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991.
Polycarbonates and copolycarbonates based on BPSi and BPA were easily made using the standard interfacial technique. Molecular weight and NMR data indicate that up to 4 mol % of the BPSi decomposes during polymerization via a base-catalyzed rearrangement of BPSi to arylsiloxanes. Oxygen index studies show an increased flame resistance with increasing BPSi monomer content. DSC measurements show a decrease in glass transition with BPSi monomer concentration while TGA shows an increase in char residue with BPSi monomer content. In addition, TGA indicates no change in either thermal or thermooxidative stability with the relative BPSi/BPA concentrations. Outdoor weathering of BPSi PC and BPA PC films indicates that BPSi PC is ca. 5 times more weathering resistant than BPA PC. This latter result can be attributed to a combination of BPSi PC's lower UV absorptivity, higher water repellency, and lower likelihood for side chain photooxidation. © 1993 John Wiley & Sons, Inc. 相似文献
992.
993.
U. Weisbrod R. Gutschke J. Knoth H. Schwenke 《Fresenius' Journal of Analytical Chemistry》1991,341(1-2):83-86
Summary Single layers and layer systems on diverse substrates were measured by Total Reflection X-Ray Fluorescence (TXRF) spectrometry. The angular dependence of the fluorescence intensities at grazing incidence allows the elemental composition, density and thickness of the layers to be evaluated using model calculations. 相似文献
994.
995.
Isothermal vapor-liquid equilibrium (VLE) data, at 25° C were determined by a saturation method for each of the six methanol or methyl acetate binary systems with dichloromethane, chloroform, and 1,2-trans-dichloroethylene. The experimental data satisfy the Redlich-Kister consistency test, and were correlated with five Gibbs free energy models. All the binary mixtures of methanol with the chlorinated compounds exhibit strong positive deviations from ideality while the mixtures of methyl acetate with the chlorinated compounds present negative deviations from ideal behavior.Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60th birthday, Clermont-Ferrand, France, 17–18 May 1990. 相似文献
996.
P. Schuurmans J. Wouters P. De Moor N. Severijns W. Vanderpoorten J. Vanhaverbeke L. Vanneste 《Hyperfine Interactions》1992,75(1-4):423-430
Anisotropic α-emission from nuclei in the decay chain from223Ra to207Tl has been observed using low temperature nuclear orientation in combination with high resolution α-detection at 4.2 K. Information
on partial wave amplitudes as well as hyperfine interactions has been extracted. 相似文献
997.
W. Królas A. Maj P. Bednarczyk B. Fornal W. Mceczynski J. Styczeń M. Zicebliński 《Zeitschrift für Physik A Hadrons and Nuclei》1992,344(2):145-147
High-energy gamma-rays emitted in the decay of the giant dipole resonance built on excited states of55Mn nucleus were measured with a bismuth germanate detector. Resonance parameters were extracted from the fits to the experimental spectra. Two new high-energy calibration points originating from slow-neutron capture in germanium isotopes of bismuth germanate crystal are proposed for large-volume BGO detectors. 相似文献
998.
H. Tsertos E. Berdermann F. Bosch M. Clemente S. Huchler P. Kienle W. Koenig C. Kozhuharov 《Zeitschrift für Physik A Hadrons and Nuclei》1992,342(1):79-94
We present the results obtained from systematic studies of positron creation for a series of heavy-collision systems, with united chargeZ u =Z 1 +Z 2 ranging fromZ u =164 (Pb + Pb) toZ u =184 (U+U) at bombarding energies close to the Coulomb barrier, using the Orangeβ-spectrometer at GSI. For each collision system studied, the dominating continuous distributions due to quasiatomic and nuclear positron emission are determined accurately. This is essential in obtaining the characteristics of the still unexplained monoenergetic positron lines which appear in the energy range between 200 keV and 400 keV. Our results are compared with coupled-channels calculations for quasi-atomic positron creation. The latter describe quite well the global features of the measured spectra, but overestimate systematically their absolute values. From the comparison, a common normalization factor of about 0.75 can be established for the calculated spectra. In particular, the dependence onZ u of the measured emission probabilities was found to follow a power law (∝Z u 195±1), in fair agreement with the theoretical prediction. 相似文献
999.
J. Kircher M. Cardona M. Alouani S. Gopalan O. Jepsen O. K. Andersen
E. Kaldis
J. Karpinski S. Rusieki 《Physica C: Superconductivity and its Applications》1992,200(3-4):413-417We report results of ellipsometric measurements of the dielectric tensor of YBa2Cu4O8 as well as calculations employing density functional theory in the local density approximation (LDA). For the computation of the one-electron eigenvalues and states the linear-muffin-tin-orbital method (LMTO) was used. Measured and calculated results show good agreement. In particular, the calculation predicts different band structures for YBa2Cu3O7 and YBa2Cu4O8 in the vicinity of the Fermi energy which lead to significant differences in the optical spectra. One such difference is a region of small ε2 in the near infrared which is a fingerprint of the high (relative to the top of the highest fully occupied band) Fermi energy as compared to the situation in YBa2Cu3O7. Our experimental results confirm the theoretical findings. 相似文献
1000.