全文获取类型
收费全文 | 393761篇 |
免费 | 5108篇 |
国内免费 | 1151篇 |
专业分类
化学 | 209133篇 |
晶体学 | 5795篇 |
力学 | 17679篇 |
综合类 | 7篇 |
数学 | 45743篇 |
物理学 | 121663篇 |
出版年
2020年 | 3259篇 |
2019年 | 3572篇 |
2018年 | 4742篇 |
2017年 | 4537篇 |
2016年 | 7156篇 |
2015年 | 4801篇 |
2014年 | 7070篇 |
2013年 | 17714篇 |
2012年 | 14192篇 |
2011年 | 17127篇 |
2010年 | 11742篇 |
2009年 | 11399篇 |
2008年 | 15565篇 |
2007年 | 15617篇 |
2006年 | 14619篇 |
2005年 | 13359篇 |
2004年 | 12046篇 |
2003年 | 10483篇 |
2002年 | 10334篇 |
2001年 | 10853篇 |
2000年 | 8382篇 |
1999年 | 6547篇 |
1998年 | 5621篇 |
1997年 | 5456篇 |
1996年 | 5259篇 |
1995年 | 4736篇 |
1994年 | 4754篇 |
1993年 | 4703篇 |
1992年 | 5055篇 |
1991年 | 5241篇 |
1990年 | 4855篇 |
1989年 | 4799篇 |
1988年 | 4758篇 |
1987年 | 4558篇 |
1986年 | 4298篇 |
1985年 | 5869篇 |
1984年 | 6145篇 |
1983年 | 4933篇 |
1982年 | 5365篇 |
1981年 | 5139篇 |
1980年 | 4967篇 |
1979年 | 5164篇 |
1978年 | 5429篇 |
1977年 | 5179篇 |
1976年 | 5375篇 |
1975年 | 4955篇 |
1974年 | 5035篇 |
1973年 | 5021篇 |
1972年 | 3457篇 |
1971年 | 2898篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.
Ukrainian Mathematical Journal - We establish new criteria of compatibility for a linear system of equations (equivalent to the Kronecker–Capelli theorem) or inequalities (equivalent to the... 相似文献
33.
Restricted testing conditions were considered recently. For the maximal operator, Hytönen, Li and Sawyer [8] first obtained parental testing condition. Later, they [9] showed that it suffices to restrict testing to doubling cubes. Chen and Lacey [3] gave a similar restricted testing condition. In our paper, we discuss a version of the latter in the multilinear setting.
相似文献34.
Corinne Rondeau-Mouro Mireille Cambert Laurent Blondel Yves Diascorn Léo Mbaya Nor Nadiah Binti Ahmad Nazari Sarah Helary Tiphaine Lucas 《Magnetic resonance in chemistry : MRC》2022,60(7):678-691
A temperature control unit was implemented to vary the temperature of samples studied on a commercial Mobile Universal Surface Explorer nuclear magnetic resonance (MOUSE-NMR) apparatus. The device was miniaturized to fit the maximum MOUSE sampling depth (25 mm). It was constituted by a sample holder sandwiched between two heat exchangers placed below and above the sample. Air was chosen as the fluid to control the temperature at the bottom of the sample, at the interface between the NMR probe and the sample holder, in order to gain space. The upper surface of the sample was regulated by the circulation of water inside a second heat exchanger placed above the sample holder. The feasibility of using such a device was demonstrated first on pure water and then on several samples of bread dough with different water contents. For this, T1 relaxation times were measured at various temperatures and depths and were then compared with those acquired with a conventional compact closed-magnet spectrometer. Discussion of results was based on biochemical transformations in bread dough (starch gelatinization and gluten heat denaturation). It was demonstrated that, within a certain water level range, and because of the low magnetic field strength of the MOUSE, a linear relationship could be established between T1 relaxation times and the local temperature in the dough sample. 相似文献
35.
Crystallography Reports - Some questions related to the establishment, development, and prospects of physical studies using inelastic thermal-neutron scattering are briefly reviewed. The directions... 相似文献
36.
Avrutskiy V. I. Ishkhanyan A. M. Krainov V. P. 《Theoretical and Mathematical Physics》2021,208(3):1201-1206
Theoretical and Mathematical Physics - The fractional derivative method is used to take wave dispersion into account in the wave equation when describing the propagation of gravitational soliton... 相似文献
37.
S. Venkatesan S. Suresh P. Ramu M. Kandasamy J. Arumugam S. Thambidurai K.M. Prabu N. Pugazhenthiran 《印度化学会志》2022,99(5):100436
A facile biosynthesis route was followed to prepare zinc oxide nanoparticles (ZnO NPs) using Euphorbia milii (E. milii) leaf constituents. The SEM images exhibited presence of spherical ZnO NPs and the corresponding TEM images disclosed monodisperse nature of the ZnO NPs with diameter ranges between 12 and 20 nm. The Brunauer–Emmett–Teller (BET) analysis revealed that the ZnO NPs have specific surface area of 20.46 m2/g with pore diameter of 2 nm–10 nm and pore volume of 0.908 cm3/g. The EDAX spectrum exemplified the existence of Zn and O elements and non-appearance of impurities that confirmed pristine nature of the ZnO NPs. The XRD pattern indicated crystalline peaks corresponding to hexagonal wurtzite structured ZnO with an average crystallite size of 16.11 nm. The FTIR spectrum displayed strong absorption bands at 512 and 534 cm?1 related to ZnO. The photocatalytic action of ZnO NPs exhibited noteworthy degradation of methylene blue dye under natural sunlight illumination. The maximum degradation efficiency achieved was 98.17% at an illumination period of 50 min. The reusability study proved considerable photostability of the ZnO NPs during photocatalytic experiments. These findings suggest that the E. milii leaf constituents can be utilized as suitable biological source to synthesis ZnO NPs for photocatalytic applications. 相似文献
38.
Crystallography Reports - Methods of coherent X-ray diffraction imaging of the spatial structure of noncrystalline objects and nanocrystals (nanostructures) are considered. Particular attention is... 相似文献
39.
40.
Laurens Kooijman Dr. Matthias Schuster Christian Baumann Simon Jurt Dr. Frank Löhr Dr. Boris Fürtig Prof. Dr. Peter Güntert Prof. Dr. Oliver Zerbe 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21151-21158
To achieve efficient proton pumping in the light-driven proton pump bacteriorhodopsin (bR), the protein must be tightly coupled to the retinal to rapidly convert retinal isomerization into protein structural rearrangements. Methyl group dynamics of bR embedded in lipid nanodiscs were determined in the dark-adapted state, and were found to be mostly well ordered at the cytosolic side. Methyl groups in the M145A mutant of bR, which displays only 10 % residual proton pumping activity, are less well ordered, suggesting a link between side-chain dynamics on the cytosolic side of the bR cavity and proton pumping activity. In addition, slow conformational exchange, attributed to low frequency motions of aromatic rings, was indirectly observed for residues on the extracellular side of the bR cavity. This may be related to reorganization of the water network. These observations provide a detailed picture of previously undescribed equilibrium dynamics on different time scales for ground-state bR. 相似文献