全文获取类型
收费全文 | 492篇 |
免费 | 7篇 |
专业分类
化学 | 291篇 |
晶体学 | 5篇 |
力学 | 9篇 |
数学 | 49篇 |
物理学 | 145篇 |
出版年
2023年 | 4篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 4篇 |
2014年 | 10篇 |
2013年 | 11篇 |
2012年 | 4篇 |
2011年 | 13篇 |
2010年 | 9篇 |
2009年 | 12篇 |
2008年 | 13篇 |
2007年 | 13篇 |
2006年 | 18篇 |
2005年 | 22篇 |
2004年 | 21篇 |
2003年 | 23篇 |
2002年 | 18篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 7篇 |
1995年 | 11篇 |
1994年 | 14篇 |
1993年 | 16篇 |
1992年 | 22篇 |
1991年 | 14篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 13篇 |
1987年 | 8篇 |
1986年 | 9篇 |
1985年 | 7篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1978年 | 4篇 |
1977年 | 7篇 |
1976年 | 5篇 |
1975年 | 6篇 |
1973年 | 6篇 |
1970年 | 5篇 |
1967年 | 2篇 |
1965年 | 3篇 |
1931年 | 2篇 |
排序方式: 共有499条查询结果,搜索用时 203 毫秒
21.
22.
Shi G Wu JT Li Y Geleziunas R Gallagher K Emm T Olah T Unger S 《Rapid communications in mass spectrometry : RCM》2002,16(11):1092-1099
23.
Gallagher PA Shoemaker JA Wei X Brockhoff-Schwegel CA Creed JT 《Fresenius' Journal of Analytical Chemistry》2001,369(1):71-80
An accelerated solvent extraction (ASE) device was evaluated as a semi-automated means of extracting arsenicals from ribbon kelp. The effect of the experimentally controllable ASE parameters (pressure, temperature, static time, and solvent composition) on the extraction efficiencies of arsenicals from seaweed was investigated. The extraction efficiencies for ribbon kelp (approximately 72.6%) using the ASE were fairly independent (< 7%) of pressure, static time and particle size after 3 ASE extraction cycles. The optimum extraction conditions for the ribbon kelp were obtained by using a 3 mL ASE cell, 30/70 (w/w) MeOH/H2O, 500 psi (1 psi = 7 KPa), ambient temperature, 1 min heat step, 1 min static step, 90% vol. flush, and a 120 s purge. Using these conditions, two other seaweed products produced extraction efficiencies of 25.6% and 50.5%. The inorganic species present in the extract represented 62.5% and 27.8% of the extracted arsenic. The speciation results indicated that both seaweed products contained 4 different arsenosugars, DMA (dimethylarsinic acid), and As(V). One seaweed product also contained As(III). Both of these seaweed products contained an arsenosugar whose molecular weight was determined to be 408 and its structure was tentatively identified using ion chromatography-electrospray ionization-mass spectrometry/mass spectrometry (IC-ESI-MS/MS). 相似文献
24.
Colm Crean John F. Gallagher Albert C. Pratt 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):o36-o38
The title complex, C17H9N5·C6H4S4, contains π‐deficient bis(dinitrile) and TTF molecules stacked alternately in columns along the a‐axis direction; the interplanar angle between the TTF molecule and the isoindolinyl C4N[C(CN)2]2 moiety is 1.21 (4)°. The N‐allyl moiety in the TCPI molecule is oriented at an angle of 87.10 (10)° with respect to the five‐membered C4N ring, and the four C[triple‐bond]N bond lengths range from 1.134 (3) to 1.142 (3) Å, with C—C[triple‐bond]N angles in the range 174.3 (3)–176.9 (2)°. In the TTF system, the S—C bond lengths are 1.726 (3)–1.740 (3) and 1.751 (2)–1.763 (2) Å for the external S—C(H) and internal S—C(S) bonds, respectively. 相似文献
25.
Lithiation of 1,1-bis(phenylthio)-3-phenylthio-1-propene 3 and reaction with a range of electrophiles gave exclusively the γ-substituted product 4. This reagent has been used in a short synthesis of the pheromone, (±)-eldanolide. 相似文献
26.
Matthias Tacke Lorcan T. Allen William M. Gallagher Oscar Mendoza Franz-Josef K. Rehmann 《Journal of organometallic chemistry》2004,689(13):2242-2249
Starting from 6-(p−N,N-dimethylanilinyl)fulvene (1a) or 6-(pentamethylphenyl)fulvene (1b) [1,2-di(cyclopentadienyl)-1,2-di(p−N,N-dimethylaminophenyl)ethanediyl] titanium dichloride (2a) and [1,2-di(cyclopentadienyl)-1,2-bis(pentamethylphenyl)ethanediyl] titanium dichloride (2b) and their corresponding dithiocyanato complexes (3a, 3b) were synthesized. Titanocene 2b did not show a cytotoxic effect, but when 2a was tested against pig kidney carcinoma cells (LLC-PK) or human ovarian carcinoma cells (A2780/cp70) inhibitory concentrations (IC50) of 2.7 × 10−4 and 1.9 × 10−4 M, respectively, were observed. 相似文献
27.
W.Robert Sinclair J.B. Macchesney P.K. Gallagher P.B. O''Connor 《Thermochimica Acta》1979,30(1-2):225-231
The reaction between SiCl4 and O2 at 1 atm between 25 and 1200°C has been followed by mass spectrometry. Below 600°C no reaction with O2 is noted. Above 600°C the reaction proceeds in two steps. Between 800 and 1000°C the 28Si/32O2 peak height ratio is constant with no evolution of Cl2. It is suggested that silicon oxychlorides are being formed in this temperature regime. Above 1000°C the reaction between SiCl4 and O2 intensifies with concomitant production of Cl2. It is suggested that above 1000°C the reaction SiCl4 + O2 → SiO2 + Cl2 becomes important.
At low temperatures (<800°C) adsorbed H2O and OH groups from the surface of the fused silica tube react with SiCl4 to form HCl. The importance of this reaction decreases with increasing temperature. The increased production of HCl above 1000°C is ascribed to H2O and H2 diffusing from the tube. 相似文献
28.
29.
30.
Hans-Peter Ros Rolf Kyburz Nigel W. Preston Rex T. Gallagher I. Ralph C. Bick Manfred Hesse 《Helvetica chimica acta》1979,62(2):481-487
The revised structure 1 is put forward for peduncularine, the main alkaloid of Aristotelia peduncularis (Labill.) HOOK. F. (Elaeocarpaceae), on the basis of its spectroscopic properties and those of its degradation products, the Hofmann base 3 and the hydrogenation product 4 . Structure 1 represents the relative configuration of the alkaloid. Peduncularine belongs to the class of indole alkaloids with a monoterpene unit as the aliphatic portion. To our knowledge it constitutes the first example in which an isopropyl group has become detached from the terpene unit and occurs as a substituent on nitrogen. 相似文献