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81.
K. Yanada M. Sakairi T. Kikuchi Y. Oya Y. Kojima 《Surface and interface analysis : SIA》2010,42(4):189-193
An in situ artificial micro‐pit fabrication method with an area selective electrochemical measurement technique was applied to investigate the effect of the geometry of artificially formed pits on their localized corrosion behavior in anodized 1000 series aluminum. This technique enables the fabrication of artificial micro‐pits with different aspect ratios (pit depth/pit diameter) in solutions. The aspect ratios of the fabricated artificial micro‐pits in this experiment could be varied from 0.13 to 1.83 by controlling the irradiation time of the focused pulsed YAG laser beam. By applying a constant potential to the final laser‐beam‐irradiated spot in chloride environments, localized dissolution occurred only at the laser beam irradiated area, because the anodic oxide film acted as an insulator. The corrosion current and charge increase with increasing aspect ratio at any applied potential. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
82.
A separation/preconcentration procedure based on the coprecipitation of Pb(II), Fe(III), Co(II), Cr(III) and Zn(II) ions with copper(II)-N-benzoyl-N-phenyl-hydroxylamine complex (Cu-BPHA) has been developed. The analytical variables including pH, amount of BPHA, amount of copper(II) as carrier element, and sample volume were investigated for the quantitative recoveries of the elements. No interfering effects were observed from the concomitant ions when present in real samples. The recoveries of the analyte ions were in the range of 95–100%. The detection limits (3 s) for Pb(II), Co(II), Fe(III), Cr(III) and Zn(II) ions were found to be 2.3, 0.7, 0.7, 0.3 and 0.4 µg L?1, respectively. The validation of the procedure was performed by the analysis of CRM (SRM NIST-1547 peach leaves and LGC6019 river water) standard reference materials. The method was applied to the determination of the analytes in real samples including natural waters, hair, urine, soil, sediment and peritoneal fluids samples etc., and good results were obtained (relative standard deviations <4%, recoveries >95%). 相似文献
83.
Radiation-induced graft polymerization is one of the best methods for obtaining materials with new properties. In this work, radiation grafting of 2-chloroacrylonitrile to cellulose by mutual and pre-irradiation grafting methods was investigated. The grafting yield was enhanced by applying the emulsion grafting method. The grafting yield determined in the above systems was observed as 27% at highest and 6% at lowest. The effects of concentration of monomer, reaction time and reaction temperature on grafting yield were studied. Evidence of grafting has been based on the comparative studies of cellulose and grafted cellulose by infrared spectroscopy, thermal analysis and contact angle measurement. Grafting enhances thermal stability of cellulose backbone. 相似文献
84.
Marian Vîrgolici Corneliu Ponta Mihaela Manea Daniel Neguţ Mihalis Cutrubinis Ioan Moise Rareş Şuvăilă Eugen Teodor Costel Sârbu Andrei Medvedovici 《Journal of chromatography. A》2010,1217(12):1977-1987
Research on the chemical composition of fossil resins has evolved during the last decades as a multidisciplinary field and is strongly oriented toward the correlation with their geological and botanical origin. Various extraction procedures and chromatographic techniques have been used together for identifying the volatile compounds contained in the fossil resin matrix. Hyphenation between thermal desorption (TD), gas chromatography (GC) and mass spectrometry detection (MS) has been chosen to investigate the volatile compounds fraction from ambers with a focus on Romanite (Romanian amber) and Baltic amber species. A data analysis procedure was developed for the main purpose of fingerprinting ambers based on the MS identity of the peaks generated by the volatile fraction, together with their relative percentual area within the chromatogram. Chromatographic data analysis was based entirely on Automated Mass Spectral Deconvolution & Identification System (AMDIS) software to produce deconvoluted mass spectra which were used to build-up a mixed mass spectra and relative retention scale library. Multivariate data analysis was further applied on AMDIS results with successful discrimination between Romanite and Baltic ambers. A special trial was conducted to generate pyrolysis “like” macromolecular structure breakdown to volatile compounds by gamma irradiation with a high absorbed dose of 500 kGy. Contrary to our expectations the volatile fraction fingerprints were not modified after irradiation experiments. A complementary non-destructive new approach by ESR spectroscopy was also proposed for discriminating between Romanite and Baltic ambers. 相似文献
85.
Erdoğan Şen Serkan Araci Mehmet Acikgoz 《Mathematical Methods in the Applied Sciences》2014,37(17):2619-2625
In this work, we study the asymptotic properties of a new Sturm–Liouville problem with retarded argument. Contrary to previous works, differential equation includes eigenparameter as a quadratic function. In the considered problem arise new difficulties. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
86.
Mustafa Özdemir Melek Erdoğdu Hakan Şimşek 《Advances in Applied Clifford Algebras》2014,24(1):179-192
In this paper, we examine eigenvalue problem of a rotation matrix in Minkowski 3 space by using split quaternions. We express the eigenvalues and the eigenvectors of a rotation matrix in term of the coefficients of the corresponding unit timelike split quaternion. We give the characterizations of eigenvalues (complex or real) of a rotation matrix in Minkowski 3 space according to only first component of the corresponding quaternion. Moreover, we find that the casual characters of rotation axis depend only on first component of the corresponding quaternion. Finally, we give the way to generate an orthogonal basis for ${\mathbb{E}^{3}_{1}}$ by using eigenvectors of a rotation matrix. 相似文献
87.
Vagif Sabir Guliyev Turhan Karaman Rza Chingiz Mustafayev Ayhan Şerbetçi 《Czechoslovak Mathematical Journal》2014,64(2):365-386
In this paper, the boundedness of a large class of sublinear commutator operators T b generated by a Calderón-Zygmund type operator on a generalized weighted Morrey spaces \({M_{p,\varphi }}(w)\) with the weight function w belonging to Muckenhoupt’s class A p is studied. When 1 < p < ∞ and b ∈ BMO, sufficient conditions on the pair (φ 1, φ 2) which ensure the boundedness of the operator T b from \({M_{p,\varphi 1}}(w)\) to \({M_{p,\varphi 2}}(w)\) are found. In all cases the conditions for the boundedness of T b are given in terms of Zygmund-type integral inequalities on (φ 1, φ 2), which do not require any assumption on monotonicity of φ 1(x, r), φ 2(x, r) in r. Then these results are applied to several particular operators such as the pseudo-differential operators, Littlewood-Paley operator, Marcinkiewicz operator and Bochner-Riesz operator. 相似文献
88.
A collocation method based on the Bessel functions of the first kind for singular perturbated differential equations and residual correction 下载免费PDF全文
Şuayip Yüzbaşı 《Mathematical Methods in the Applied Sciences》2015,38(14):3033-3042
In this paper, a collocation method is given to solve singularly perturbated two‐point boundary value problems. By using the collocation points, matrix operations and the matrix relations of the Bessel functions of the first kind and their derivatives, the boundary value problem is converted to a system of the matrix equations. By solving this system, the approximate solution is obtained. Also, an error problem is constructed by the residual function, and it is solved by the presented method. Thus, the error function is estimated, and the approximate solutions are improved. Finally, numerical examples are given to show the applicability of the method, and also, our results are compared by existing results. Copyright © 2014 JohnWiley & Sons, Ltd. 相似文献
89.
Positivity - Many researchers have been interested in the concept of statistical convergence because of the fact that it is stronger than the classical convergence. Also, the concepts of... 相似文献
90.