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71.
1,2-Dimyristoyl-sn-glycero-3-phospho-rac-glycerol has been suggested to form at intermediate temperatures and at high concentrations in low-salt solutions as a continuous sponge phase (Heimburg, T.; Biltonen, R. L. Biochemistry 1994, 33, 9477-9488). In the present study, the changes in signals seen for a range of fluorescent probes during phase transformations of this phospholipid indicate continuous melting and a change in lipid packing, in accordance with previous reports. However, in accordance with Lamy-Freund and Riske (Lamy-Freund, M. T.; Riske, K. A. Chem. Phys. Lipids 2003, 122, 19-32), no enhancement of lipid mixing within the putative sponge phase region was seen, suggesting a lack of a connected lipid surface. Accordingly, a typical sponge phase cannot account for the properties of the intermediate phase. The low scattering intensities of the latter have also been taken as evidence for disaggregation. While dynamic light scattering and data for membranes containing poly(ethylene glycol)-ylated lipids could lend credence to disaggregation, the most likely explanation for the scattering data would appear to be a shape transition without significant changes in neither vesicle aggregation nor bilayer connectivity. An abrupt change in light scattering and signals from some of the fluorescent probes used reveals a new transition at Tt approximately 43 degrees C, with the formation of a more ordered interface. 相似文献
72.
Sören Christensen Fabián Crocce Ernesto Mordecki Paavo Salminen 《Stochastic Processes and their Applications》2019,129(7):2561-2581
This paper develops an approach for solving perpetual discounted optimal stopping problems for multidimensional diffusions, with special emphasis on the -dimensional Wiener process. We first obtain some verification theorems for diffusions, based on the Green kernel representation of the value function. Specializing to the multidimensional Wiener process, we apply the Martin boundary theory to obtain a set of tractable integral equations involving only harmonic functions that characterize the stopping region of the problem in the bounded case. The approach is illustrated through the optimal stopping problem of a -dimensional Wiener process with a positive definite quadratic form reward function. 相似文献
73.
João M. Rocha Paavo J. Kalo Velimatti Ollilainen F. Xavier Malcata 《Journal of chromatography. A》2010,1217(18):3013-3025
A novel method was developed for the analysis of molecular species in neutral lipid classes, using separation by normal phase high-performance liquid chromatography, followed by detection by evaporative light-scattering and electrospray ionization tandem mass spectrometry. Monoacid standards, i.e. sterol esters, triacylglycerols, fatty acids, diacylglycerols, free sterols and monoacylglycerols, were separated to baseline on microbore 3 μm-silica gel columns. Complete or partial separation of molecular species in each lipid class permitted identification by automatic tandem mass spectrometry of ammonium adducts, produced via positive electrospray ionization. After optimization of the method, separation and identification of molecular species of various lipid classes was comprehensively tested by analysis of neutral lipids from the free lipid extract of maize flour. 相似文献
74.
H Pulakka L Laaksonen S Yrttiaho V Myllylä P Alku 《The Journal of the Acoustical Society of America》2012,132(2):848-861
Artificial bandwidth extension methods have been developed to improve the quality and intelligibility of narrowband telephone speech and to reduce the difference with wideband speech. Such methods have commonly been evaluated with objective measures or subjective listening-only tests, but conversational evaluations have been rare. This article presents a conversational evaluation of two methods for the artificial bandwidth extension of telephone speech. Bandwidth-extended narrowband speech is compared with narrowband and wideband speech in a test setting including a simulated telephone connection, realistic conversation tasks, and various background noise conditions. The responses of the subjects indicate that speech processed with one of the methods is preferred to narrowband speech in noise, but wideband speech is superior to both narrowband and bandwidth-extended speech. Bandwidth extension was found to be beneficial for telephone conversation in noisy listening conditions. 相似文献
75.
76.
Firstly, we compute the distribution function for the hitting time of a linear time-dependent boundary t ↦ a + bt, a ≥ 0, b ∈ ℝ, by a reflecting Brownian motion. The main tool hereby is Doob’s formula which gives the probability that Brownian motion
started inside a wedge does not hit this wedge. Other key ingredients are the time inversion property of Brownian motion and
the time reversal property of diffusion bridges. Secondly, this methodology can also be applied for the three-dimensional
Bessel process. Thirdly, we consider Bessel bridges from 0 to 0 with dimension parameter δ > 0 and show that the probability that such a Bessel bridge crosses an affine boundary is equal to the probability that this
Bessel bridge stays below some fixed value. 相似文献
77.
Kalevi Pihlaja Paavo Pasanen Jukka Whsilta 《Magnetic resonance in chemistry : MRC》1979,12(5):331-336
The addition of thioacetic acid to unsaturated alcohols or acids was utilized to obtain mercaptoalkanols which were condensed with suitable carybonyl compounds to prepare 24 methyl-substituted 1,3-oxathianes. The 1H NMR spectra of the 1,3-oxathiane products were recorded at 60, 100 and/or 300 MHz and fully analysed. The results are best explained by a chair form which is completely staggered in the C-4? C-5? C-6 moiety ψ45 or (ψ56=60±1°). 1,3-Oxathianes having syn-axial 2,4- (and/or 2,6-) methyl-methyl interactions exist appreciably, if not exclusively, in twist forms. The vicinal coupling constants lead to the conformational free energies of axial methyl groups at C-4, ΔG°=7.4±0.4 kJ mol?1, and at C-5, ΔG°=3.7±0.3 kJ mol?1, in good agreement with previous estimates. They also show that both r-4,cis-5,trans-6- and r-4,trans-5,trans-6- trimethyl-1,3-oxathianes greatly favour the chiar form where the methyl group at C-4 is axial. The chair-twist energy parameters are reestimated at ΔH°CT 27.0 kJ mol?1, ΔS°CT 11.6J mol?1K?1, and ΔG°CT(298) 23.5 kJ mol?1 for a 2,5-twist form. 相似文献
78.
The 13C NMR spectrum (at natural abundance) of monomeric chlorophyll α in acetone-d6 has been recorded to re-examine the assignments of the low field (aromatic-olefinic) region of the spectrum. The assignments, made by the examination of the fully coupled spectrum and by the use of long-range selective 1H decoupling (LSPD) with low-power irradiation, were compared with those of the previous reports. The results of the present work clarify the ambiguities previously encountered in the assignment of the 10a-ester, 7c-propionyl, P-2-phytyl, 2b-vinyl, γ- and β-methine carbon atoms, as well as the β-pyrrolic carbon-6 and α-pyrrolic carbons ?16 and ?17 of chlorophyll α. Reassignment of the three last carbons was found necessary. Knowledge of the chemical shifts of these carbon atoms was considered to be particularly valuable, as it yields relevant information on the delocalized π electron system which is crucial for the function of chlorophyll in photosynthesis. 相似文献
79.
Hannu?TiitinenEmail author Anna?Mari?M?kel? Ville?M?kinen Patrick?JC?May Paavo?Alku 《BMC neuroscience》2005,6(1):62
Background
The cortical activity underlying the perception of vowel identity has typically been addressed by manipulating the first and second formant frequency (F1 & F2) of the speech stimuli. These two values, originating from articulation, are already sufficient for the phonetic characterization of vowel category. In the present study, we investigated how the spectral cues caused by articulation are reflected in cortical speech processing when combined with phonation, the other major part of speech production manifested as the fundamental frequency (F0) and its harmonic integer multiples. To study the combined effects of articulation and phonation we presented vowels with either high (/a/) or low (/u/) formant frequencies which were driven by three different types of excitation: a natural periodic pulseform reflecting the vibration of the vocal folds, an aperiodic noise excitation, or a tonal waveform. The auditory N1m response was recorded with whole-head magnetoencephalography (MEG) from ten human subjects in order to resolve whether brain events reflecting articulation and phonation are specific to the left or right hemisphere of the human brain. 相似文献80.
A chloro-substituted derivative was prepared from chlorophyll ′. The derivative was shown to be δ-chloro-methyl pheophorbide by UV/VIS, MS and ′H NMR. 相似文献