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281.
Zhao H Bhattacharjee S Chow R Wallace D Masliyah JH Xu Z 《Langmuir : the ACS journal of surfaces and colloids》2008,24(22):12899-12910
The dispersion and gelation of clay suspensions have major impact on a number of industries, such as ceramic and composite materials processing, paper making, cement production, and consumer product formulation. To fundamentally understand controlling mechanisms of clay dispersion and gelation, it is necessary to study anisotropic surface charge properties and colloidal interactions of clay particles. In this study, a colloidal probe technique was employed to study the interaction forces between a silica probe and clay basal plane/edge surfaces. A muscovite mica was used as a representative of 2:1 phyllosilicate clay minerals. The muscovite basal plane was prepared by cleavage, while the edge surface was obtained by a microtome cutting technique. Direct force measurements demonstrated the anisotropic surface charge properties of the basal plane and edge surface. For the basal plane, the long-range forces were monotonically repulsive within pH 6-10 and the measured forces were pH-independent, thereby confirming that clay basal planes have permanent surface charge from isomorphic substitution of lattice elements. The measured interaction forces were fitted well with the classical DLVO theory. The surface potentials of muscovite basal plane derived from the measured force profiles were in good agreement with those reported in the literature. In the case of edge surfaces, the measured forces were monotonically repulsive at pH 10, decreasing with pH, and changed to be attractive at pH 5.6, strongly suggesting that the charge on the clay edge surfaces is pH-dependent. The measured force profiles could not be reasonably fitted with the classical DLVO theory, even with very small surface potential values, unless the surface roughness was considered. The surface element integration (SEI) method was used to calculate the DLVO forces to account for the surface roughness. The surface potentials of the muscovite edges were derived by fitting the measured force profiles with the surface element integrated DLVO model. The point of zero charge of the muscovite edge surface was estimated to be pH 7-8. 相似文献
282.
Photoinduced electron transfer between coumarin dyes and N,N-dimethylaniline has been investigated by using steady state and picosecond time resolved fluorescence spectroscopy in sodium dodecyl sulphate (SDS) micelles and PVP-polyvinyl pyrrolidone (SDS) polymer-surfactant aggregates. A slower rate of electron transfer is observed in PVP-SDS aggregates than in polymer-free SDS micelles. A Marcus type inversion is observed in the correlation of free energy change in comparison with the electron transfer rate. The careful investigation reveals that C-151 deviates from the normal Marcus inverted region compared to its analogs C-152 and C-481 due to slower rotational relaxation and smaller translational diffusion coefficient. 相似文献
283.
S. B.?SinghaEmail author J. K.?Bhattacharjee A. K.?Ray 《The European Physical Journal B - Condensed Matter and Complex Systems》2005,48(3):417-426
In the presence of viscosity the hydraulic jump in one
dimension is seen to be a first-order transition. A scaling relation
for the position of the jump has been determined by applying an
averaging technique on the stationary hydrodynamic equations. This
gives a linear height profile before the jump, as well as a clear
dependence of the magnitude of the jump on the outer boundary
condition. The importance of viscosity in the jump formation has been
convincingly established, and its physical basis has been understood
by a time-dependent analysis of the flow equations. In doing so, a
very close correspondence has been revealed between a perturbation
equation for the flow rate and the metric of an acoustic white hole.
We finally provide experimental support for our heuristically
developed theory. 相似文献
284.
Electromagnetic particle-in-cell simulations of fast collisionless reconnection in a two-dimensional electron-positron plasma (without an equilibrium guide field) are presented. A generalized Ohm's law in which the Hall current cancels out exactly is given. It is suggested that the key to fast reconnection in this plasma is the localization caused by the off-diagonal components of the pressure tensors, which produce an effect analogous to a spatially localized resistivity. 相似文献
285.
Abazov VM Abbott B Abolins M Acharya BS Adams DL Adams M Adams T Agelou M Agram JL Ahmed SN Ahn SH Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Anderson S Andrieu B Arnoud Y Askew A Asman B Atramentov O Autermann C Avila C Babukhadia L Bacon TC Badaud F Baden A Baffioni S Baldin B Balm PW Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Beauceron S Beaudette F Begel M Bellavance A Beri SB Bernardi G Bernhard R Bertram I 《Physical review letters》2005,94(4):042001
Using the exclusive decay B0s-->J/psi(mu+mu-)phi(K+K-), we report the most precise single measurement of the B0s lifetime. The data sample corresponds to an integrated luminosity of approximately 220 pb(-1) collected with the D0 detector at the Fermilab Tevatron Collider in 2002-2004. We reconstruct 337 signal candidates, from which we extract the B0s lifetime, tau(B0s)=1.444(+0.098)(-0.090)(stat)+/-0.020(sys) ps. We also report a measurement for the lifetime of the B0 meson using the exclusive decay B0-->J/psi(mu+mu-)K*0(892)(K+pi-). We reconstruct 1370 signal candidates, obtaining tau(B0)=1.473(+0.052)(-0.050)(stat)+/-0.023(sys) ps, and the ratio of lifetimes, tau(B0s)/tau(B0)=0.980(+0.076)(-0.071)(stat)+/-0.003(sys). 相似文献
286.
Bhattacharjee SM 《Physical review letters》1996,76(24):4568-4571
287.
Abachi S Abbott B Abolins M Acharya BS Adam I Adams DL Adams M Ahn S Aihara H Alitti J Álvarez G Alves GA Amidi E Amos N Anderson EW Aronson SH Astur R Avery RE Baden A Balamurali V Balderston J Baldin B Bantly J Bartlett JF Bazizi K Bendich J Beri SB Bertram I Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Bischoff A Biswas N Blazey G Blessing S Bloom P Boehnlein A Bojko NI Borcherding F Borders J Boswell C Brandt A Brock R Bross A Buchholz D Burtovoi VS Butler JM Carvalho W Casey D 《Physical review letters》1996,76(13):2228-2233
288.
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