weight and moisture content showed good growth of callus, which is used in further studies of alkaloid production. Micropropagation of this plant allows the production of clones at a fast rate and in continuous manner. This work can lead to the development of an efficient protocol for callus induction and other issues. 相似文献
66.
Catalytic action of Mn‐superoxide dismutase in scavenging superoxide radical anion by double hydrogen abstraction from dihydrolipoic acid: A theoretical study 下载免费PDF全文
The mechanism of scavenging superoxide radical anion ( ) by dihydrolipoic acid (diLA) in absence and presence of the enzyme Manganese‐superoxide dismutase (Mn‐SOD) has been investigated using density functional theory. Mn‐SOD was modelled by a complex of a manganese cation (Mn2+) bonded to three similar molecules having a histidine ring each and a water molecule. It has been shown that the scavenging mechanism involves double hydrogen abstraction by from different pairs of neighboring sites of diLA. It has been found that diLA alone cannot scavenge superoxide radical anions efficiently as the barrier energies involved in the reactions are very high. However, in presence of Mn‐SOD, owing to its catalytic action, the corresponding reactions become barrierless due to which superoxide radical anions would be scavenged highly efficiently. H2O2 formed from superoxide radical anion due to double hydrogen abstraction from diLA is scavenged by diLA alone barrierlessly without involving Mn‐SOD or any other catalyst. 相似文献
67.
Lead-free perovskite Ba(In1/2Nb1/2)O3 was prepared by conventional ceramic fabrication technique at 1350 °C/5 h in air atmosphere. The crystal symmetry, space group and unit cell dimensions were determined from Rietveld analysis using FullProf software whereas crystallite size and lattice strain were estimated from Williamson-Hall approach. XRD analysis of the compound indicated the formation of a single-phase cubic structure with the space group Pm3m. EDAX and SEM studies were carried out in order to evaluate the quality and purity of the compound. Complex impedance as well as electric modulus analyses suggested the dielectric relaxation to be of non-Debye type. The correlated barrier hopping (CBH) model was employed to successfully explain the mechanism of charge transport in Ba(In1/2Nb1/2)O3. 相似文献
68.
S. Naveen C. S. Ananda Kumar S. B. Benaka Prasad K. Vinaya M. A. Sridhar J. Shashidhara Prasad K. S. Rangappa 《Journal of chemical crystallography》2009,39(6):395-398
Abstract The title compound 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine was synthesized and the structure was investigated by X-ray
crystallography. The title compound, C24H26N2O2S crystallizes in the monoclinic crystal class in the space group P21/c with cell parameters a = 13.5800(10) ?, b = 8.9630(7) ?, c = 18.9040(10) ?, β = 106.851(3)°, Z = 4 and V = 2202.1(3) ?3. The structure has been solved by direct methods and refined to R
1 = 0.0468 for 3174 observed reflections I > 2σ(I). The structure reveals that the piperazine ring is in a chair conformation. The geometry around the S atom is a distorted
tetrahedron.
Graphical Abstract The title compound 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine was synthesized and the structure was investigated by X-ray
crystallography. The title compound, C24H26N2O2S crystallizes in the monoclinic crystal class in the space group P21/c with cell parameters a = 13.5800(10) ?, b = 8.9630(7) ?, c = 18.9040(10) ?, β = 106.851(3)°, Z = 4 and V = 2202.1(3) ?3. The structure has been solved by direct methods and refined to R
1 = 0.0468 for 3174 observed reflections I > 2σ(I). The structure reveals that the piperazine ring is in a chair conformation. The geometry around the S atom is a distorted
tetrahedron.
相似文献
M. A. SridharEmail: |
69.
70.
P. Lasitha Prof. Dr. Edamana Prasad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(30):10558-10564
Perylene diimide (PDI) derivatives exhibit a high propensity for aggregation, which causes the aggregation‐induced quenching of emission from the system. Host–guest chemistry is one of the best‐known methods for preventing aggregation through the encapsulation of guest molecules. Herein we report the use of 18‐crown‐6 (18‐C‐6) as a host system to disaggregate suitably substituted PDI derivatives in methanol. 18‐C‐6 formed complexes with amino‐substituted PDIs in methanol, which led to disaggregation and enhanced emission from the systems. Furthermore, the embedding of the PDI ? 18‐C‐6 complexes in poly(vinyl alcohol) (PVA) films generated remarkably high emission quantum yields (60–70 %) from the PDI derivatives. More importantly, the host–guest systems were tested for their ability to conduct electricity in PVA films. The electrical conductivities of the self‐assembled systems in PVA were measured by electrochemical impedance spectroscopy (EIS) and the highest conductivity observed was 2.42×10?5 S cm?1. 相似文献