Implementing minimal clock skew Directed Logic

Although the physics of computing allows the possibility of logic operations with no energy dissipation, over 40 years of work by brilliant scientists in many fields has not achieved it. The solution described here required breaking from the tacit assumptions that logic gates had to be electronic. The system is implemented entirely with passive optical components. Also needed was a logic that could utilize those passive components. Hardy and Shamir showed how to map a Boolean logic problem into a form suitable to be implemented by light flowing through various paths and cascaded as needed. This paper examines a modular approach to implementing their approach (called Directed Logic) in an integrated optical system. We start from unit cells, implementing a dynamic flip-flop principle and combine the cells in a network or “logic fabric.” Contrary to proofs by the founders of this field, speed is limited only by the message bandwidth of the optical signal, and, of course, no energy is dissipated. There are still aspects that need additional work on issues like accuracy using analog components and size relative to electronics. But the basic problem is solved at last and paths toward solving the remaining problems have been identified.     

Emergent universe scenario in the Einstein–Gauss–Bonnet gravity with dilaton

We obtain cosmological solutions which admit emergent universe (EU) scenario in the framework of Einstein Gauss–Bonnet (GB) gravity coupled with a dilaton field in 4-dimensions. The coupling parameter of the GB terms and the dilaton in the theory are determined for obtaining an EU scenario. The corresponding dilaton potential which admits such scenario is determined. It is found that the GB terms coupled with a dilaton field plays an important role in describing the dynamics of the evolution of the early as well as the late universe. We note an interesting case where the GB term dominates initially in the asymptotic past regime, subsequently it decreases and thereafter its contribution in determining the dynamics of the evolution dominates once again. We note that the Einstein’s static universe solution permitted here is unstable which the asymptotic EU might follow. We also compare our EU model with supernova data.     

Metal Quinolates as Phosphors for PC-LED Applications

Metal quinolates, Liq Alq₃ Znq₂ Mgq₂ exhibit efficient luminescence in blue green region and find applications as emission layer in OLEDs. In most of these quinolates the excitation spectra are broad in the range 350 to 410 nm, just short of emission spectra of efficient GaN based blue LEDs. In this paper we report metal quinolates synthesized by slightly modified method in which the excitation gets extended beyond 450 nm so that there is better overlap between emission spectra of blue LED and the excitation spectra. Therefore these phosphors may be used for PC-LED applications.     

Semi-Analytical Simulation of Titanium-Indiffused Lithium Niobate–Integrated Optic Directional Couplers Consisting of Curved Waveguides

Integrated optic directional couplers consisting of curved waveguides are simulated analytically by solving the Riccati equation. The coupling coefficient between the curved waveguides with a parabolically varying gap and the condition of total power transfer between the waveguides are derived. In order to compute the overall coupling coefficient and hence the power distribution along the waveguides for Ti:LiNbO ₃ curved waveguide directional couplers, the coupling coefficient for straight waveguide couplers is computed for different gaps using the effective-index-based matrix method (EIMM). Finally, the power distribution in the curved waveguides along the length is computed. The method is mostly analytical except the effective-index method and is computationally simple.     

Dielectric properties of KDP-type ferroelectric crystals in the presence of external electric field

Considering external electric field as well as third- and fourth-order phonon anharmonic interaction terms in the pseudospin-lattice coupled mode (PLCM) model Hamiltonian for KDP-type ferroelectrics, expressions for field-dependent shift, width, renormalized soft mode frequency, Curie temperature, dielectric constant and dielectric loss are evaluated. For the calculation, method of statistical double-time temperature-dependent Green’s function has been used. By fitting model values of physical quantities, temperature and electric field dependences of soft mode frequency, dielectric constant and loss have been calculated which compare well with experimental results of Baumgartner [8] and Choi and Lockwood [9]. Both dielectric constant and loss decrease with electric field.     

Flow visualization and local mass transfer studies for turbulent flow in a wind tunnel with chamfered ribs

The paper presents results of flow visualization and mass transfer studies for fully developed turbulent flow of air in a square section wind tunnel with repeated chamfered rib roughness on the bottom of the tunnel (rib head chamfer angles ϕ of -15°, 0°, and 15°; relative roughness pitchp/e = 3, 5, 7.5, and 10). Direct video recordings of flow patterns were made using a simple technique of particles visualization. For the positively chamfered closely spaced ribs (p/e <- 5) vigorous vortex shedding has been seen compared to the square or negatively chamfered ribs, which is found to be a function of the Reynolds number. For the widely spaced ribs, the study shows flow separation at the ribs and reattachment in the inter-rib region. Local mass transfer studies, based on the variation in colour of cobaltous chloride solution impregnated paper due to evaporation of water, showed a significant improvement in mass transfer rate in the recirculating region in the wake of ribs with the change in the chamfer angle from -15° to 15°. The positively chamfered 15° ribs are found to be better than square section ribs atp/e <- 7.5. The performance of negatively chamfered ribs is found to be poor compared to other ribs irrespective of the relative roughness pitch.     

Thermoelectric power of (Me4N)2Ag13I15 and (Et4N)2Ag13I15

Thermoelectric power using reversible silver electrodes and electrical conductivity on the compressed pellets of (Me₄N)₂Ag₁₃I₁₅, and (Et₄N)₂Ag₁₃I₁₅ have been measured between room temperature and below 160°C. The results of θ can be expressed by the equations:?θ = 0.115 (10³/T)+0.2905VK^?1 and ?θ = 0.150 (10³/T) + 0.305mV K^?1; and those of conductivity by the equations; σ = 28.7 exp (?0.17eV/kT) ohm^?1cm^?1 and $\text{σ = 216.6 exp (?0.24e}\text{V}\text{kT}\text{)}$ ohm^?1cm^?1; respectively for Me- and Et-electrolytes. The results are discussed and compared with those of previous authors.     

Quantitative estimations of ferric iron by phosphoric acid in aqueous-alcoholic medium

Summary The only method recommended for the direct estimation of ferric iron in presence of HCl is to reduce the ferric iron to ferrous iron and then to titrate against KMnO₄ solution by adding Reinhardt-Zimmermann reagent (MnSO₄ + H₂SO₄ + H₃PO₄). The solubility of the phosphato complexes of ferric chloride and phosphoric acid is much reduced by adding a nonaqueous solvent, ethyl alcohol or acetone. This property has been availed of to find out a method of estimating ferric iron directly against standard solution of phosphoric acid in aqueous-nonaqueous medium using K₄Fe(CN)₆ or cupferron as external indicators. A slight discrepancy at the end point, however, exists in the direct titration but it can be removed by applying a correction factor determined from the estimated results.     

Easy Access to α-Bromoketones and Epoxides from vic-Dibromides Under Aqueous Conditions

The conversion of vic-1,2 dibromides to α-bromoketones and epoxides using H₂O₂/dioxane and NaOH/water respectively under mild conditions has been described.     

Cobalt(III) complexes of unsaturated carboxylic acids: synthesis, characterization, and photochemical studies in aqueous medium

Cobalt(III) ammine complexes coordinated to carboxylic acids are classic examples showing photoredox reactions originating from the ligand to metal charge transfer excited states. Cobalt(III) pentaammine complexes coordinated to unsaturated carboxylic acids as ligands were synthesized and characterized by spectroscopic methods. The photolysis of these complexes produces a carboxylate free radical. This free radical undergoes further transformation to form organic photoproducts. The organic photoproducts were characterized by spectroscopic methods. The nature of the decomposition products from the organic photoproduct was examined in detail. The quantum yields were also determined. The photochemical reactions have the potential to produce novel compounds from the decarboxylation of unsaturated acids, which shows interesting reaction pathways.