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111.
Two disperse dyestuffs, though exhibiting similar behaviour upon TG-DTG-DTA, have different dyeing properties. Thermoanalytical investigations are not sufficient to predict dyeing characteristics and fastness.
Zusammenfassung Zwei Dispersionsfarbstoffe, die sich bei der TG-DTG-DTA ähnlich verhalten, zeigen unterschiedliche Färbeeigenschaften. Thermoanalytische Untersuchungen sind nicht ausreichend, um Färbeeigenschaften und die Farbechteheit vorherzusagen.
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112.
Methods that rapidly evaluate molecular complexity and synthetic feasibility are becoming increasingly important for in silico chemistry. We propose a new metric based on relative atomic electronegativities and bond parameters that evaluate both synthetic and molecular complexity (SMCM) starting from chemical structures. Against molecular weight, SMCM has the lowest fraction of adjusted variance (R2=0.535) on a series of 261,048 diverse compounds, when compared to the complexity metric of Baron and Chanon (R2=0.777; J. Chem. Inf. Comput. Sci. 2001, 41, 269-272) and Rücker (R2=0.895 for log complexity values; J. Chem. Inf. Comput. Sci. 2004, 44, 378-386), respectively. These metrics are in general agreement when the metabolic synthesis of cholesterol from S-3-hydroxy-3-methyl-glutaryl coenzyme A is monitored, indicating that SMCM can be useful in discerning increases in complexity. Because the presence of substructure patterns can be directly incorporated into this scheme, SMCM is relatively straightforward and can be easily tailored to rapidly evaluate virtual (combinatorial) libraries and high throughput screening hits. 相似文献
113.
We prove that the strange duality conjecture of Beauville–Donagi–Tu holds for all curves. We establish first a more extended
level-rank duality, interesting in its own right, from which the standard level-rank duality follows by restriction. 相似文献
114.
The modulational stability of travelling waves in 2D anisotropic systems is investigated. We consider normal travelling waves,
which are described by solutions of a globally coupled Ginzburg–Landau system for two envelopes of left- and right-travelling
waves, and oblique travelling waves, which are described by solutions of a globally coupled Ginzburg–Landau system for four
envelopes associated with two counterpropagating pairs of travelling waves in two oblique directions. The Eckhaus stability
boundary for these waves in the plane of wave numbers is computed from the linearized Ginzburg–Landau systems. We identify
longitudinal long and finite wavelength instabilities as well as transverse long wavelength instabilities. The results of
the stability calculations are confirmed through numerical simulations. In these simulations we observe a rich variety of
behaviors, including defect chaos, elongated localized structures superimposed to travelling waves, and moving grain boundaries
separating travelling waves in different oblique directions. The stability classification is applied to a reaction–diffusion
system and to the weak electrolyte model for electroconvection in nematic liquid crystals.
相似文献
115.