Flows in a lower half heated upper half cooled cylindrical model reactor loaded with porous media

This paper presents an experimental and numerical investigation on the natural convection flow in a cylindrical model hydrothermal reactor. The flow is visualized non-intrusively and simulated with a conjugate computational model. Results show that the flow structure consists of wall layers and core flows. In the lower half, the flows are steady due to the porous media. The three-dimensional unsteady upper core flow is driven by the streams originated from the wall layer collision. The thermal condition in the upper half core region is mainly determined by the total heat flow rate specified on the lower sidewall; while the variations of porous media parameters, in the normal range for hydrothermal crystal growth process, have minor effects.     

计算发散爆轰波传播的DSD方法

首先对爆轰冲击动力学（ＤＳＤ）方法的理论基础进行了探讨，完整地给出了它的数学表达，并研究了它的具体计算问题，指出了它的难点在于动边界问题的处理、然后针对两种特殊的几何条件，提出了用变量替换方法变动边界为定边界的思路。最后，根据计算结果，讨论了各种参数对波形的影响，特别是钝感炸药和敏感炸药所体现出的差异。     

损伤和断裂的统一

本文讨论了连续损伤力学基础的缺陷,从微裂纹随机演化出发给损伤概念作出新的普适的统计定义,导出了损伤断裂几率的动力学方程,使损伤、断裂、统计、微观机理及宏观特性五者有机地相结合,从而有可能形成一个统一的损伤断裂微观统计理论。     

分析蜂窝夹芯板脱胶问题的片条合成-能量法

本文提出了分析蜂窝夹芯板脱胶问题的片条合成－能量法。在文献[2]建立的分析模型的基础上，根据分析蜂窝夹芯梁脱胶问题得到的位移模态，用片条合成的方法构造蜂窝夹芯脱胶板的位移模态，然后用最小势能原理进行求解，得到了位移幅值，应力分布和幅值。通过算例对本文方法的适用性和有效性进行了讨论，分析表明本文的结果与文献[2]中双三角级数解法所得的结果吻合的很好。而利用片条合成－能量法，可以得到蜂窝夹芯板脱胶问题的闭合形式解答，便于工程应用。     

杆和梁在锁定过程的响应

对杆和梁在锁定过程的响应进行了详细分析，用波传播理论解释了部分结果的物理含义，对用Ｅｕｌｅｒ梁理论分析锁定问题的可行性进行了探讨。     

A Competitor-switched Electrochemical Sensor for Detection of DNA

A competitor‐switched electrochemical sensor based on a generic displacement strategy was designed for DNA detection. In this strategy, an unmodified single‐stranded DNA (cDNA) completely complementary to the target DNA served as the molecular recognition element, while a hairpin DNA (hDNA) labeled with a ferrocene (Fc) and a thiol group at its terminals served as both the competitor element and the probe. This electrochemical sensor was fabricated by self‐assembling a dsDNA onto a gold electrode surface. The dsDNA was pre‐formed through the hybridization of Fc‐labeled hDNA and cDNA with their part complementary sequences. Initially, the labeled ferrocene in the dsDNA was far from surface of the electrode, the electrochemical sensor exhibited a "switch‐off" mode due to unfavorable electron transfer of Fc label. However, in the presence of target DNA, cDNA was released from hDNA by target DNA, the hairpin‐open hDNA restored its original hairpin structure and the ferrocene approached onto the electrode surface, thus the electrochemical sensor exhibited a "switch‐on" mode accompanying with a change in the current response. The experimental results showed that as low as 4.4×10⁻¹⁰ mol/L target DNA could be distinguishingly detected, and this method had obvious advantages such as facile operation, low cost and reagentless procedure.     

Two new eudesmane derivatives from Verbesina virginica

<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods.     

Synthesis of linear and V-shaped oligo(phenylene ethynylene) derivatives: geometric effects on photophysical properties

<正>A series of linear and V-shaped oligo(phenylene ethynylene) derivatives 1-3 were synthesized through sequent Sonogashira coupling and propargyl alcohol deprotection reaction in high yields.The alkoxy chains(i.e.,n-hexyloxy groups) were introduced to assure good solubility of compounds 1-3 in common solvents.The photophysical properties of 1-3 in solution depend strongly on the geometries of these compounds.     

高效稳定的Al~(3+)偶联多层Eosin Y敏化TiO_2光催化制氢体系研究

通过Al3+偶联制备了多层EosinY敏化的TiO2催化剂,其光催化制氢性能优于Fe3+偶联的催化剂.在水体系、甲醇-水体系中,以三乙醇胺(TEOA)作电子给体,采用原位载Pt,考察了催化剂在可见光(λ420nm)下的制氢活性与稳定性.结果表明,含水0.5%(体积分数)的体系、载铂量为1.0%时,显示了较高的活性和良好的稳定性,20h的平均量子效率为20.5%,转换数为220.较高的活性和稳定性初步归结于Al3+水解趋势较Fe3+小,且催化剂在甲醇中比在水中更稳定,进一步的研究正在进行中.     

“一锅法”合成11,11′-双(8,11-二氢苯并[f]呋喃并[3,4-b]喹啉-10-酮)(英文)

微波辐射下,不使用催化剂,在醋酸和DMF的混合溶剂中二醛、季酮酸和萘胺反应,"一锅法"合成11,11′-双(8,11-二氢苯并[f]呋喃并[3,4-b]喹啉-10-酮)。所合成化合物的结构经红外光谱、核磁共振光谱和高分辨率质谱予以确证。该方法具有产率高、操作简单、反应时间短等优点。