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31.
Campomanes P Menéndez MI Cárdenas-Jirón GI Sordo TL 《The journal of physical chemistry. A》2005,109(34):7822-7831
A theoretical analysis of the silver-induced ring expansion of N-chloro-N-methyl-1-hydroxycyclopropylamine to form N-methyl-2-azetidinone, and of the Cl(-) elimination from this substrate without Ag(+) assistance, was performed using the B3LYP method and the 6-31+G(d) basis set for C, N, O, H, and Cl atoms and the relativistic effective core pseudopotential LANL2DZ complemented with one set of f polarization functions (zeta(f) = 0.473) for the Ag atom. The partial Ag(+)-assisted extrusion of Cl(-) at the rate-determining transition state provokes an important change in the nodal properties of the frontier molecular orbitals of the H(3)CClNCOHAg(+) fragment, thus making very stabilizing HOMO-LUMO interactions between this fragment and the C(2)H(4) moiety possible. This interaction leads to the ring opening and release of most of the strain energy, giving rise to a low energy barrier for the process. Also, by assisting the Cl(-) extrusion, Ag(+) avoids the elimination of the hydroxyl hydrogen atom, which would provoke the fragmentation of the system instead of the formation of the beta-lactam. 相似文献
32.
This research was aimed
to investigate the role of clay on the combustion and kinetic behavior of
crude oils in limestone matrix. For this purpose, simultaneous TG (thermogravimetry)
and DTA (differential thermal analysis) experiments were performed at three
different heating rates as 10–15 and 20°C min–1,
respectively. A uniform trend of decreasing activation energies was observed
with the addition of clay. It was concluded that clays surface area affects
the values of Arrhenius constant, while it is the catalytic properties of
clay, which lower the activation energies of all the reactions, involved in
the combustion process. 相似文献
33.
Volker Strauss Huize Wang Simon Delacroix Marc Ledendecker Pablo Wessig 《Chemical science》2020,11(31):8256
Luminescent compounds obtained from the thermal reaction of citric acid and urea have been studied and utilized in different applications in the past few years. The identified reaction products range from carbon nitrides over graphitic carbon to distinct molecular fluorophores. On the other hand, the solid, non-fluorescent reaction product produced at higher temperatures has been found to be a valuable precursor for the CO2-laser-assisted carbonization reaction in carbon laser-patterning. This work addresses the question of structural identification of both, the fluorescent and non-fluorescent reaction products obtained in the thermal reaction of citric acid and urea. The reaction products produced during autoclave–microwave reactions in the melt were thoroughly investigated as a function of the reaction temperature and the reaction products were subsequently separated by a series of solvent extractions and column chromatography. The evolution of a green molecular fluorophore, namely HPPT, was confirmed and a full characterization study on its structure and photophysical properties was conducted. The additional blue fluorescence is attributed to oligomeric ureas, which was confirmed by complementary optical and structural characterization. These two components form strong hydrogen-bond networks which eventually react to form solid, semi-crystalline particles with a size of ∼7 nm and an elemental composition of 46% C, 22% N, and 29% O. The structural features and properties of all three main components were investigated in a comprehensive characterization study.Products of the thermal reaction of citric acid and urea have been identified as a complex mixture of fluorophores and particles. 相似文献
34.
Elizabeth Nunes Fernandes Mariele Nair de Campos Moura Jos Luis F. Costa Lima Boaventura F. Reis 《Microchemical Journal》2004,77(2):107-112
An automatic flow procedure for the determination of glycerol in wines by employing a flow system based on multicommutation and enzymatic reaction is described. Glycerol dehydrogenase was immobilized on aminopropyl glass beads and packed into a column that was coupled to the flow system. The NADH produced by the enzymatic reaction was monitored by spectrophotometry at 340 nm and its radiation absorption presented a relationship with glycerol concentration. The system manifold comprised a set of three-way solenoid valves controlled by a microcomputer, which was furnished with electronic interfaces and runs a software that was designed to carry out on-line sample dilution, reagent addition, and data acquisition. The procedure allows the determination of glycerol in wine samples without any prior pretreatment. The procedure presented as profitable features a linear response range between 2.0 and 10.0 g l−1 glycerol (R=0.998), a detection limit of 0.006 g l−1 glycerol, a relative standard deviation of 1.8% (n=14) for a typical wine sample presenting 5.3 g l−1 glycerol, a sampling throughput of 33 determinations per hour, and a NAD+ consumption of 0.8 mg per determination. The results were compared with those obtained using a reference method and no significant difference at 90% confidence level was observed. 相似文献
35.
Irene Fonseca David Kinderlehrer Pablo Pedregal 《Calculus of Variations and Partial Differential Equations》1994,2(3):283-313
In this paper we deal with energy functionals depending on elastic strain and chemical composition and we obtain lower semicontinuity results, existence theorems and relaxation in the spacesH
1,p(; n)×L
q
(; d) with respect to weak convergence. Our proofs use parametrized measures associated with weakly converging sequences.The research was partially supported by the National Science Foundation under Grants No. DMS-9000133 and DMS-9201215 and also by the Army Research Office and the National Science Foundation through the Center for Nonlinear Analysis.The research was partially supported by the National Science Foundation uncer Grants No. DMs 911572, the AFOSR 91 0301, the ARO DAAL03 92 G 003 and also by the ARO and the NSF through the Center for Nonlinear Analysis.The research was supported by DGICYT (Spain) through Programa de Perfeccionamiento y Movilidad del Personal Investigador and through grant PB90-0245, by the Army Research Office and the National Science Foundation through the Center for Nonlinear Analysis and also by the project EurHomogenization SC1-CT91-0732 of the European Comunity. 相似文献
36.
Oscillatory properties of a weak convergent sequence of functions bounded inL
p
, 1 ≤p ≤ ∞, may be summarized by the parametrized measure it generates. When such a measure is generated by the gradients of a sequence
of functions bounded inH
1,p
, it must have special properties. The purpose of this paper is to characterize such parametrized measures as the ones that
obey Jensen’s inequality for all quasiconvex functions with the appropriate growth at infinity. We have found subtle differences
between the casesp < ∞ andp = ∞. A consequence is that any measure determined by biting convergence is in fact generated by a sequence convergent in
a stronger sense. We also give a few applications.
Research groupTransitions and Defects in Ordered Materials, funded by the NSF, the AFOSR, and the ARO. The work of the second author is also supported by DGICYT (Spain) through “Programa
de Perfeccionamiento y Movilidad del Personal Investigador” and through Grant PB90-0245. 相似文献
37.
An introduction to population approaches for optimization and hierarchical objective functions: A discussion on the role of tabu search 总被引:3,自引:0,他引:3
Pablo Moscato 《Annals of Operations Research》1993,41(2):85-121
Population approaches suitable for global combinatorial optimization are discussed in this paper. They are composed of a number of distinguishable individuals called "agents", each one using a particular optimization strategy. Periods of independent search follow phases on which the population is restarted from new configurations. Due to its intrinsic parallelism and the asynchronicity of the method, it is particularly suitable for parallel computers. Results on two test problems are presented in this paper. The individual search optimization strategies for each agent have been chosen having the basic characteristics of tabu search. This has been done in order to avoid mixing the hypothesized properties of these population approaches with those of more elaborate tabu search strategies, but remarking on its main characteristics. A set of four test problem "landscapes" is discussed and their use to improve and benchmark the results by using tabu search as the individual optimization strategy within a population heuristic is suggested and explored. The application of tabu search to new problem areas, like molecular biology, is also investigated. 相似文献
38.
den Brok MW Nuijen B Miranda E Floriano P Munt S Manzanares I Beijnen JH 《Journal of chromatography. A》2003,1020(2):251-258
ES-285 x HCl [(2S,3R)-2-amino-3-octadecanol hydrochloride] is a novel investigational anticancer agent, which has shown in vitro and in vivo cytotoxic activity against various tumor cell lines with selectivity for certain solid tumors. The pharmaceutical development of ES-285 x HCl warranted the availability of an assay for the quantification and purity determination of ES-285 x HCl active pharmaceutical ingredient (API) and its pharmaceutical dosage form. A liquid chromatographic method (LC) comprising of derivatisation of ES-285 x HCl with phenylisothiocyanate and UV-detection was developed. The method was found to be linear, precise and accurate. The assay also proved selectivity as determined by analysing ES-285 x HCl in combination with 15 analogues and in combination with hydroxypropyl-beta-cyclodextrin, the excipient used in the lyophilised pharmaceutical dosage form. Stress testing showed that the degradation products were separated from the parent compound, confirming its stability indicating capacity. The method was found robust as determined with design of experiments (DoE), which made it possible to predict system suitability responses in worst case experimental conditions and to define criteria for system suitability testing. 相似文献
39.
Different transformations of chiral epoxy esters 1 afford two different amino gamma-butyrolactones 2 and 6, and amino gamma-butenolides 8, by different nucleophilic opening-closing processes. [reaction: see text] 相似文献
40.
Mary E. R. McHale Ann-Sofi M. Kauppila Joyce R. Powell Pablo Otero Jr. Melani Jayasekera William E. Acree Jr. 《Journal of solution chemistry》1996,25(3):295-302
Experimental solubilities are reported for benzil dissolved in six binary mixtures containing dibutyl ether with hexane, heptane, octane, cyclohexane, methylcyclohexane, and 2,2,4-trimethylpentane at 25°C. Results of these measurements are compared to the predictions of equations developed previously for solubility in systems of nonspecific interactions. The most successful equation in terms of goodness of fit involved a volume fraction average of the excess Gibbs energies relative to the Flory-Huggins model, and predicted the experimental solubilities in the six systems studied to within an overall average absolute deviation of 3.4% and with a maximum deviation of 6.0%. 相似文献