Application of time-variable feedback to the input amplifier of pulse magnetic resonance spectrometers: Experimental studies

Experimental research on the improvement of the sensitivity and time resolution of pulsed magnetic resonance spectrometers is discussed. It is shown that application of a time-variable feedback of a signal to the input of the receiver amplifier can decouple, the “fixed” relationship between the quality factorQ and the ringdown time of the resonance system. Experiments were performed with low-frequency, radio-frequency and microwave pulse-type magnetic resonance receivers. Modifications of an S/C-band electron spin echo modulation spectrometer carried out to check the “time-variable feedback” performance are described. It is demonstrated that the application of a time-variable feedback can significantly reduce the ringdown time and improve the recovery properties of the magnetic resonance receiver system. It is also demonstrated that the time-variable feedback can improve the overall receiver sensitivity due to the fact that the working bandwidth of the resonance system can be optimized separately for the transmitting and the receiving mode. Signal values could be increased at least three times and the signal-to-noise ratio about 1.5–2 times. The largest improvement is achieved with the initially overcoupled resonator. Experimental spectra of test samples for different settings of the time-variable feedback are shown.     

Four-Dimensional Lie Group Integration of the Klein–Fock Equation

A method of four-dimensional Lie group integration of the Fock–Klein equation is described in the present paper. The method is based on the formalism of co-adjoint representation orbits and on the non-commutative integration method. Right-invariant metrics being solutions of the Einstein equation are also classified for manifolds of four-dimensional Lie groups.     

A rapid and sensitive extractive spectrophotometric determination of copper(II) in pharmaceutical and environmental samples using benzildithiosemicarbazone.

Benzildithiosemicarbazone (BDTSC) is proposed as a sensitive and selective analytical reagent for the extractive spectrophotometric determination of copper(II). BDTSC reacts with copper(II) in the pH range 1.0-7.0 to form a yellowish complex. Beer's law is obeyed in the concentration range 0.5-0.4 microg cm(-3). The yellowish Cu(II)-BDTSC complex in chloroform shows a maximum absorbance at 380 nm, with molar absorptivity and Sandell's sensitivity values of 1.63 x 10(4) dm3 mol(-1) cm(-1) and 0.00389 microg cm(-2), respectively. A repetition of the method is checked by finding the relative standard deviation (RSD) (n = 10), which is 0.6%. The composition of the Cu(II)-BDTSC complex is established as 1:1 by slope analysis, molar ratio and Asmus' methods. An excellent linearity with a correlation coefficient value of 0.98 is obtained for the Cu(II)-BDTSC complex. The instability constant of the complex calculated from Edmond and Birnbaum's method is 7.70 x 10(-4) and that of Asmus' method is 7.66 x 10(-4), at room temperature. The method is successfully employed for the determination copper(II) in pharmaceutical and environmental samples. The reliability of the method is assured by analyzing the standard alloys (BCS 5g, 10g, 19e, 78, 32a, 207 and 179) and by inter-comparison of experimental values, using an atomic absorption spectrometer.     

Pattern Search Method for Discrete <Emphasis Type="Italic">L</Emphasis><Subscript>1</Subscript>–Approximation

We propose a pattern search method to solve a classical nonsmooth optimization problem. In a deep analogy with pattern search methods for linear constrained optimization, the set of search directions at each iteration is defined in such a way that it conforms to the local geometry of the set of points of nondifferentiability near the current iterate. This is crucial to ensure convergence. The approach presented here can be extended to wider classes of nonsmooth optimization problems. Numerical experiments seem to be encouraging. This work was supported by M.U.R.S.T., Rome, Italy.     

Certain constructions of asymptotic analysis related to the Stone-Čcech compactification

The paper considers the representations of attraction sets in topological spaces and their relations with the relaxation of accessibility problems under the conditions of sequentially relaxed constraints. The author studies the structure of approximate (in essence, asymptotic) solutions and generalized elements and establishes the possibility of their real identification for a certain version (related to the Stone-Čech compactification and the Wallman relaxation) of relaxation of the initial problem. __________ Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 26, Nonlinear Dynamics, 2005.     

Influence of ionizing radiation on the magnetically sensitive properties of planar triacs

Changes in the magnetically sensitive properties of multilayer semiconductors devices, such as planar diffusion triacs, that are related to atomic-displacement-induced defects and ionization by irradiation are considered. It is shown that irradiation may significantly raise the magnetic sensitivity of the triacs. Processes and underlying mechanisms responsible for the improvement of the magnetic sensitivity under the action of a number of galvanomagnetic effects are studied.