一类n阶非线性两点边值问题解的存在性与唯一性

本文利用Leray-Schauder度理论,上下解方法及微分不等式方法等,在较弱的Nagumo条件下得到了一类n阶非线性两点边值问题解的存在性与唯-性结果,并给出了应用举例.     

金属的有效真二次电子发射系数与高能原电子入射角的关系

推导出高能原电子斜入射时的金属的有效真二次电子发射系数的表达式，它与入射角的余弦近似成反比，并对结果进行了讨论.     

衬底温度对La0.8Sr0.2MnO3/TiO2异质P-N结整流特性的影响

本文利用磁控溅射法通过改变衬底温度成功制备出La0.8Sr0.2 MnO3/TiO2异质P-N结.当衬底温度升高时,LSMO/TiO2异质PN结表现出相对较好的整流特性.这可能是由于衬底温度的升高导致氧气吸收的增加,进而导致载流子浓度增大,串联电阻降低.电流电压的变温特性曲线显示随着测量温度的降低,扩散电压增大,这可能由于能带结构模型与热激活模型共同决定.值得提出的,异质P-N结结电阻随温度变化曲线呈现出单层LSMO表现的金属绝缘相变特性,并且在低测量温度时表现出随着测量温度的降低结电阻增大,这可能是由于宽带隙的TiO2的引入导致.     

一些特殊变换群的联合不变量和联合微分不变量

The theory of moving frames developed by Peter J Olver and M Fels has importaut applications to geometry,classical invariant theory.We will use this theory to classify joint invariants and joint differential invariants of some transformation groups.     

Synthesis and Thermal Behavior of 1,8-Dihydroxy- 4,5-dinitroanthraquinone Manganese Salt

A novel energetic combustion catalyst, 1,8-dihydroxy-4,5-dinitroanthraquinone manganese salt （DHDNEMn）, was synthesized by virtue of the metathesis reaction in a yield of 91%, and its structure was characterized by IR, element analysis and differential scanning calorimetry（DSC）. The thermal decomposition reaction kinetics was studied by means of different heating rate DSC. The results show that the apparent activation energy and pre-exponential factor of the exothermic decomposition reaction of DHDNEMn obtained by Kissinger＇s method are 162.3 kJ/mol and 1011.8 s^-1, respectively. The kinetic equation of major exothermic decomposition reaction of DHDNEMn is dα/dT= 10^118/β 2/5（1-α）[-ln（1-α）[-ln（1-α）]^3/5 exp（-1.623×10^5/RT）. The entropy of activation（△S^≠）, enthalpy of activation（△H^≠） and free energy of activation（A△G^≠） of the first thermal decomposition are -24.49 J·mol^-1·K^-1, 185.20 kJ/mol and 199.29 kJ/mol（T=575.5 K）, respectively. The self-accelerating decomposition temperature（TSADT） and critical temperature of thermal explosion（Tb） are 562.9 and 580.0 K, respectively. The above-mentioned information on the thermal behavior is quite useful for analyzing and evaluating the stability and thermal safety of DHDNEMn.     

基于二甲胺（DMA）光催化降解的纳米TiO2/硅藻土光催化剂的制备和表征

以钛酸四丁酯为原料,通过溶胶 凝胶法制备纳米TiO2/硅藻土复合光催化剂,以难降解有机物二甲胺（DMA）为被降解物,考察了制备条件对光催化性能的影响.结果表明,TiO2/硅藻土光催化剂的制备最佳条件为水醇比0.6,500 ℃煅烧5 h,硅藻土2 g∶9 mL负载1次,溶胶pH值为2.复合光催化剂经扫描电子显微镜（SME）和X射线衍射仪（XRD）表征,达到纳米级别,3 g·L-1催化剂对400 mg·L-1 DMA的6 h降解率平均可达70%,光催化性能优良.     

基于二甲胺（DMA）光催化降解的纳米TiO2/硅藻土光催化剂的制备和表征

以钛酸四丁酯为原料,通过溶胶-凝胶法制备纳米TiO2/硅藻土复合光催化剂,以难降解有机物二甲胺(DMA)为被降解物,考察了制备条件对光催化性能的影响.结果表明,TiO2/硅藻土光催化剂的制备最佳条件为水醇比0.6,500℃煅烧5h,硅藻土2g∶9mL负载1次,溶胶pH值为2.复合光催化剂经扫描电子显微镜(SME)和X射线衍射仪(XRD)表征,达到纳米级别,3g·L-1催化剂对400mg·L-1 DMA的6h降解率平均可达70%,光催化性能优良.     

10Be中子谱因子的实验研究

核谱因子描述了单粒子轨道中核子的占有状态,在核结构和核天体物理中有重要的应用。目前国际上10Be中子谱因子的研究结果存在3倍左右的差异。本实验利用中国原子能科学研究院HI-13串列加速器的高灵敏度Q3D磁谱仪,对13C（9Be,10Be）12C反应角分布进行了精确测量。通过实验数据和扭曲波玻恩近似（DWBA）计算结果进行比较,导出了10Be的中子谱因子。该结果与转动不变壳模型理论及曾敏尔等的评价结果基本一致。利用该结果可以得到9Be（n,γ）10Be的天体物理反应率,评价该反应在相关天体环境中对CNO循环种子核12C的影响,为核结构和核天体物理提供可靠数据。Spectroscopic factor describes the overlap between the initial and final states and gives some information on the occupancy of a given single-particle orbiting around nuclear. It plays an important role in a variety of topics on nuclear structure and nuclear astrophysics. Nowadays, several experiments have been performed to study the neutron spectroscopic factor of 10Be, but the results have a big difference with each other. In order to clarify this discrepancy, new measurement is highly needed. In this work, the angular distribution of 13C(9Be,10Be)12C reaction was measured at the Q3D magnetic spectrometer of the HI-13 tandem accelerator, China Institute of Atomic Energy, Beijing. And then, the neutron spectroscopic factor of 10Be was derived by normalizing the calculational differential cross-sections with the distorted-wave Born approximation to the experimental data. The present value is in good agreement with that obtained by Tsang et al. and also in good agreement with that derived from translationary invariant shell model calculation. One can use this result to calculate the 9Be(n, γ)10Be reaction rates and calculate its influence to the production of 12C.     

新型多氢键双功能手性酰胺类化合物的高效合成

以BINOL-3,3′-二羧酸为原料,经外消旋化合物的拆分和缩合反应,合成了7个新型的联二萘骨架手性酰胺类化合物,收率51%~70%,其结构经¹H NMR, ¹³C NMR, FT-IR, HR-MS（ESI）和元素分析表征。     

有机硅氧烷改性St/BA/AA三元共聚乳液的制备

采用核壳乳液聚合法,制备了乙烯基三乙氧基硅烷（VTES）改性的St/BA/AA三元共聚乳液,其结构经FT IR确证。研究了VTES用量、乳化剂用量及配比和引发剂用量对单体转化率和粒径的影响。结果表明：在最优条件［48%St, 48%BA, 4%AA, 1%N-MA, 4%VTES, 8%乳化剂（OP-10/SDS=1/3）, 0.8%引发剂］下,单体转化率为95.8%,平均粒径242 nm。并研究了改性St/BA/AA乳胶膜(1)的耐溶剂性和铅笔硬度。结果表明：1具有良好的耐溶剂性,铅笔硬度为2H。