Origin of charge density at LaAlO3 on SrTiO3 heterointerfaces: possibility of intrinsic doping

As discovered by Ohtomo and Hwang, a large sheet charge density with high mobility exists at the interface between SrTiO3 and LaAlO3. Based on transport, spectroscopic, and oxygen-annealing experiments, we conclude that extrinsic defects in the form of oxygen vacancies introduced by the pulsed laser deposition process used by all researchers to date to make these samples is the source of the large carrier densities. Annealing experiments show a limiting carrier density. We also present a model that explains the high mobility based on carrier redistribution due to an increased dielectric constant.     

Distinguishing conventional and distonic radical cations by using dimethyl diselenide

Dimethyl diselenide is demonstrated to be among the most powerful reagents used to identify distonic radical cations. Most such ions readily abstract CH₃Se^. from dimethyl diselenide. The reaction is faster and more exclusive than CH₃S^. abstraction from dimethyl disulfide, a reaction used successfully in the past to identify numerous distonic ions. Very acidic distonic ions, such as HC⁺(OH)OCH^.₂, do not undergo CH₃Se^. abstraction, but instead protonate dimethyl diselenide. In sharp contrast to the reactivity of distonic ions, most conventional radical cations were found either to react by exclusive electron transfer or to be unreactive toward dimethyl diselenide. Hence, this reagent allows distinction of distonic and conventional isomers, which was demonstrated directly by examining two such isomer pairs. To be able to predict whether electron transfer is exothermic (and hence likely to occur), the ionization energy of dimethyl diselenide was determined by bracketing experiments. The low value obtained (7.9 ± 0.1 eV) indicates that dimethyl diselenide will react with many conventional carbon-, sulfur-, and oxygen-containing radical cations by electron transfer. Nitrogen-containing conventional radical cations were found either to react with dimethyl diselenide by electron transfer or to be unreactive.     

Quantitative portfolio selection: Using density forecasting to find consistent portfolios

In the knowledge that the ex-post performance of Markowitz efficient portfolios is inferior to that implied ex-ante, we make two contributions to the portfolio selection literature. Firstly, we propose a methodology to identify the region of risk-expected return space where ex-post performance matches ex-ante estimates. Secondly, we extend ex-post efficient set mathematics to overcome the biases in the estimation of the ex-ante efficient frontier. A density forecasting approach is used to measure the accuracy of ex-ante estimates using the Berkowitz statistic, we develop this statistic to increase its sensitivity to changes in the data generating process. The area of risk-expected return space where the density forecasts are accurate, where ex-post performance matches ex-ante estimates, is termed the consistency region. Under the 'laboratory' conditions of a simulated multivariate normal data set, we compute the consistency region and the estimated ex-post frontier. Over different sample sizes used for estimation, the behaviour of the consistency region is shown to be both intuitively reasonable and to enclose the estimated ex-post frontier. Using actual data from the constituents of the US Dow Jones 30 index, we show that the size of the consistency region is time dependent and, in volatile conditions, may disappear. Using our development of the Berkowitz statistic, we demonstrate the superior performance of an investment strategy based on consistent rather than efficient portfolios.     

Impacts of age on memory for auditory intensity

It is hypothesized that older listeners are more likely than younger listeners to be impaired when asked to make intensity judgments about target tones embedded in rapidly presented auditory sequences. This study examined this hypothesis by asking listeners ranging in age from 19 to 74?yr to make judgments of intensity based on narrowband noise bursts varying in frequency and intensity. In two experiments, listeners made intensity judgments of target bursts alone or embedded in sequences of bursts. In the first experiment, one of four fixed sequences was presented and had to be identified. In the second experiment, pre- or post-trial bursts acted as cues that identified the frequency of the target burst in the sequence. In both experiments, intensity discrimination thresholds for single bursts were good predictors of performance with sequences and were little affected by age. Significant negative relationships between age and accuracy were observed when single sequences had to be identified or a post-trial cue was used, but no age effects were apparent when a pre-trial cue was used. These data are interpreted as being consistent with previous suggestions that the aging process results in a decline in auditory memory capacity and/or internally generated selective attention.     

Hypergolic ionic liquids to mill, suspend, and ignite boron nanoparticles

Boron nanoparticles prepared by milling in the presence of a hypergolic energetic ionic liquid (EIL) are suspendable in the EIL and the EIL retains hypergolicity leading to the ignition of the boron. This approach allows for incorporation of a variety of nanoscale additives to improve EIL properties, such as energetic density and heat of combustion, while providing stability and safe handling of the nanomaterials.     

Quantile regression for index tracking and enhanced indexation

Quantile regression differs from traditional least-squares regression in that one constructs regression lines for the quantiles of the dependent variable in terms of the independent variable. In this paper we apply quantile regression to two problems in financial portfolio construction, index tracking and enhanced indexation. Index tracking is the problem of reproducing the performance of a stock market index, but without purchasing all of the stocks that make up the index. Enhanced indexation deals with the problem of out-performing the index. We present a mixed-integer linear programming formulation of these problems based on quantile regression. Our formulation includes transaction costs, a constraint limiting the number of stocks that can be in the portfolio and a limit on the total transaction cost that can be incurred. Numeric results are presented for eight test problems drawn from major world markets, where the largest of these test problems involves over 2000 stocks.     

Linear Operators that Preserve Commuting Pairs of Nonnegative Real Matrices

A pair of n×n matrices (A, B) is called a commuting pair if AB=BA. We characterize the linear operators that preserve the set of commuting pairs of matrices over a subsemiring of nonnegative real numbers.