Kinetics of Hydrogen Peroxide Decomposition in Guaiacol Solution, Catalyzed by Hexacyanoferrate(II)

The kinetics of hydrogen peroxide decomposition in a guaiacol solution, catalyzed by potassium hexacyanoferrate(II), were studied. The reaction mainly follows the pathway of guaiacol hydroxylation. The reaction order is 1 with respect to H₂O₂, 0.5 with respect to hexacyanoferrate, and from 0.4 to 0 with respect to guaiacol (the latter parameter decreases with increasing guaiacol concentration). The apparent activation energy is 105 kJ mol^{- 1}. A kinetic scheme of the process was proposed. An expression consistent with the experiment was obtained for the rate of hydrogen peroxide decomposition in the presence of guaiacol, catalyzed by hexacyanoferrate(II).     

Recovery of Butadiene-Styrene Rubber from Latex at Low Temperature with Various Coagulants

The influence of the charge of a metal cation and the nature of a coagulant on the recovery of butadiene-styrene rubber and properties of rubber stocks and vulcanizates was examined.     

An implicit characteristic-flux-averaging method for the euler equations for real gases

A formulation of an implicit characteristic-flux-averaging method for the unsteady Euler equations with real gas effects is presented. Incorporation of a real gas into a general equation of state is achieved by considering the pressure as a function of density and specific internal energy. The Ricmann solver as well as the flux-split algorithm are modified by introducing the pressure derivatives with respect to density and internal energy. Expressions for calculating the values of the flow variables for a real gas at the cell faces are derived. The Jacobian matrices and the eigenvectors are defined for a general equation of state. The solution of the system of equations is obtained by using a mesh-sequencing method for acceleration of the convergence. Finally, a test case for a simple form of equation of state displays the differences from the corresponding solution for an ideal gas.     

The effect of the external lateral electric field on the luminescence intensity of InAs/GaAs quantum dots

We report on low-temperature microphotoluminescence (μ-PL) measurements of InAs/GaAs quantum dots (QDs) exposed to a lateral external electric field. It is demonstrated that the QDs’ PL signal could be increased severalfold by altering the external and/or the internal electric field, which could be changed by an additional infrared laser. A model which accounts for a substantially faster lateral transport of the photoexcited carriers achieved in an external electric field is employed to explain the observed effects. The results obtained suggest that the lateral electric fields play a major role for the dot luminescence intensity measured in our experiment—a finding which could be used to tailor the properties of QD-based optoelectronic applications. The text was submitted by the authors in English.     

Interference inspection of the aspherical components of an objective for nanolithography

Methods and schemes to inspect the EUV mirror shape are developed on the basis of a point diffraction interferometer with computer processing of interferograms. A measurement accuracy to within 0.001 of a wavelength in the visual range is achieved.     

Addendum and Corrigendum to "Local Saturation of Conservative Operators'

In this note we make a correction in the paper [1] by two of the authors. Specifically we modify an auxiliary localization result and prove that the applications to the saturation theory of some outstanding conservative operators remain valid. Moreover, we enrich a corollary dealing with the well-known Szász-Mirakjan operators. This revised version was published online in June 2006 with corrections to the Cover Date.     

Primary abelian <Emphasis Type="Italic">n</Emphasis>-Σ-groups

We prove the following theorem: Any abelian p-group is an n-Σ-group which is a strong ω-elongation of a totally projective group by a p ^ω+n -projective group precisely when it is totally projective. In particular, each p-torsion p ^ω+n -projective n-Σ-group is a direct sum of countable p-groups of length not exceeding ω + n and vice versa. These two claims generalize our recent results in [6] and [7]. Published in Lietuvos Matematikos Rinkinys, Vol. 47, No. 2, pp. 155–162, April–June, 2007.     

Analytical and numerical investigation of two families of Lorenz-like dynamical systems

We investigate two families of Lorenz-like three-dimensional nonlinear dynamical systems (i) the generalized Lorenz system and (ii) the Burke–Shaw system. Analytical investigation of the former system is possible under the assumption (I) which in fact concerns four different systems corresponding to  = ±1, m = 0, 1.

(I)

The fixed points and stability characteristics of the Lorenz system under the assumption (I) are also classified. Parametric and temporal (t → ∞) asymptotes are also studied in connection to the memory of both the systems. We calculate the Lyapunov exponents and Lyapunov dimension for the chaotic attractors in order to study the influence of the parameters of the Lorenz system on the attractors obtained not only when the assumption (I) is satisfied but also for other values of the parameters σ, r, b, ω and m.     

Sets of reflections defining twisted Bruhat orders

Twisted Bruhat orders are certain partial orders on a Coxeter system (W,S) associated to initial sections of reflection orders, which are certain subsets of the set of reflections T of a Coxeter system. We determine which subsets of T give rise to a partial order on W in the same way.