Correlation between 1H FID and T1rho components in heterogeneous polymer systems: an application to SBS

Wideline ¹H FID and relaxation measurements of a relatively simple motionally heterogeneous system, the triblock copolymer styrene–butadiene–styrene, have been performed in a temperature range between the polystyrene and polybutadiene glass transition temperatures. The two FID and the two spin lattice relaxation time in the rotating frame (T_1ρ) components found at each temperature have been correlated by means of a two-dimensional approach. It is shown that this approach allows dynamic information, not accessible simply by interpreting proton T₁ and T_1ρ data, to be revealed. In the case examined, the correlation found could be confirmed by high-resolution ¹H T_1ρ-selective ¹³C Cross Polarization experiments.     

Relativistic quantum field theory with fractional spin and statistics

We construct a relativistic quantum field theory in 2 + 1 dimensions whose Fock states provide a multivalued representation of the Poincaré group. We add a topological term to the action of a scalar field theory and we show that this endows the path integral of the theory with an operator-valued cocycle which modifies the transformation properties of physical states. We demonstrate that one-particle states carry (in general) fractional spin. We determine the spin of many-particle states and we prove a generalized spin-statistics relation. We propose an equation of motion for on-shell states which generalizes naturally the Dirac equation.     

Sur le principe de l'équipartition de l'énergie dans la théorie statistique des milieux continus

Sommaire On formule et démontre un principe d'équipartition de l'énergie dans la thèorie statistique des milieux continus, considérés comme milieux possédant une infinité dénombrable de degrés de liberté. Un tel principe s'accorde avec le principe classique d'é₁uipartition de l'énergie, relatif aux milieux à un nombre fini de degrés de liberté, et il en est une extension naturelle. Travaux exécutés pour la réalisation du programme du Groupe de recherche n^o 7 du C. N. R. (1962–1963). Le principe de l'équipartition de l'énergie, traité dans le § 3 a été établi parB. Forte. Les liaisons entre ce principe et le principe classique ont été developpées par M.lleBraccini, auteur aussi de l'introduction de cet ouvrage.     

INO thermodynamic properties and ultraviolet spectrum

The equilibrium I₂(g) + 2NO(g) = 2INO(g) has been studied at room temperature by ultraviolet absorption spectroscopy. The equilibrium constant has been measured as K_p = (2.7 ± 0.3) × 10^?6 atm^?1 at 298 K. Third-law calculations lead to ΔH°_f,298 (INO) = 120.0 ± 0.3 kJ/mol. The relative absorption spectrum of INO has been measured between 225 and 300 nm. Quantitative measurements gave ?(λ_max = 238 nm) = (1.79 ± 0.5) × 10⁴ L/mol·cm and ?(410 nm) = 234.7 ± 21 L/mol·cm.     

Local Characterization of Starshapedness

The basic intention of this note is to characterize a global condition as the starshapedness of a set S by means of the existence of points of maximal visibility in S, that is a local property.     

Determination of 30 elements in colorectal biopsies by sector field inductively coupled plasma mass spectrometry: method development and preliminary baseline levels

An analytical procedure applicable to restricted sample sizes was developed and applied to the analysis of 30 chemical elements in colorectal biopsies of healthy patients. Acidic microwave digestion processed 相似文献   

Electroanalytical Performance of (SiPy+Cl−/CuTsPc)5 LbL Film for Detecting Promethazine Hydrochloride

A (SiPy⁺Cl^?/CuTsPc)₅ layer‐by‐layer film was employed for the electroanalytical determination of promethazine hydrochloride in BR buffer pH 5.0 with peaks at 0.48 and 0.79 V. After optimisation of the square‐wave parameters (f=100 s^?1, a=40 mV and ΔE_s=2 mV), the peak at 0.79 V was used for quantification and a detection limit of 8.71×10^?9 mol L^?1 and a quantification limit of 9.31×10^?8 were calculated. The applicability of this procedure was tested on commercial formulations of promethazine hydrochloride by observing the stability, specificity, recovery and precision of the procedure in complex samples, without any preliminary treatment.     

CP MAS 13C spectral editing and relative quantitation of a soil sample

A hydrofluoric acid (HF)-treated soil sample was studied by 13C NMR spectroscopy. Cross polarization (CP) Magic Angle Spinning (MAS) 13C spectral editing and relative CP peak quantitation, obtained through variable-contact-time experiments, were used to aid the interpretation of the spectrum. The combination of these two types of experiment allowed to obtain a higher degree of detail on the composition of the sample with respect to a standard CP MAS experiment.