全文获取类型
收费全文 | 2716篇 |
免费 | 106篇 |
国内免费 | 7篇 |
专业分类
化学 | 1711篇 |
晶体学 | 125篇 |
力学 | 85篇 |
数学 | 264篇 |
物理学 | 644篇 |
出版年
2023年 | 19篇 |
2022年 | 50篇 |
2021年 | 50篇 |
2020年 | 45篇 |
2019年 | 55篇 |
2018年 | 58篇 |
2017年 | 47篇 |
2016年 | 88篇 |
2015年 | 78篇 |
2014年 | 87篇 |
2013年 | 241篇 |
2012年 | 141篇 |
2011年 | 140篇 |
2010年 | 113篇 |
2009年 | 109篇 |
2008年 | 125篇 |
2007年 | 115篇 |
2006年 | 91篇 |
2005年 | 94篇 |
2004年 | 81篇 |
2003年 | 64篇 |
2002年 | 76篇 |
2001年 | 34篇 |
2000年 | 25篇 |
1999年 | 27篇 |
1998年 | 16篇 |
1997年 | 21篇 |
1996年 | 31篇 |
1995年 | 27篇 |
1994年 | 18篇 |
1993年 | 30篇 |
1992年 | 30篇 |
1991年 | 32篇 |
1990年 | 28篇 |
1989年 | 38篇 |
1988年 | 26篇 |
1987年 | 25篇 |
1986年 | 30篇 |
1985年 | 28篇 |
1984年 | 33篇 |
1983年 | 25篇 |
1982年 | 25篇 |
1981年 | 30篇 |
1980年 | 26篇 |
1979年 | 25篇 |
1978年 | 15篇 |
1977年 | 32篇 |
1976年 | 16篇 |
1975年 | 21篇 |
1974年 | 20篇 |
排序方式: 共有2829条查询结果,搜索用时 31 毫秒
11.
CR-39 is a polycarbonate widely used as SSNTD for recording nuclear charged particles and in other applications. Latent ion tracks produced in the polymers due to the damage produced by the passage of Swift Heavy Ions contain amorphous material with highest degree of disorder, changing the free volume properties which have strong correlation with the macroscopic properties of the material. Positron annihilation lifetime spectroscopy (PALS) provides direct information about the dimension, content and hole size distribution of free volume in polymers. The effect of irradiation of 40Ar (14.9 MeV/n) ions on CR-39 polycarbonate by Positron Annihilation Lifetime Spectroscopy (PALS) is reported here. PALS provides a non-destructive and non-interfering probe, having high detection efficiency for free volume hole properties. From o-Ps lifetime mean free volume hole radius and average free volume of the micro-voids have been calculated. PAL measurement shows an increase in free volume on irradiation. 相似文献
12.
Sankar Prasad Bhuniya Safikur Rahman Anshul J. Satyanand Mahendrasinh M. Gharia Ashok M. Dave 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1650-1658
Maize starch was modified by allyl chloride adopting an interfacial reaction technique with cetyltrimethyl ammonium bromide as a phase‐transfer catalyst and pyridine as an acid acceptor. The degree of substitution was determined from an increasing carbon content of the modified starch. The percentage of carbon and hydrogen of the allyl‐modified starch was estimated by elemental analysis (C, H, and N), and the product characterization was done through 1H NMR and 13C NMR analyses. The allyl‐modified starch was then copolymerized with methacrylic acid and a combination of methacrylic acid and acrylamide at 50 and 70 °C with potassium persulfate as an initiator. The copolymer thus formed swelled in distilled water after neutralization with sodium carbonate. The percentage of absorption capacity of the hydrogels was determined with distilled water and 0.9% NaCl solution. The highest percentage of absorption, 6500%, was achieved for the developed hydrogel containing allyl starch and acrylic monomer in a 1.7:1 w/w ratio and acrylic monomer, namely, methacrylic acid and acrylamide in a 3.2:1 w/w ratio. The study on biodegradability of the developed hydrogel showed that the hydrogel is degradable in the presence of diastase (amylase). © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1650–1658, 2003 相似文献
13.
Rehan A. Kazi Vyas M.N. Prasad Jeeve Kanagalingam Christopher M. Nutting Peter Clarke Peter Rhys-Evans Kevin J. Harrington 《Journal of voice》2007,21(6):661-668
The objective of this study was to assess the difference in voice quality as defined by acoustical analysis using sustained vowel in laryngectomized patients in comparison with normal volunteers. This was designed as a retrospective single center cohort study. An adult tertiary referral unit formed the setting of this study. Fifty patients (40 males) who underwent total laryngectomy and 31 normal volunteers (18 male) participated. Group comparisons with the first three formant frequencies (F1, F2, and F3) using linear predictive coding (LPC) (Laryngograph Ltd, London, UK) was performed. The existence of any significant difference of F1, F2, and F3 between the two groups using the sustained vowel /i/ and the effects of other factors namely, tumor stage (T), chemoradiotherapy, pharyngectomy, cricothyroid myotomy, closure of pharyngoesophageal segment, and postoperative complication were analyzed. Formant frequencies F1, F2, and F3 were significantly different in male laryngectomees compared to controls: F1 (P<0.001, Mann-Whitney U test), F2 (P<0.001, Student's t test), and F3 (P=0.008, Student's t test). There was no significant difference between females in both groups for all three formant frequencies. Chemoradiotherapy and postoperative complications (pharyngocutaneous fistula) caused a significantly lower formant F1 in men, but showed little effect in F2 and F3. Laryngectomized males produced significantly higher formant frequencies, F1, F2, and F3, compared to normal volunteers, and this is consistent with literature. Chemoradiotherapy and postoperative complications significantly influenced the formant scores in the laryngectomee population. This study shows that robust and reliable data could be obtained using electroglottography and LPC in normal volunteers and laryngectomees using a sustained vowel. 相似文献
14.
15.
16.
The authors prove that in the space of nonsingular transformations of a Lebesgue probability space the type III1 ergodic transformations form a denseG
set with respect to the coarse topology. They also prove that for any locally compact second countable abelian groupH, and any ergodic type III transformationT, it is generic in the space ofH-valued cocycles for the integer action given byT that the skew product ofT with the cocycle is orbit equivalent toT. Similar results are given for ergodic measure-preserving transformations as well.Research supported in part by: Nat. Sci. and Eng. Res. Council #A7163 and # U0080 F.C.A.C. Quebec, NSF Grants # MCS-8102399 and # DMS-8418431. 相似文献
17.
18.
Beryllium can be precipitated from homogeneous solution as a dense and easily filterable precipitate by the hydrolysis of urea, in the presence of sulphate. The method has been applied to the gravimetric determination of beryllium as oxide. The nature of the precipitate thus obtained has been examined by thermogravimetric, infrared, photomicrographic and X-ray methods. 相似文献
19.
Y. Shi L. Sun J. E. S. Venart R. C. Prasad 《Journal of Thermal Analysis and Calorimetry》2006,86(3):585-590
The transient hot-wire technique is widely used for absolute measurements
of the thermal conductivity and thermal diffusivity of fluids. It is well
established that fluid radiation effects significantly influence these measurements,
especially those for the thermal diffusivity. Corrections for radiation effects
are based on the models developed and deviations of the measured data from
the ideal line source model. In this paper, the effect of fluid radiation
on the measurements of the thermal conductivity of n-pentane
is presented. For comparison, the influence of thermal radiation effect on
measurement of transparent fluids, such as argon is also shown. The difference
between the influence of natural convection and thermal radiation is also
demonstrated. 相似文献
20.
Selenocystine ([Sec]2) and aryl-substituted selenocysteine (Sec) derivatives are synthesized, starting from commercially available amino acid l-serine. These compounds are characterized by a number of analytical techniques such as NMR (1H, 13C and 77Se) and TOF mass spectroscopy. This study reveals that the introduction of amino/imino substituents capable of interacting with selenium may stabilize the Sec derivatives. This study further suggests that the oxidation-elimination reactions in Sec derivatives could be used for the generation of biologically active selenols having internally stabilizing substituents. 相似文献