全文获取类型
收费全文 | 615篇 |
免费 | 18篇 |
国内免费 | 3篇 |
专业分类
化学 | 302篇 |
晶体学 | 10篇 |
力学 | 8篇 |
数学 | 38篇 |
物理学 | 278篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 9篇 |
2019年 | 16篇 |
2018年 | 14篇 |
2017年 | 10篇 |
2016年 | 15篇 |
2015年 | 10篇 |
2014年 | 20篇 |
2013年 | 53篇 |
2012年 | 28篇 |
2011年 | 44篇 |
2010年 | 18篇 |
2009年 | 29篇 |
2008年 | 26篇 |
2007年 | 28篇 |
2006年 | 26篇 |
2005年 | 25篇 |
2004年 | 13篇 |
2003年 | 9篇 |
2002年 | 18篇 |
2001年 | 11篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 9篇 |
1997年 | 4篇 |
1996年 | 17篇 |
1995年 | 17篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 13篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1986年 | 5篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 15篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1978年 | 8篇 |
1977年 | 2篇 |
1975年 | 4篇 |
1960年 | 1篇 |
1958年 | 1篇 |
1938年 | 2篇 |
排序方式: 共有636条查询结果,搜索用时 32 毫秒
131.
132.
First principles electronic structure calculations have been performed for the double perovskite Bi(2)CoMnO(6) in its non-centrosymmetric polar state using the generalized gradient approximation plus the Hubbard U approach. We find that the ferromagnetic state is more favored compared to the ferrimagnetic state with both Co and Mn in high spin states. The calculated dynamical charge tensors are anisotropic reflecting a low-symmetry structure of the compound. The magnetic structure dependent phonon frequencies indicate the presence of a weak spin-phonon coupling. Using the Berry phase method, we obtain a spontaneous ferroelectric polarization of 5.88?μC?cm(-2), which is close to the experimental value observed for a similar compound, Bi(2)NiMnO(6). 相似文献
133.
Bhattacharjee S Dong J Ma Y Hovde S Geiger JH Baker GL Bruening ML 《Langmuir : the ACS journal of surfaces and colloids》2012,28(17):6885-6892
Layer-by-layer polyelectrolyte adsorption is a simple, convenient method for introducing ion-exchange sites in porous membranes. This study demonstrates that adsorption of poly(acrylic acid) (PAA)-containing films at pH 3 rather than pH 5 increases the protein-binding capacity of such polyelectrolyte-modified membranes 3-6-fold. The low adsorption pH generates a high density of -COOH groups that function as either ion-exchange sites or points for covalent immobilization of metal-ion complexes that selectively bind tagged proteins. When functionalized with nitrilotriacetate (NTA)-Ni(2+) complexes, membranes containing PAA/polyethylenimine (PEI)/PAA films bind 93 mg of histidine(6)-tagged (His-tagged) ubiquitin per cm(3) of membrane. Additionally these membranes isolate His-tagged COP9 signalosome complex subunit 8 from cell extracts and show >90% recovery of His-tagged ubiquitin. Although modification with polyelectrolyte films occurs by simply passing polyelectrolyte solutions through the membrane for as little as 5 min, with low-pH deposition the protein binding capacities of such membranes are as high as for membranes modified with polymer brushes and 2-3-fold higher than for commercially available immobilized metal affinity chromatography (IMAC) resins. Moreover, the buffer permeabilities of polyelectrolyte-modified membranes that bind His-tagged protein are ~30% of the corresponding permeabilities of unmodified membranes, so protein capture can occur rapidly with low-pressure drops. Even at a solution linear velocity of 570 cm/h, membranes modified with PAA/PEI/PAA exhibit a lysozyme dynamic binding capacity (capacity at 10% breakthrough) of ~40 mg/cm(3). Preliminary studies suggest that these membranes are stable under depyrogenation conditions (1 M NaOH). 相似文献
134.
Nivedita Singh Akhansha Nayyar G. Bhattacharjee A. K. Singh Vikas Pruthi 《Applied biochemistry and biotechnology》2012,167(6):1688-1698
The invasion of opportunistic pleiomorphic Candida albicans into oral cavity environment leads to development and progression of its resistance to both naturally occurring antifungal peptides in human saliva as well as commercially available antifungal therapies. As a result of this, the usage and popularity of natural medicine and dentifrices had increased significantly in the last decade. In the present investigation, we have assessed the action of locally available dentifrices against C. albicans biofilm. Disk diffusion test showed maximum zone of inhibition (20?mm) by herbal dentifrice (D-5) as compared to other dentifrices when incubated at 37?°C and 48?h. Assessment of dentifrice D-5 for its effectiveness against C. albicans was further shown in MIC90 (3.12?mg?mL?1) and SMIC90 (6.2?mg?mL?1) values for planktonic and sessile cells (biofilm forming), respectively. Our data depicted 80% reduction in the cell surface hydrophobicity when 6.2?mg?mL?1 of herbal dentifrice D-5 was used against 48-h grown Candida biofilm at 37?°C. Visualization of herbal dentifrice D-5-treated C. albicans biofilm under SEM revealed drastic reduction in the dense network of yeast, hyphae, and pseudohyphae enclosed in its ECM as compared to its control biofilm. The data were further supported by CLSM analysis which depicted C. albicans architecture disruption by herbal dentifrices. From the above data, it is inferred that these studies would provide researchers and medical practitioners with better insight into the antifungal effect of natural herbal dentifrices. 相似文献
135.
Bhattacharjee A Chavarot-Kerlidou M Andreiadis ES Fontecave M Field MJ Artero V 《Inorganic chemistry》2012,51(13):7087-7093
A combined theoretical and experimental approach has been employed to characterize the hydrido-cobaloxime [HCo(dmgH)(2)(PnBu(3))] compound. This complex was originally investigated by Schrauzer et al. [Schrauzer et al., J. Am. Chem. Soc. 1971, 93,1505] and has since been referred to as a key, stable analogue of the hydride intermediate involved in hydrogen evolution catalyzed by cobaloxime compounds [Artero, V. et al. Angew. Chem., Int. Ed. 2011, 50, 7238-7266]. We employed quantum chemical calculations, using density functional theory and correlated RI-SCS-MP2 methods, to characterize the structural and electronic properties of the compound and observed important differences between the calculated (1)H NMR spectrum and that reported in the original study by Schrauzer and Holland. To calibrate the theoretical model, the stable hydrido tetraamine cobalt(III) complex [HCo(tmen)(2)(OH(2))](2+) (tmen = 2,3-dimethyl-butane-2,3-diamine) [Rahman, A. F. M. M. et al. Chem. Commun. 2003, 2748-2749] was subjected to a similar analysis, and, in this case, the calculated results agreed well with those obtained experimentally. As a follow-up to the computational work, the title hydrido-cobaloxime compound was synthesized and recharacterized experimentally, together with the Co(I) derivative, giving results that were in agreement with the theoretical predictions. 相似文献
136.
Flexural gravity wave scattering by multiple articulated floating elastic plates is investigated in the three cases for water of finite depth, infinite depth and shallow water approximation under the assumptions of two-dimensional linearized theory of water waves. The elastic plates are joined through connectors, which act as articulated joints. In the case when two semi-infinite plates are connected through a single articulation, using the symmetric characteristic of the plate geometry and the expansion formulae for wave-structure interaction problem, the velocity potentials are obtained in closed forms in the case of finite and infinite water depths. On the other hand, in the case of shallow water approximation, the continuity of energy and mass flux are used to obtain a system of equations for the determination of the full velocity potentials for wave scattering by multiple articulations. Further, using the results for single articulation and assuming that the articulated joints are wide apart, the wide-spacing approximation method is used to obtain the reflection coefficient for wave scattering due to multiple articulated floating elastic plates. The effects of the stiffness of the connectors, length of the elastic plates and water depth on the propagation of flexural gravity waves are investigated by analysing the reflection coefficient. 相似文献
137.
138.
K. A. V. David S. S. Rane Manjula Mathur S. K. Bhattacharjee 《Photochemistry and photobiology》1988,47(1):107-113
Abstract— The role of the replicative state of DNA and of the photosynthetic electron transport system in determining UV-sensitivity of A. nidulans under conditions of non-photoreactivation (by incubating the cells for 24 h in the dark following UV-irradiation) has been investigated. Both the DNA synthesis data and the data on survival levels during cell cycle synchrony forced by light to dark and dark to light transitions showed that the differential UV-sensitivity was not correlated with the replicative state of the DNA as suggested earlier. However, incubation in the light with the herbicides 2/3-4, dichlorophenyl/-l, 1-dimethyl urea (DCMU) and 2-chloro-4-ethylamino-6-isopropylamino-s-triazine (atrazine) which are known to inhibit electron transport by specifically binding to the high turnover B protein of photosynthetic electron transport system II (PSII), enhanced the UV-resistance with kinetics similar to those of a culture transferred from light to dark. We interpret this result as implicative of PSII as the second lethal target in the case of cyanobacteria. The inactivation of electron transport activity of PSII as measured by the fall in DCMU-sensitive fluorescence yield during post-UV dark incubation supports this hypothesis. It is proposed that in wild type cells the survival under conditions of non-photoreactivation following UV-irradiation is essentially determined by the level of dark-repair of damage to PSII and that the 32 kD B protein may have a role in dark-repair of damage to the electron transport system. This hypothesis explains the paradox of negative liquid holding recovery phenomenon under conditions which promote excision-repair of damaged DNA in cyanobacteria. 相似文献
139.
K. K. Bhattacharjee J. Subramanian D. P. Santry J. -H. Fuhrhop 《Journal of Chemical Sciences》1986,97(5-6):601-606
The influence of metal ion on the oxidation and ionisation potentials of metalloporphyrins is investigated by the simple electrostatic
model using SCF perturbation theory. The zero order wavefunctions are obtained from PPP and CNDO/2 methods. The wide variations
in redox potentials with metal and the relative insensitivity of the optical transitions with metal are very well accounted
for by the perturbation approach. 相似文献
140.
D. K. Bhattacharjee D. K. Maity P. J. Cherian 《Zeitschrift fur Physik C Particles and Fields》1991,52(2):265-269
We have analysed ourpn data at 400 GeV (corresponding to a centre-of-mass energy \(\sqrt s = 27.5\) GeV) together with otherpp and \(p\bar p\) data in the centre of mass energy range 11.5–900 GeV. The fits of all these distributions to a negative binomial distribution are performed. The variations in the fitted average multiplicity and in the inverse of the fitted parameterk are obtained with respect to the centre of mass energy. An assessment of the single diffractive component in the multiplicity distribution is made and its variation with the centre of mass energy discussed. The average number of clans and the average charged multiplicity per clan are determined and the centre of mass energy dependences shown. 相似文献