全文获取类型
收费全文 | 711篇 |
免费 | 45篇 |
国内免费 | 3篇 |
专业分类
化学 | 509篇 |
晶体学 | 8篇 |
力学 | 17篇 |
数学 | 108篇 |
物理学 | 117篇 |
出版年
2023年 | 4篇 |
2022年 | 13篇 |
2021年 | 13篇 |
2020年 | 25篇 |
2019年 | 13篇 |
2018年 | 6篇 |
2017年 | 11篇 |
2016年 | 20篇 |
2015年 | 22篇 |
2014年 | 20篇 |
2013年 | 31篇 |
2012年 | 60篇 |
2011年 | 58篇 |
2010年 | 44篇 |
2009年 | 21篇 |
2008年 | 59篇 |
2007年 | 44篇 |
2006年 | 38篇 |
2005年 | 34篇 |
2004年 | 23篇 |
2003年 | 18篇 |
2002年 | 18篇 |
2001年 | 9篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 7篇 |
1939年 | 3篇 |
1924年 | 2篇 |
排序方式: 共有759条查询结果,搜索用时 15 毫秒
61.
Distributions of simultaneous fiber failures—bursts—in loaded fiber bundles are studied considering inertia and damping. Resulting burst size distributions have universal properties: all approach the power law DΔΔ−2.5 for larger burst sizes Δ. Momentary burst size distributions evolve with increasing damage and do not follow power laws but are still universal. Finally, it is briefly outlined how to use distribution progression to assess damage state. 相似文献
62.
Karolien De Wael Sandra Van Vlierberghe Hans Buschop Peter Dubruel Bart Vekemans Etienne Schacht Laszlo Vincze Annemie Adriaens 《Surface and interface analysis : SIA》2009,41(5):389-393
The aim of the present paper is to characterize a cross‐linked horse heart cytochrome c (HHC) film on cysteamine‐modified gold electrodes. The HHC film was deposited using 1‐ethyl‐3‐(3‐dimethylaminopropyl)‐carbodiimide (EDC) as a coupling agent. Attenuated total reflection infrared (ATR‐IR) spectroscopic analyses were performed to characterize the newly formed surface on a qualitative and conformational level. The film thickness was measured using a noncontact optical surface profiler, while quantitative data and information on the heterogeneity of the film were obtained by means of synchrotron radiation X‐ray micro fluorescence (SR micro‐XRF). Results indicate that, in addition to electrochemical studies, spectroscopic analysis methods are essential to gain insight in the effect of immobilization strategies on protein conformations. The latter is of relevance in the development and optimization of biosensors. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
63.
Etienne Airiau Thomas Spangenberg Nicolas Girard Dr. Angèle Schoenfelder Jessica Salvadori Maurizio Taddei Prof. André Mann Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(35):10938-10948
The development of hydroformylative domino reactions of easily accessible vinyl acetamides is described. Extremely regioselective hydroformylation of terminal double bounds provides a transient N‐acyliminium that can be trapped by various nucleophiles to give several aza‐heterocylic scaffolds in a diastereoselective manner. 相似文献
64.
65.
Ferdinand Tantangmo Bruno Ndjakou Lenta Silvre Ngouela Louis Marie Kamdem Bernard Weniger Etienne Tsamo Annelise Lobstein Catherine Vonthron‐Sncheau 《Helvetica chimica acta》2010,93(11):2210-2217
Phytochemical investigation of the bark and leaves of Pancovia laurentii (Sapindaceae) resulted in the isolation of a new ceramide and a new cerebroside, named pancoviamide ( 1 ), and pancovioside ( 2 ) respectively, together with six known compounds: uracil, (R)‐N‐[(1S,2S,3R)‐2,3‐dihydroxy‐1‐(hydroxymethyl)heptadec‐5‐en‐1‐yl]‐2‐hydroxytetracosanamide, stigmasta‐7,22‐dien‐3‐ol, β‐stitosterol, β‐sitosterol 3‐O‐β‐D ‐glucopyranoside, and 2,3‐dihydroxypropyl pentadecanoate. The structures of 1 and 2 were determined by means of spectroscopic methods. Compounds 1 and 2 were tested in vitro for their antiprotozoal properties against several protozoa and for their cytotoxicity. 相似文献
66.
Structural transformations induced in gamma and alpha globulins under influence of gamma irradiation using doses of 2.5 and
24 kGy were studied by differential scanning calorimetry (DSC) and thermogravimetry (TG, DTG). Thermal decomposition of the
globulins irradiated in water suspensions occurs at higher temperatures, in comparison to the reference non-irradiated samples.
This was related to formation of covalent linkages in the irradiated proteins, apart to chemical changes induced in amino-acids.
Essential modification of thermal decomposition was detected already after irradiation with a dose of 2.5 kGy performed for
water suspensions. Irradiation of solid native proteins induces decrease in decomposition temperature and gives evidence of
proteins degradation. 相似文献
67.
Dr. Gilles Alcaraz Dr. Sylviane Sabo‐Etienne 《Angewandte Chemie (International ed. in English)》2010,49(40):7170-7179
There have been a number of approaches developed for the catalyzed dehydrogenation of amine–boranes as potential dihydrogen sources for hydrogen storage applications in recent years. Key advances in this area have been recently made thanks to catalytic and stoichiometric studies. In this Minireview, the fate of amine–boranes upon coordination to a metal center is discussed with a particular emphasis on B? H activation pathways. We focus on the few cases in which coordination of the resulting dehydrogenated product could be achieved, which includes the coordination of aminoborane, the simplest unit resulting from dihydrogen release of ammonia–borane. 相似文献
68.
Tim Desmet T. Billiet Elke Berneel Ria Cornelissen David Schaubroeck Etienne Schacht Peter Dubruel 《Macromolecular bioscience》2010,10(12):1484-1494
In the last decade, substantial research in the field of post‐plasma grafting surface modification has focussed on the introduction of carboxylic acids on surfaces by grafting acrylic acid (AAc). In the present work, we report on an alternative approach for biomaterial surface functionalisation. Thin poly‐ε‐caprolactone (PCL) films were subjected to a dielectric barrier discharge Ar‐plasma followed by the grafting of 2‐aminoethyl methacrylate (AEMA) under UV‐irradiation. X‐ray photoelectron spectroscopy (XPS) confirmed the presence of nitrogen. The ninhydrin assay demonstrated, both quantitatively and qualitatively, the presence of free amines on the surface. Confocal fluorescence microscopy (CFM), atomic force microscopy (AFM) and scanning electron microscopy (SEM) were used to visualise the grafted surfaces, indicating the presence of pAEMA. Static contact angle (SCA) measurements indicated a permanent increase in hydrophilicity. Furthermore, the AEMA grafted surfaces were applied for comparing the physisorption and covalent immobilisation of gelatin. CFM demonstrated that only the covalent immobilisation lead to a complete coverage of the surface. Those gelatin‐coated surfaces obtained were further coated using fibronectin. Osteosarcoma cells demonstrated better cell‐adhesion and cell‐viability on the modified surfaces, compared to the pure PCL films.
69.
Melting in two spatial dimensions, as realized in thin films or at interfaces, represents one of the most fascinating phase transitions in nature, but it remains poorly understood. Even for the fundamental hard-disk model, the melting mechanism has not been agreed upon after 50 years of studies. A recent Monte?Carlo algorithm allows us to thermalize systems large enough to access the thermodynamic regime. We show that melting in hard disks proceeds in two steps with a liquid phase, a hexatic phase, and a solid. The hexatic-solid transition is continuous while, surprisingly, the liquid-hexatic transition is of first order. This melting scenario solves one of the fundamental statistical-physics models, which is at the root of a large body of theoretical, computational, and experimental research. 相似文献
70.
Structure-preserving numerical schemes for a nonlinear parabolic fourth-order equation, modeling the electron transport in quantum semiconductors, with periodic boundary conditions are analyzed. First, a two-step backward differentiation formula (BDF) semi-discretization in time is investigated. The scheme preserves the nonnegativity of the solution, is entropy stable and dissipates a modified entropy functional. The existence of a weak semi-discrete solution and, in a particular case, its temporal second-order convergence to the continuous solution is proved. The proofs employ an algebraic relation which implies the G-stability of the two-step BDF. Second, an implicit Euler and $q$ -step BDF discrete variational derivative method are considered. This scheme, which exploits the variational structure of the equation, dissipates the discrete Fisher information (or energy). Numerical experiments show that the discrete (relative) entropies and Fisher information decay even exponentially fast to zero. 相似文献