One-pot synthesis of trichloromethyl carbinols from primary alcohols

Versatile trichloromethyl carbinols can be prepared in one pot from primary alcohols by treatment with Dess-Martin periodinane (DMP) in CHCl(3) followed by introduction of commercially available 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD). A modification of the method was used to convert chiral primary alcohol (R)-(-)-2,2-dimethyl-1,3-dioxolane-4-methanol to the corresponding trichloromethyl carbinol with complete stereochemical fidelity, despite the reactant proceeding through a base-sensitive aldehyde intermediate.     

A highly selective chemodosimeter for the rapid detection of Hg2+ ions in aqueous media

A novel S,S′-diallyl carbohydrazonodithioate derivative 3 of rhodamine B hydrazone was developed as a chemodosimeter for selective detection of mercury ions based on Hg²⁺ promoted cyclization. The allyl groups of 3 play a key role in the binding and selection of Hg²⁺ ions. The probe responds selectively to Hg²⁺ over various other competitive cations with marked chromo- and fluorogenic changes. The formation of stable oxadiazole derivative 8 was a strong driving force for this high selectivity. Practically, this probe is more promising because of the remarkable high selectivity, faster response, low detection limit, and aqueous solubility of 3.     

Catalysis by Amberlite IR-120 resin: a rapid and green method for the synthesis of phenols from arylboronic acids under metal, ligand, and base-free conditions

A clean process has been developed for the ipso-hydroxylation of aryl and heteroaryl boronic acids to the corresponding phenols using commercially available and recyclable Amberlite IR-120 resin and aqueous hydrogen peroxide as an oxidizing agent. The ion-exchange sulfonic acid resin catalyst could be readily recycled by filtration and directly reused at least four times without any significant loss of activity.     

Time dependent stretching of aging dynamics in a generalized hydrodynamic model for supercooled liquids

The nonequilibrium dynamics and aging behavior of a supercooled liquid is investigated from an analysis of the correlation of density fluctuations at two different times. The dynamic correlation functions are computed by solving numerically the equations of nonlinear fluctuating hydrodynamics. The aging time dependence follows a modified stretched exponential form with a relaxation time which is dependent on the aging time. This is similar to the behavior seen in the aging data of dielectric response functions of a typical glass forming liquid.     

High resolution spectral analysis of oxygen. II. Rotational spectra of a(1)Δ(g) O2 isotopologues

As part of a comprehensive review on molecular oxygen spectroscopy, we have measured rotational spectra of isotopic forms of molecular oxygen in its a(1)Δ(g) electronic state with high-resolution terahertz spectroscopy. The data are recorded in close proximity to predicted positions. Due to the high resolution and good signal-to-noise ratio, the fundamental hyperfine parameters eQq and C(I) are determinable for (17)O-substituted species for the first time. A refined nuclear spin orbit coupling constant, a = -211.9328(283) MHz, was determined, and is roughly two orders of magnitude more precise than values determined from near infrared spectroscopy or electron spin resonance studies. Vibrationally excited oxygen in the a(1)Δ(g) electronic state was also observable with small signal levels for many of the rotational transitions.     

Decomposition of γ-Cyclotrimethylene Trinitramine (γ-RDX): Relevance for Shock Wave Initiation

To elucidate the reactive behavior of RDX crystals at pressures and temperatures relevant to shock wave initiation, Raman spectroscopy and optical imaging were used to determine the pressure-temperature (P-T) stability and the decomposition of γ-RDX, the high pressure phase of RDX. Experiments were performed on single crystals in a diamond anvil cell at pressures from 6 to 12 GPa and at temperatures up to 600 K. Evidence for the direct decomposition of γ-RDX above 6 GPa, without the involvement of other phases, is provided. The upper limit of the P-T locus for the γ-RDX thermal decomposition was determined. A refined P-T phase diagram of RDX is presented that includes the current findings for γ-RDX. The static compression results are used to gain key insight into the shock initiation of RDX, including a determination of the RDX phase at decomposition and understanding the role of pressure and temperature in accelerating shock induced decomposition. This study has established the important role that γ-RDX plays in decomposition of RDX under static and shock compression conditions; thus theoretical modeling of RDX decomposition at high pressures and temperatures needs to incorporate the γ-phase response.     

Some properties of the bivariate lognormal distribution for reliability applications

In this paper, we study the bivariate lognormal distribution from a reliability point of view. The conditional distribution of X given Y > y is found to be log‐skew normal. The monotonicity of the hazard rates of the univariate as well as the conditional distributions is discussed. Clayton's association measure is obtained in terms of the hazard gradient, and its value in the case of our model is derived. The probability distributions, in the case of series and parallel systems, are derived, and the monotonicity of their failure rates is discussed. Three real applications of the bivariate lognormal distribution are provided, two from financial economics and one from reliability. Copyright © 2012 John Wiley & Sons, Ltd.     

COTS selection using fuzzy interactive approach

In this paper, we introduce fuzzy mathematical programming (FMP) for decision-making related to software creation by selecting optimal commercial-off-the-shelf (COTS) products in a modular software system. Each module in such software systems have different alternatives with variations in their properties, for example, quality, reliability, execution time, size and cost. Due to these variations, component-based software developers generally deals with the problem of selecting appropriate COTS products. The development of COTS-based systems largely depends on the success of the selection process. Various crisp optimization models of COTS products selection have been proposed in literature. However, in real COTS products selection problem, it is difficult to estimate precisely the values of various model parameters due to lack of sufficient data and also because of measurement errors. Hence, instead of crisp optimization model, if we use flexible optimization model then we might obtain results which are more preferred by the decision maker. In this study, we use multiple methodologies such as quality model, analytical hierarchy process and FMP to develop fuzzy multiobjective optimization model of the COTS products selection. To determine a preferred compromise solution for the multiobjective optimization problem, an interactive fuzzy approach is used.     

Improved performance of silicon‐nanoparticle film‐coated dye‐sensitized solar cells

Silicon (Si) nanoparticles with average size of 13 nm and orange–red luminescence under UV absorption were synthesized using electrochemical etching of silicon wafers. A film of Si nanoparticles with thickness of 0.75 µm to 2.6 µm was coated on the glass (TiO₂ side) of a dye‐sensitized solar cell (DSSC). The cell exhibited nearly 9% enhancement in power conversion efficiency (η) at film thickness of ～2.4 µm under solar irradiation of 100 mW/cm² (AM 1.5) with improved fill factor and short‐circuit current density. This study revealed for the first time that the Si‐nanoparticle film converting UV into visible light and helping in homogeneous irradiation, can be utilized for improving the efficiency of the DSSCs. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Thermal effect on vibration of non-homogenous visco-elastic rectangular plate of linearly varying thickness

An analysis for vibration of non-homogenous visco-elastic rectangular plate of linearly varying thickness subjected to thermal gradient has been discussed in the present investigation. For visco-elastic, the basic elastic and viscous elements are combined. We have taken Kelvin model for visco-elasticity that is the combination of the elastic and viscous elements in parallel. Here the elastic element means the spring and the viscous element means the dashpot. The governing differential equation of motion has been solved by Galerkin’s technique. Deflection, time period and logarithmic decrement at different points for the first two modes of vibration are calculated for various values of thermal gradients, non homogeneity constant, taper constant and aspect ratio for non-homogenous visco-elastic rectangular plate which is clamped on two parallel edges and simply supported on remaining two edges. Comparison studies have been carried out with homogeneous visco-elastic rectangular plate to establish the accuracy and versatility.