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261.
262.
Surface Enhanced Raman Spectra (SERS) of 2-methylthiophene (2-MT) and 3-methylthiophene (3-MT) in silver colloid are compared with their normal Raman spectra in the bulk and in acetonitrile solution. Experimental results indicate that both the methylthiophene molecules are adsorbed on a metal surface through the sulfur atom. Assuming the image dipole theory to be valid, the observed surface enhancement factor of the C-H stretching mode in 2-MT indicates that the C-H bond of this isomer makes an angle of 51 degrees with the surface normal. The experimental results further suggest that the 3-MT molecule is adsorbed with its ring plane almost vertical to the metal surface; the 2-MT molecule, on the other hand, is tilted more than 45 degrees to the surface normal. The concentration dependence of the relative enhancement factor indicates that a monomolecular layer is formed on the metal surface at a specific concentration of the methylthiophenes in silver sol. No oligomerization of the two methylthiophenes on the silver surface is observed. Copyright 1999 Academic Press. 相似文献
263.
Chakraborty D Chandrasekhar V Bhattacharjee M Krätzner R Roesky HW Noltemeyer M Schmidt HG 《Inorganic chemistry》2000,39(1):23-26
Reactions of Ph2P(O)(OH) and t-BuP(O)(OSiMe3)(OH) with Ti(O-i-Pr)4 in equimolar ratios gave titanium phosphonates of the type [(O-i-Pr)3Ti(mu-O)2PR1R2]2 (1, R1 = R2 = Ph; 2, R1 = t-Bu, R2 = OSiMe3) as colorless crystalline solids in moderate yields. Reactions of Ph2P(O)(OH) and the isopropoxides of zirconium and hafnium resulted in products of the composition [(O-i-Pr)3M(mu-O-i-Pr)2(mu-OPOPh2)M(O-i-Pr)2]Ph2P(O)(OH) (M = Zr (3), Hf (4)) in high yields. The compounds were characterized by 1H, 31P, and 29Si NMR, infrared (IR), and mass spectroscopic (MS) techniques. The molecular structures of 2 and 3 were confirmed by X-ray crystallography. 相似文献
264.
Jayeeta Bhattacharjee Alok Sarkar Tarun K. Panda 《Current Opinion in Green and Sustainable Chemistry》2021
This article reports the synthesis of a series of alkali metal complexes with diverse multi-dentate ligands. The sodium and potassium complexes show excellent activity in the ring-opening polymerization of ε-CL and δ-VL and rac-Lactide. 相似文献
265.
Vasanthi Palanisamy Palash Sanphui Muthuramalingam Prakash Vladimir Chernyshev 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(8):1102-1117
Lesinurad (systematic name: 2‐{[5‐bromo‐4‐(4‐cyclopropylnaphthalen‐1‐yl)‐4H‐1,2,4‐triazol‐3‐yl]sulfanyl}acetic acid, C17H14BrN3O2S) is a selective uric acid reabsorption inhibitor related to gout, which exhibits poor aqueous solubility. High‐throughput solid‐form screening was performed to screen for new solid forms with improved pharmaceutically relevant properties. During polymorph screening, we obtained two solvates with methanol (CH3OH) and ethanol (C2H5OH). Binary systems with caffeine (systematic name: 3,7‐dihydro‐1,3,7‐trimethyl‐1H‐purine‐2,6‐dione, C8H10N4O2) and nicotinamide (C6H6N2O), polymorphs with urea (CH4N2O) and eutectics with similar drugs, like allopurinol and febuxostat, were prepared using the crystal engineering approach. All these novel solid forms were confirmed by XRD, DSC and FT–IR. The crystal structures were solved by single‐crystal and powder X‐ray diffraction. The crystal structures indicate that the lesinurad molecule is highly flexible and the triazole moiety, along with the rotatable thioacetic acid (side chain) and cyclopropane ring, is almost perpendicular to the planar naphthalene moiety. The carboxylic acid–triazole heterosynthon in the drug is interrupted by the presence of methanol and ethanol molecules in their crystal structures and forms intermolecular macrocyclic rings. The caffeine cocrystal maintains the consistency of the acid–triazole heterosynthons as in the drug and, in addition, they are bound by several auxiliary interactions. In the binary system of nicotinamide and urea, the acid–triazole heterosynthon is replaced by an acid–amide synthon. Among the urea cocrystal polymorphs, Form I (P, 1:1) consists of an acid–amide (urea) heterodimer, whereas in Form II (P21/c, 2:2), both acid–amide heterosynthons and urea–urea dimers co‐exist. Density functional theory (DFT) calculations further support the experimentally observed synthon hierarchies in the cocrystals. Aqueous solubility experiments of lesinurad and its binary solids in pH 5 acetate buffer medium indicate the apparent solubility order lesinurad–urea Form I (43‐fold) > lesinurad–caffeine (20‐fold) > lesinurad–allopurinol (12‐fold) ? lesinurad–nicotinamide (11‐fold) > lesinurad, and this order is correlated with the crystal structures. 相似文献
266.
Gupta Kalyan K. Sen Bhattacharjee Nandini Pal Biswajit Ghosh Saktiprosad 《Transition Metal Chemistry》1999,24(3):268-273
The kinetics of oxidation of the neutralized -hydroxy acids: lactic, -hydroxyisobutyric, mandelic, benzilic and atrolactic acids by tris(pyridine-2-carboxylato)manganese(III) have been studied. The reactions were carried out in a Na(pic)-picH [Na(pic) = sodium salt of pyridine-2-carboxylic acid and picH = pyridine-2-carboxylic acid] buffer medium in the 4.89–6.10pH range. The oxidation rate was found to be independent of pH, and rate follows the order: benzilate > mandelate >atrolactate>lactate > -hydroxy isobutyrate. The oxidation products are MeCHO, Me2CO, PhCHO, Ph2CO and PhCOMe for the respective reactions. A mechanism is proposed involving intermediate formation of hepta-coordinated MnIII complexes in a fast step. The complexes then decompose to give free radicals and MnII in the rate determining step. The free radicals subsequently react with another molecule of the MnIII species to give the respective carbonyl compounds in a fast step. 相似文献
267.
Reissert compounds have been prepared from 1,7-, 4,6-, and 4,7-phenanthrolines. In the case of 4,7-phenanthroline, both mono- and di-Reissert compounds have been prepared. A number of Reissert analogs have also been prepared in this series. 1,10-Phenanthroline fails to give a Reissert compound. 相似文献
268.
A fully statistical kernel describing the probability of energy transfer in collisions between polyatomic reactant (A) and heat bath (M) molecules in a thermal system is developed, proceeding through the formation of an intermediate collision complex (AM) whose internal degrees of freedom are assumed to exchange energy. After pointing out that this kernel does not give a quantitatively useful answer, the kernel is modified by introducing the concept that the collision complex lifetime is due to orbiting collisions, and that the (AM) lifetime must equal collision duration. This puts two constraints on the internal degrees of freedom of (AM): (1) those that correlate with relative translation and intrinsic rotation of separated A and M (= transitional modes) can contain only an amount of energy not exceeding E*, which is the maximum energy for which orbiting can occur; (2) those that correlate with internal degrees of freedom of M must have a density of states such that, subject to constraint (1), the lifetime of (AM) is equal to collision duration. It turns out, quite unambiguously, that the appropriate density of states is equivalent to just one oscillator of M participating in energy exchange. Calculations of average amount of energy transferred (Δ E>) in the system CH3NC + M show good quantitative agreement with experiment for both polar and non-polar M. The modified theory does not give any appreciable dependence of Δ E> on the size of M because collision duration is assumed to depend only on the long-range part of the potential. 相似文献
269.
Reaction of quinazoline with trimethylsilyl cyanide and benzoyl chloride gave 2,4-dicyano-1,3-dibenzoyl-1,2,3,4-tetrahydroquinazoline as the major product. This compound undergoes monoalkylation with methyl iodide in the presence of sodium hydride. Reaction of cinnoline with trimethylsilyl cyanide and benzoyl chloride gave 1,2-dibenzoyl-4-cyano-1,2-dihydrocinnoline. 相似文献