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11.
Surajit Sen 《Physica A》2006,360(2):304-324
There are very few formalisms available to solve the Liouville equation for energy-conserved systems. The continued fraction formalism, introduced through the works of Zwanzig, Mori, Kubo, Lee, Grigolini and others is described here. A detailed discussion is presented on ways to apply the continued fraction formalism to solve for relaxation functions and for the dynamical variable itself for a simple and exactly solvable quantum spin system.  相似文献   
12.
王云仙  戴长键 《光学学报》1994,14(11):142-1146
采用ππ偏振激光,通过两步激发和光电离方法,在0-154V/cm电场范围内,测定了Yb原子n-18附近m=0的斯塔克光谱,首次把包含斯塔克效应的能量矩阵对角化方法推广到Yb原子,所获得的理论斯塔克图与实验结果基本符合,观察到低场中斯塔克簇随电场增加呈现线性结构以及^1P1态与斯塔克簇在抗交叉过程中振子强度发生转移的现象,讨论了结构与量子亏损的关系。  相似文献   
13.
    
From flash photolysis data of benzil and 2,2′-dichlorobenzil, the role of conformeric triplets in the formation of hydrogen adduct radicals has been discussed. The planar relaxed triplet absorbing at 470 nm is less efficient in forming a hydrogen adduct radical as compared to its puckered conformeric partner. Among the hydrogen donors, triethyl amine and isopropanol, the former is more efficient in converting puckered triplets and less efficient in the case of planar conformers. Absorptions of radicals and radical anions of 2,2′-dichlorobenzil appear at 355 nm and 460 nm respectively. These are blue-shifted as compared to those of the parent compound benzil appearing at 370 nm and 540 nm, respectively. This blue-shift has been discussed in terms of steric hindrance due to ortho-substitution.  相似文献   
14.
M.C. Paul  R. Sen  R.E. Youngman  A. Dhar 《Journal of Non》2008,354(52-54):5408-5420
A theoretical approach was made to find out a complete fluorine incorporation zone on a ternary diagram which serves as a useful graphical representation to select the flows of the supplied reagents for incorporation of the suitable amount of fluorine into cladding glass of optical fiber preform made by the MCVD process using CCl2F2 as a source of fluorine under oxygen abundance, oxygen deficiency and intermediate oxygen state conditions. The possible mechanism for incorporation of fluorine into cladding glass of optical fiber is also evaluated on the basis of the thermodynamical data. The fluorine incorporation mechanism in silica glass by the MCVD process is found to be dependent on the CCl2F2/SiCl4 ratio in the input gas mixture. Fluorine doping is found to be effective for removing the strained Si–O–Si bonds, which govern the optical transparency in deep ultra-violet (DUV) and vacuum ultra-violet (VUV) regions. The maximum refractive index depression of ?0.5 × 10?3 is obtained with incorporation of fluorine into silica cladding glass by the MCVD process using CCl2F2 as a dopant precursor with suitable flow of SiCl4 vapor along with O2 through backward deposition pass. The structure of fluorine doped silica glass preform samples containing 1.70–1.79 mol% fluorine incorporated by the MCVD process based on the analyses of 19F MAS spectra done by high-resolution 19F NMR spectroscopy reveal the presence of two distinct types of fluorine environments. The majority of the fluorine environments are formed in SiO1.5F polyhedral and less abundant species is observed to be highly unusual, yielding a fivefold coordinated silicon of the type SiO2F polyhedral which become increased with increasing the fluorine content.  相似文献   
15.
It is shown that time-dependent temperatures in a transient, conductive system can be approximately modeled by a fractional-order differential equation, the order of which depends on the Biot number. This approximation is particularly suitable for complex shapes for which a first-principles approach is too difficult or computationally time-consuming. Analytical solutions of these equations can be written in terms of the Mittag-Leffler function. The approximation is especially useful if a suitable fractional-order controller is to be designed for the system.  相似文献   
16.
This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently.  相似文献   
17.
The recently proposed Harbola–Sahni local potential in its exchange-only version [Phys. Rev. Lett. 62 , 689 (1989)] is found to give the static dipole and quadrupole polarizabilities for the Neisoelectronic series in excellent agreement with the corresponding Hartree–Fock estimates. © 1992 John Wiley & Sons, Inc.  相似文献   
18.
N. Luo  M. de la Sen 《TOP》1995,3(1):1-34
Summary The problem of robust stabilization of internally delayed uncertain systems via sliding mode controllers (SMC's) is studied in this paper. The robustness property and assymptotic stability of the system are discussed. Some sufficient conditions for the design of SMC and the switching hyperplane are given. Further generalization results, which lead to a simple design and implementation, are made for the system being described in companion form. A method is suggested for the elimination of limit cycles in systems being regulated by a relay SMC while allowing the generation of sliding motion and thus ensuring the closed-loop asymptotic stability.  相似文献   
19.
The effect of ultraviolet (UV) light on the thermooxidative stability of Linear Low Density Polyethylene(LLDPE) films was studied. LLDPE was stabilized with phenolic type antioxidant known as Irganox 1010, hindered amine light stabilizer known as Chimmasorb 944 and phenolic type gamma stabilizer. The influence of these additives on the thermooxidative stability of gamma and UV irradiated LLDPE were investigated by isothermal Differential Scanning Calorimeter (DSC). The oxidation induction time (OIT) experiments indicate that antirad free LLDPE films which contains antioxidant and UV stabilizer are more sensitive to gamma and UV radiation. On the other hand, films which contain antirad and irradiated to different doses of γ-radiation demonstrated improved thermooxidative stability.  相似文献   
20.
武森涛  储伟  崔名全 《合成化学》2003,11(3):257-259,266
以改性活性炭担载的Pt为催化剂催化硝基苯经加氢重排一步合成对氨基苯酚,收率54.70%,选择性可达91.40%。  相似文献   
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