Synthesis of polysaccharides. Communication 15. Synthesis of β-(1 → 6)-D-galactan

Conclusions 1,2-0-(1-exo-Cyano)ethylidene-3,4-di-0-acety1-6-0-trityl- and 1,2-0-(1-exo-cyano)ethylidene-3,4-di-0-benzoyl-6-0-trityl--D-galactopyranoses were synthesized. Their polycondensation led to D-galactans, which do not contain -glycoside bonds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya., No. 10, pp. 2358–2363, October, 1984.     

First direct evidence for a magnetic phase transition in the heavy-electron system UCd11

Muon-spin-rotation and relaxation measurements performed on polycrystalline UCd₁₁ give first direct evidence for an antiferromagnetic phase transition at 5 K. As far as probed by the positive muon the behaviour close to the phase transition is clearly contrasted to that in other magnetic heavy-electron materials investigated by μ⁺SR, e.g. U₂Zn₁₇ and UCu₅, because in UCd₁₁ longitudinal field measurements reveal dynamic relaxation effects which are attributed to the critical slowing down of the uranium 5f-moments. No signal could be observed in the ordered regime because of a large dipolar field spread.     

Normal-state resistivity of superconducting Bi1.95Sr1.65La0.4CuO6+δ single crystals

The anisotropy of the normal-state resistivity of a number of superconducting Bi_1.95Sr_1.65La_0.4CuO_6+δ single crystals has been measured by using both a six- and a four-terminal technique. We find that the ab-plane resistivity _ab in general increases almost linearly with temperature (d_ab/dT> 0). the temperature variation of the c-axis resistivity _c, however, is strongly sample dependent. Both metallic-like (d_c/dT> 0) and mixed temperature dependences of _c, including d_c/dT < 0 are observed. The mixed _c(T) data can be well described by fitting to _c(T) = A + BT + C/T, indicating that the temperature dependence of _c(T) is the result of a competition between metallic and non-metallic terms. The temperature T_min at which _c reaches a minimum increases with increasing d_ab/dT, suggesting that the metallic term of _c arises from misaligned Cu---O planes. This is confirmed by an electron-microscope (HRTEM) analysis of the samples. The anisotropy ratio _c/_ab is of the order of 10³ but increases monotonically with decreasing temperature, indicating differences in the scattering processes parallel and perpendicular to the Cu---O plane.     

NMR studies of U0.2Y0.8Pd3 and YPd3 at low temperatures

We report results of ⁸⁹Y-NMR measurements on U_0.2Y_0.8Pd₃ as well as YPd₃, performed at frequencies between 9 and 16MHz and at temperatures between 0.25 and 2 K. In this temperature range the average Knight shift is +0.5%, temperature-independent and the same for both materials. Also the NMR linewidth for both compounds was found to be temperature and field independent but one order of magnitude larger for U_0.2Y_0.8Pd₃ than for YPd₃. For U_0.2Y_0.8Pd₃ our results indicate a distribution of internal static fields at the Y sites and a small temperature-dependent enhancement of the spin-lattice relaxation rate T ₁ ^?1 with respect to YPd₃. The NMR spectra are consistent with the presence of very small frozen U moments, but the temperature dependence of the spin-lattice relaxation rate indicates a more complicated situation. In particular (T₁T)^?1 shows an anomalous temperature dependence.     

Structure and low temperature properties of SrB6

A detailed study of the room temperature structure of high quality single crystalline SrB6 has been made. Minute changes in interatomic distances may drastically affect the electronic spectrum of this compound. Electronic transport properties both at zero and non-zero frequencies above ⁴He temperatures indicate that SrBP₆ is close to be a semiconductor. However, at very low temperatures this compound enters a metallic state with a low concentration of itinerant charge carriers. Possible correlation effects are indicated by anomalous temperature dependences of the electrical resistivity and the specific heat below 1 K.     

Muon Knight shift and μ+ site in the monopnictide CeAs

The transverse field μSR-signal from μ⁺ implanted in a CeAs single crystal shows a splitting into two components, displaying a positive and a negative Knight shift, respectively which both scale reasonably well with the magnetic bulk susceptibility above 10 K. The orientation dependence of the frequency shifts, measured at 15 K, is fully accounted for by the demagnetization field, implying an isotropic Knight shift, consistent with the μ⁺ residing at the only interstitial site of high (cubic) symmetry, i.e., at the position (1/4,1/4,1/4). The occurrence of a split signal remains unexplained. This revised version was published online in July 2006 with corrections to the Cover Date.