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461.
An abc-permutation is a permutation σ abc S n obtained by exchanging an initial block of length a and a final block of length c of {1,…,n}, where n=a+b+c. In this note we compute the limit of the probability that a random abc-permutation is a long cycle. This resolves Arnold’s open problem (Arnold in Arnold’s problems, 2004, p. 144).   相似文献   
462.
We present a much simplified proof of Dehn’s theorem on the infinitesimal rigidity of convex polytopes. Our approach is based on the ideas of Trushkina [1] and Schramm [2].  相似文献   
463.
We report on measurements of directed flow as a function of pseudorapidity in Au + Au collisions at energies of square root of SNN = 19.6, 62.4, 130 and 200 GeV as measured by the PHOBOS detector at the BNL Relativistic Heavy Ion Collider. These results are particularly valuable because of the extensive, continuous pseudorapidity coverage of the PHOBOS detector. There is no significant indication of structure near midrapidity and the data surprisingly exhibit extended longitudinal scaling similar to that seen for elliptic flow and charged particle pseudorapidity density.  相似文献   
464.
金融市场中经纪人相互竞争和适应性行为的物理模型   总被引:1,自引:0,他引:1  
全宏俊  汪秉宏  许伯铭 《物理》2001,30(10):606-611
金融物理中的争当少数者博奕模型,是一个用来模拟金融市场动力学行为的最简单的模型,可以尝试利用它来对实际金融市场中许多现象提供物理的理解.文章介绍了关于金融物理的争当少数者博奕模型的一些主要研究结果和若干最新的发展方向.  相似文献   
465.
The problem of interpretation of hotwire measurements of acoustic fields in compressible flows is considered. Relations between massflow and totaltemperature fluctuations registered by a hotwire anemometer and pressure and velocity fluctuations are found. The relations obtained are applicable in the general case for measurement of resultant acoustic fluctuations at some point of the flow, which are generated by arbitrary distributed sources of sound with priorunknown properties.  相似文献   
466.
We review our theoretical work done on a variety of different chemical systems, which show different H-bonding characteristics. The systems include water clusters, its interactions with polar molecules and π-systems, organic nanotubes, enzymes, and ionophores/receptors. Special features of normal, short, short strong, and π-type H-bonding interactions in these systems are discussed in terms of structures, interaction energies, and spectra.  相似文献   
467.
    
The electrochemical oxidation of catechol (=benzene‐1,2‐diol; 1a ) and some of its derivatives in H2O/MeCN 1 : 1 containing benzoylacetonitrile (=β‐oxobenzenepropanenitrile; 3 ) as a nucleophile was studied by cyclic voltammetry and controlled‐potential coulometry. The voltammetric data showed that electrochemically generated o‐benzoquinones (=cyclohexa‐3,5‐diene‐1,2‐diones) from catechol ( 1a ) and 3‐methylcatechol ( 1b ) participate in a Michael‐addition reaction with 3 to form the corresponding 5,6‐dihydroxybenzofuran‐3‐carbonitrile 8 (Scheme 1). In this work, we report an efficient one‐pot method with high atom economy for the synthesis of new substituted 5,6‐dihydroxybenzofuran‐3‐carbonitriles in an undivided cell under ambient conditions.  相似文献   
468.
    
S‐Alkylated cysteines are used as efficient tridentate N,O,S‐donor‐atom ligands for the fac‐[M(CO)3]+ moiety (M=99mTc or Re). Reaction of (Et4N)2[ReBr3(CO)3] ( 3 ) with the model S‐benzyl‐L ‐cysteine ( 2 ) leads to the formation of [Re( 2′ )(CO)3] ( 4 ) as the exclusive product ( 2′ =C‐terminal anion of 2 ). The tridentate nature of the alkylated cysteine in 4 was established by X‐ray crystallography. Compound 2 reacts with [99mTc(OH2)3(CO)3]+ under mild conditions (10−4 M , 50°, 30 min) to afford [99mTc( 2′ )(CO)3] ( 5 ) and represents, therefore, an efficient chelator for the labelling of biomolecules. L ‐Cysteine, S‐alkylated with a 3‐aminopropyl group (→ 7 ), was conjugated via a peptide coupling sequence with Coα‐[α‐(5,6‐dimethyl‐1H‐benzimidazolyl)]‐Coβ‐cyanocobamic b‐acid ( 6 ), the b‐acid of cyanocob(III)alamin (vitamin B12) (Scheme 3). More convenient was a one‐pot procedure with a derivative of vitamin B12 comprising a free amine group at the b‐position. This amine 15 was treated with NHS (N‐hydroxysuccinimide)‐activated 1‐iodoacetic acid 14 to introduce an I‐substituent in vitamin B12. Subsequent addition of unprotected L ‐cysteine resulted in nucleophilic displacement of the I‐atom by the S‐substituent, affording the vitamin B12 alkylated cysteine fragment 17 (Scheme 4). The procedure was quantitative and did not require purification of intermediates. Both cobalamin–cysteine conjugates could be efficiently labelled with [99mTc(OH2)3(CO)3]+ ( 1 ) under conditions identical to those of the model complex 5 . Biodistribution studies of the cobalamin conjugates in mice bearing B10‐F16 melanoma tumors showed a tumor uptake of 8.1±0.6% and 4.4±0.5% injected dose per gram of tumor tissue after 4 h and 24 h, respectively (Table 1).  相似文献   
469.
Nuclear-purity uranium was refined by passing a solution of uranyl nitrate in 3–5 M HNO3 in succession through pulsed extraction, washing, and stripping columns for feeding into the U(III)–U(IV) chemical exchange system for uranium isotope separation. The extractant (tri-n-butyl phosphate, TBP), the diluent (kerosene), nitric acid, ammonium carbonate, sodium nitrate, and water were preliminarily refined to chemical purity. The diameter and height of pulsed columns for uranium purification was 25 and 1500 mm, respectively, and the pulse frequency was 1 s–1. The content of transition metals (Fe, Co, Ni, Cu, Ag) and Pb, which can catalyze the U(III) oxidation in acidic aqueous solutions, was reduced to the level lower than 1 ppm (10–4%). The total purification factor was higher than 103. The purification required 3–4 theoretical plates with HETP of the columns of 35–40 cm.  相似文献   
470.
The propagation of an ultrashort optical pulse in the multilayered structure formed by alternating graphene and boron nitride layers is considered. Conduction electrons of this system at low temperatures are described by the effective long-wavelength Hamiltonian, and the electromagnetic field is considered based on the classical Maxwell equations. Dependence of the evolution on the ultrashort pulse amplitude and nanoribbon layer width is established.  相似文献   
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