Air-cooled gas-turbine discs: a review of recent research

The flow between corotating compressor or turbine discs and the flow between a turbine disc and an adjacent stationary casing can be respectively modelled by a rotating cavity and by a rotor-stator system. This paper reviews some of the recent experimental and theoretical work on flow and heat transfer in these two classes of rotating-disc systems. Comparisons between the theoretical and measured distributions of velocity, pressure, and Nusselt numbers are made for the rotating cavity with a superimposed radial flow of cooling air. For the rotor-stator system, some recent work on the fluid dynamics is outlined, and particular mention is made of the so-called “ingress problem” and of the use of pre-swirl air to improve the blade-cooling effectiveness.     

The interrelation between void fraction fluctuations and flow patterns in two-phase flow

A fast response, linearized X-ray void measurement system has been used to obtain statistical measurements in normally fluctuating air-water flow in a rectangular channel. It is demonstrated that the probability density function (PDF) of the fluctuations in void fraction may be used as an objective and quantitative flow pattern discriminator for the three dominant patterns of bubbly, slug, and annular flow. This concept is applied to data over the range of 0.0 to 37 m/sec mixture velocities to show that slug flow is simply a transitional, periodic time combination of bubbly and annular flows. Film thicknesses calculated from the PDF data are similar in magnitude in both slug and annular flows. Calculation of slug length and residence time ratios along with bubble lengths in slug flow are also readily obtainable from the statistical measurements. Spectral density measurements showed bubbly flow to be stochastic while slug and annular flows showed periodicities correlatable in terms of the liquid volume flux.     

Aryl-aryl bond formation by the fluoride-free cross-coupling of aryldisiloxanes with aryl bromides

The prevalence of the biaryl structural motif in biologically interesting and synthetically important molecules has inspired considerable interest in the development of methods for aryl-aryl bond formation. Herein we describe a novel strategy for this process involving the fluoride-free, palladium-catalysed cross-coupling of readily accessible aryldisiloxanes and aryl bromides. Using a statistical-based optimisation process, preparatively useful reaction conditions were formulated to allow the cross-coupling of a wide range of different substrates. This methodology represents an attractive, cost-efficient, flexible and robust alternative to the traditional transition-metal-catalysed routes typically used to generate molecules containing the privileged biaryl scaffold.     

Differentiation of Regioisomeric Aromatic Ketocarboxylic Acids by Positive Mode Atmospheric Pressure Chemical Ionization Collision-Activated Dissociation Tandem Mass Spectrometry in a Linear Quadrupole Ion Trap Mass Spectrometer

Positive-mode atmospheric pressure chemical ionization tandem mass spectrometry (APCI-MS ⁿ ) was tested for the differentiation of regioisomeric aromatic ketocarboxylic acids. Each analyte forms exclusively an abundant protonated molecule upon ionization via positive-mode APCI in a commercial linear quadrupole ion trap (LQIT) mass spectrometer. Energy-resolved collision-activated dissociation (CAD) experiments carried out on the protonated analytes revealed fragmentation patterns that varied based on the location of the functional groups. Unambiguous differentiation between the regioisomers was achieved in each case by observing different fragmentation patterns, different relative abundances of ion-molecule reaction products, or different relative abundances of fragment ions formed at different collision energies. The mechanisms of some of the reactions were examined by H/D exchange reactions and molecular orbital calculations.     

Metallosurfactants of bioinorganic interest: Coordination-induced self assembly

This review covers selected surfactant ligands that undergo a change in aggregate morphology upon coordination of a metal ion, with a particular focus on coordination-induced micelle-to-vesicle transitions. The surfactants include microbially produced amphiphilic siderophores, as well as synthetic amphiphilic ligands. The mechanism of the metal-induced phase change is considered in light of the coordination chemistry of the metal ions, the nature of the ligands, and changes in molecular geometry that result from metal coordination. Of particular interest are biologically produced amphiphiles that coordinate transition metal ions and amphiphilic ligands of relevance to bioinorganic chemistry.     

Trusted Threat Intelligence Sharing in Practice and Performance Benchmarking through the Hyperledger Fabric Platform

Historically, threat information sharing has relied on manual modelling and centralised network systems, which can be inefficient, insecure, and prone to errors. Alternatively, private blockchains are now widely used to address these issues and improve overall organisational security. An organisation’s vulnerabilities to attacks might change over time. It is utterly important to find a balance among a current threat, the potential countermeasures, their consequences and costs, and the estimation of the overall risk that this provides to the organisation. For enhancing organisational security and automation, applying threat intelligence technology is critical for detecting, classifying, analysing, and sharing new cyberattack tactics. Trusted partner organisations can then share newly identified threats to improve their defensive capabilities against unknown attacks. On this basis, organisations can help reduce the risk of a cyberattack by providing access to past and current cybersecurity events through blockchain smart contracts and the Interplanetary File System (IPFS). The suggested combination of technologies can make organisational systems more reliable and secure, improving system automation and data quality. This paper outlines a privacy-preserving mechanism for threat information sharing in a trusted way. It proposes a reliable and secure architecture for data automation, quality, and traceability based on the Hyperledger Fabric private-permissioned distributed ledger technology and the MITRE ATT&CK threat intelligence framework. This methodology can also be applied to combat intellectual property theft and industrial espionage.     

Das Atomgewicht des Palladiums

Ohne Zusammenfassung