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51.
Dominant strategy mechanisms for contract auctions with risk aversion and moral hazard 总被引:1,自引:0,他引:1
Frank H. Page Jr. 《International Journal of Game Theory》1994,23(1):25-42
Within the class dominant strategy incentive compatible mechanisms, we show that there exists an optimal contracting mechanism for the principal for a version of the incomplete information principal-agent problem in which several agents compete for a contract and the principal selects an agent via a contract auction. In our auction model, we assume that the principal and the agents are risk averse, and we allow for uncountably many agent types. We also assume that the principal's probability measure over type profiles in such that correlation between agent's types is possible. Thus, we do not require that agents' types be independently distributed. Finally, we impose limited liability constraints upon the set of contracts. Due to the nature of the individual rationality and incentive compatibility constraints, the existence problem is nonstandard and novel existence arguments are required. We prove existence using a measurable selection result and a new notion of compactness called K-compactness. 相似文献
52.
Mutations involved in many cancers have been identified, but with some cancers requiring six or more mutations to take on their fully metastatic forms, the question remains whether all of these mutations can be acquired via a process of successive mutation, at a normal rate, and clonal expansion or whether heightened mutation rates are required. This issue has been debated for decades. Recently there has been much interest in forms of genomic instability such as chromosomal instability and microsatellite instability. It remains to definitively show whether or not these instabilities are very early causal events in tumorigenesis. This article reviews the evidence for and against genomic instability being an early causal event in tumorigenesis and surveys the mathematical modelling literature in this area. The focus is on chromosomal instability and microsatellite instability in colorectal cancer. 相似文献
53.
Mazzocchi C Grzywacz R Liddick SN Rykaczewski KP Schatz H Batchelder JC Bingham CR Gross CJ Hamilton JH Hwang JK Ilyushkin S Korgul A Królas W Li K Page RD Simpson D Winger JA 《Physical review letters》2007,98(21):212501
An alpha-decay branch of (1.4+/-0.4) x 10(-4) has been discovered in the decay of 109I, which predominantly decays via proton emission. The measured Q(alpha) value of 3918+/-21 keV allows the indirect determination of the Q value for proton emission from 105Sb of 356+/-22 keV, which is approximately of 130 keV more bound than previously reported. This result is relevant for the astrophysical rapid proton-capture process, which would terminate in the 105Sn(p,gamma)106Sb(p,gamma)107Te(alpha decay)103Sn cycle at the densities expected in explosive hydrogen burning scenarios, unless unusually strong pairing effects result in a 103Sn(p,gamma)104Sb(p,gamma)105Te(alpha decay)101Sn) cycle. 相似文献
54.
Tuning the energy gap of conjugated polymer zwitterions for efficient interlayers and solar cells 下载免费PDF全文
Zachariah A. Page Feng Liu Thomas P. Russell Todd Emrick 《Journal of polymer science. Part A, Polymer chemistry》2015,53(2):327-336
Narrow band gap conjugated polymer zwitterions (CPZs) were synthesized by Suzuki polymerization and characterized to understand their electronic properties and utility as cathode modification layers in solar cells. The polymers were prepared from diketopyrrolopyrrole (DPP) and iso-indigo monomers containing sulfobetaine (SB) pendant groups, benefiting from an ion-rich aqueous phase in the polymerizations. UV–vis absorption spectroscopy revealed the optical energy gap value for the CPZs, ranging from 1.7 to 1.2 eV. Ultraviolet photoelectron spectroscopy of the CPZs as thin layers on Ag metal showed that the pendent zwitterions impart an interfacial dipole (Δ) to the metal and a work function reduction of ∼0.9 eV. OPVs fabricated using a conventional bulk heterojunction (BHJ) device architecture of ITO/PEDOT:PSS/(PTB7:PC71BM)/CPZ/Ag led to dramatic improvements in power conversion efficiency (PCE) values relative to devices having bare Ag cathodes (PCE < 2% for bare Ag vs. 6.7–7.7% for CPZ/Ag). The benzothiadiazole (BT)/DPP polymer denoted as PT2BTDPPSB gave an optimal PCE of 7.7% in a conventional BHJ OPV device architecture fabricated on a Ag cathode. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 327–336 相似文献
55.
Microprojectile methods of genetic engineering sometimes employ a macroprojectile which launches the microprojectiles when it hits a stopping plate. A study has been made of the relationship between the velocities of the macroprojectile and the microprojectile it launches. Macroprojectile velocities were measured using a beam blanking method and the microprojectile velocities were measured with a laser Doppler anemometer. Particles of tungsten, titanium dioxide and silicon carbide were investigated as microprojectiles. The microprojectile velocity was found to depend not only on the macroprojectile velocity but also on the microprojectile size and material, the bond strength with the macroprojectile and the gas flow that develops ahead of the macroprojectile. On average the microprojectile launch velocity was similar to the macroprojectile velocity. However, some tungsten particles had velocities twice this value. Experimental evidence suggests that these higher velocities were caused by early break-way of particles from the macroprojectile followed by further acceleration by aerodynamic drag arising from the gas flow ahead of the macroprojectile.We are especially grateful for the advice of Dr. M. Gharib on the use of the HSI color system. John Lyons provided expert help in the laboratory and materials for and advice on photography. We thank the staff of the SIO Hydraulics Laboratory for making the wind-wave channel available for our use, and the staff of UCSD library for enabling us to use the Barneyscanner photometer-digitizer. We thank an anonymous reviewer who pointed out a numerical error and improved the clarity of the text. 相似文献
56.
It has been reported that the introduction of a dielectric barrier between adjacent digits of an interdigitated electrode array can improve the sensitivity of the array as an electrochemical impedance biosensor. Here we present an in‐depth analysis of the impedance in planar interdigitated electrodes and 3‐D interdigitated electrodes (with dielectric barriers). The analysis indicates that the planar geometry not only provides lower impedance but also a higher change impedance as a result of molecular immobilization on the electrode array surface. 相似文献
57.
Jeffs L Arquier D Kariuki B Bethell D Page PC Hutchings GJ 《Organic & biomolecular chemistry》2011,9(4):1079-1084
By synthesising S-2-phenyl-N-(4-nitrophenyl)aziridine from S-phenylglycinol, it has been demonstrated that the aziridination of styrene by [N-(4-nitrobenzenesulfonyl)imino]phenyliodinane (nosyliminophenyliodinane, PhINNs) in the presence of S,S-2,2'-isopropylidene-bis(4-phenyl-2-oxazoline), catalysed by copper(II) triflate in CH(3)CN solution or heterogeneously by CuHY, has predominantly an R-configuration. The enantioselectivity of the aziridination of styrene by [N-arenesulfonylimino]-phenyliodinanes catalysed by copper-exchanged zeolite Y (CuHY), in conjunction with a chiral bis-oxazoline ligand, has been re-examined. In the case of PhINNs, it is shown that the product mixture of enantiomeric aziridines, on treatment with hexane, gives rise to a solid phase of low enantiomeric excess (ee) and a solution phase of high ee. Separation of the solid phase and recrystallisation afforded a true racemate (racemic compound), which has been confirmed by X-ray crystallography. The aziridine obtained from the solution phase could be recrystallised to produce the pure enantiomer originally in excess. A consequence of the new findings is that previous reports on the enantioselectivity of copper-catalysed aziridination, both in heterogeneous and homogeneous conditions, should be regarded with caution if the analytical procedure involved HPLC with injection of the enantiomeric mixture in a hexane-rich solvent. Such a method has been used in previous work from this laboratory, but has also been used elsewhere, following the procedure developed by Evans and co-workers when the (homogeneous) copper-catalysed aziridination by PhINTs was first discovered. Evidently, the change of substituent in the benzenesulfonyl group reduces the solubility in hexane, affording a solution phase of enhanced ee. 相似文献
58.
Page MJ Mahon MF Whittlesey MK 《Dalton transactions (Cambridge, England : 2003)》2011,40(31):7858-7865
Thermolysis of [Ru(PPh(3))(dppe)(CO)HCl] (dppe = 1,2-bis(diphenylphosphino)ethane) with the N-heterocyclic carbenes I(i)Pr(2)Me(2) (1,3-diisopropyl-4,5-dimethyl-imidazol-2-ylidene), IEt(2)Me(2) (1,3-diethyl-4,5-dimethyl-imidazol-2-ylidene) or ICy (1,3-dicyclohexylimidazol-2-ylidene) gave the cyclometallated carbene complexes [Ru(NHC)'(dppe)(CO)H] (NHC = I(i)Pr(2)Me(2), 4; IEt(2)Me(2), 5; ICy, 6). Dissolution of 4 in CH(2)Cl(2) or CHCl(3) gave the trans-Cl-Ru-P complex [Ru(I(i)Pr(2)Me(2))'(dppe)(CO)Cl] (7), which converted over hours at room temperature to the trans-Cl-Ru-CO isomer 7'. Chloride abstraction from 7 by NaBPh(4) under an atmosphere of H(2) produced the cationic mono-hydride complex [Ru(I(i)Pr(2)Me(2))(dppe)(CO)H][BPh(4)] (9), which could also be formed by protonating 4 with 1 eq HBF(4)·OEt(2). Treatment of 4 with excess HBF(4)·OEt(2) followed by extraction into MeCN produced the dicationic acetonitrile complex [Ru(I(i)Pr(2)Me(2))(dppe)(CO)(NCMe)(2)][BF(4)](2) (10). The structures of 6, 7, 7' and 10 have been determined by X-ray crystallography. 相似文献
59.
Edwards HG Herschy B Page K Munshi T Scowen IJ 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(1):191-195
The aim of this work is to investigate the viability and potential of three groups of organic compounds as biomarkers in a future robotic analytical exploration of Mars. The three compounds have been identified as suitable candidates for potential biomarkers for extant or extinct life from the terrestrial fossil record. The three groups of compound were all similar in structure, being either tetra- or penta-cyclic compounds. The limits of detection for a sample were also tested to estimate what concentrations it would still be amenable to Raman spectroscopic investigation. This was investigated using both solid mixtures and liquid solutions. The spectra of these compounds are characterised so that they can be added to the Raman database for future Mars missions. This involved identifying functional group characteristics, assigning peaks for each individual sample and characteristic features which would categorise the samples. 相似文献
60.
Extensive studies have been carried out on the optical conversion of F and F-aggregate colour centres produced in lithium
fluoride single crystal on gamma irradiation. Using 308 nm XeCl laser it has been shown that significantly large population
build-up of F
3
+
centre and reduction in the population of undesirable F2 centres can be achieved in gamma irradiated crystal at room temperature due to multistep photoionization processes. These
and other investigations have provided a scheme for possible laser action based on F
3
+
colour centres in LiF crystal at room temperature. 相似文献