Interaction of CdSe/ZnS core-shell semiconductor nanocrystals in solid thin films

The optical properties of CdSe/ZnS semiconductor nanocrystals with the core-shell structure are studied upon visible-laser excitation in a wide range of flux densities. It is demonstrated that the dimensional quantization effect is preserved in the films with a limiting high concentration of nanocrystals. A strong bathochromic shift of the absorption and luminescence peaks relative to the peak positions in the corresponding spectra of nanocrystals in films with a relatively low concentration of nanocrystals and solutions is caused by a high concentration of nanocrystals and the dipole moment related to the asymmetry of the nanoparticles. The shift is varied from 35 to 50 nm depending on the film thickness. The luminescence spectra of the films remain unchanged upon an increase in the laser intensity to 1 × 10⁶ W/cm². The laser action on the nanoparticle films is studied at intensities (5 × 10⁶?1 × 10⁹ W/cm²) higher than the damage threshold.     

Schottky metal library for ZNO-based UV photodiode fabricated by the combinatorial ion beam-assisted deposition

A binary alloy Schottky barrier diode on zinc oxide (ZnO) was developed using the combinatorial ion beam-assisted deposition system. The compositional fraction of the binary alloy was continuously varied using the composition-spread technique, to control the Schottky barrier height. After metal deposition, patterned Schottky diodes were fabricated on a ZnO single-crystal substrate. Pt-Ru alloy was selected from the work function viewpoint. Our experiments showed that the compositional fraction of the Schottky binary alloys changed continuously as designed and the Schottky barrier heights measured by current-voltage (I-V) measurements increased with increasing Pt content. Maximum barrier height difference for ZnO was 137 meV. Using ion beam deposition in parallel with the combinatorial system showed that the Schottky barrier heights for ZnO can be controlled by binary metal alloying.     

On the S-procedure and Some Variants

We give a concise review and extension of S-procedure that is an instrumental tool in control theory and robust optimization analysis. We also discuss the approximate S-Lemma as well as its applications in robust optimization.The many suggestions and detailed corrections of an anonymous referee are gratefully acknowledged.     

Evaluation of fluid-filled fractures during acoustic measurements on tube waves

The problem of reflection, transmission, and conversion of the tube wave on a fracture intersecting a borehole is investigated. We consider the case where an acoustic sonde is placed inside a borehole and the fracture separates two different elastic half-spaces and is filled with a porous material. Bibliography: 5 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 324, 2005, pp. 121–128.     

Controlled structure and density of “living” polystyrene brushes on flat silica surfaces

Thin layers of polystyrene were grown from surface-grafted nitroxide initiators via controlled “living” free radical polymerization. The “reactive” Langmuir-Blodgett deposition method allowed an effective control of the initiator layer density leading to PS brushes with different and high grafting density and stretching. The influence of the grafting density on the layer structure was studied. Comparison with theoretical predictions for monodispersed brushes in bad solvent was discussed. The thickness was found to vary linearly with molecular weight and the density dependence was shown using wetting measurements. Special features of controlled radical nitroxide polymerization from a surface were discussed. A direct comparison of the molecular weight and polydispersity between surface and bulk polymers was made by de-grafting the brushes into a toluene/HF solution. Finally, some evidence of a “surface Fischer” effect was shown from re-initiated layers. Received 20 December 2001     

Symmetry character of collective states in 104Pd populated in the EC-β+ decay of 104Ag

The states of ¹⁰⁴Pd, populated in the EC-β⁺ decay of the ground ( J ^π = 5⁺) and metastable ( J ^π = 2⁺) states of ¹⁰⁴Ag, have been investigated in the framework of the proton-neutron interacting boson model, extending a previous analysis to take into account the newly appeared experimental data. All positive-parity states up to an excitation energy of 3 MeV and spin in the range J = 1-6, fed by more than 0.3% in the decay of the parent nucleus, have been considered. As a result, strong evidence has been found for interpreting most of these states as states of collective nature having a quite pure full- or mixed-symmetry character and, in particular, for identifying the 1⁺ level at 2276 keV as the lowest 1⁺ mixed-symmetry state.     

A Successful Implementation of Locating Passive Cooling Facilities: The Case of Northern Thailand

This paper reports the actual implementation of a location-allocation study, which is one aspect of the overall Passive Cooling (Thailand) Project conducted in Northern Thailand since 1985. The goal has been to generate decision supports for ‘optimal’ placements of cooling facilities and the assignment of sites to these facilities as part of the post-harvest handling-chain operation of agricultural products. The basic questions addressed in this work are the issues of how many facilities to set up and where to locate them for maximum utility. Our selected approach is to use discrete location-allocation modelling, as, among other reasons, the problem at hand has a most natural network setting. Direct methods as well as efficient heuristics are examined, and sample numerical results are reported as illustrations of the continual implementation.