Complete hypersurfaces with constant scalar curvature in spheres

To a given immersion ${i:M^n\to \mathbb S^{n+1}}$ with constant scalar curvature R, we associate the supremum of the squared norm of the second fundamental form sup |A|². We prove the existence of a constant C _n (R) depending on R and n so that R ≥ 1 and sup |A|² = C _n (R) imply that the hypersurface is a H(r)-torus ${\mathbb S^1(\sqrt{1-r^2})\times\mathbb S^{n-1} (r)}$ . For R > (n ? 2)/n we use rotation hypersurfaces to show that for each value C > C _n (R) there is a complete hypersurface in ${\mathbb S^{n+1}}$ with constant scalar curvature R and sup |A|² = C, answering questions raised by Q. M. Cheng.     

Diastereoselective cobalt-catalyzed reductive aldol cyclizations using diethylzinc as the stoichiometric reductant

[reaction: see text] Cobalt catalysis enables a new method for the generation of zinc enolates using diethylzinc to reduce alpha,beta-unsaturated amides. This method has been applied to a high-yielding diastereoselective reductive aldol cyclization.     

Convergence analysis of a high-order Nyström integral-equation method for surface scattering problems

In this paper we present a convergence analysis for the Nyström method proposed in [J Comput Phys 169 (1):80–110, 2001] for the solution of the combined boundary integral equation formulations of sound-soft acoustic scattering problems in three-dimensional space. This fast and efficient scheme combines FFT techniques and a polar change of variables that cancels out the kernel singularity. We establish the stability of the algorithms in the $L^2$ norm and we derive convergence estimates in both the $L^2$ and $L^\infty $ norms. In particular, our analysis establishes theoretically the previously observed super-algebraic convergence of the method in cases in which the right-hand side is smooth.     

First Nonlinear Syzygies of Ideals Associated to Graphs

Consider an ideal I ? K[x ₁,…, x _n ], with K an arbitrary field, generated by monomials of degree two. Assuming that I does not have a linear resolution, we determine the step s of the minimal graded free resolution of I where nonlinear syzygies first appear, we show that at this step of the resolution nonlinear syzygies are concentrated in degree s + 3, and we compute the corresponding graded Betti number β _{s, s+3}. The multidegrees of these nonlinear syzygies are also determined and the corresponding multigraded Betti numbers are shown to be all equal to 1.     

Estimation of large domain Al foam permeability by Finite Difference methods

Classical methods to calculate permeability of porous media have been proposed mainly for high density (e.g. granular) materials. These methods present shortcomings in high porosity, i.e. high permeability media (e.g. metallic foams). While for dense materials permeability seems to be a function of bulk properties and occupancy averaged over the volume, for highly porous materials these parameters fail to predict it. Several authors have attacked the problem by solving the Navier-Stokes equations for the pressure and velocity of a liquid flowing through a small domain (Ω_s) of aluminium foam and by comparing the numerical results with experimental values (prediction error approx. 9%). In this article, we present calculations for much larger domains (Ω_L) using the Finite Difference (FD) method, solving also for the pressure and velocity of a viscous liquid flowing through the Packed Spheres scenario. The ratio Vol(Ω_L)/Vol(Ω_s) is around 10³. The comparison of our results with the Packed Spheres example yields a prediction error of 5% for the intrinsic permeability. Additionally, numerical permeability calculations have been performed for Al foam samples. Our geometric modelling of the porous domain stems from 3D X-ray tomography, yielding voxel information, which is particularly appropriate for FD. Ongoing work concerns the reduction in computing times of the FD method, consideration of other materials and fluids, and comparison with experimental data. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Numerical analysis of wave propagation in fluid-filled deformable tubes

The theory of Biot describing wave propagation in fluid saturated porous media is a good effective approximation of a wave induced in a fluid-filled deformable tube. Nonetheless, it has been found that Biot's theory has shortcomings in predicting the fast P-wave velocities and the amount of intrinsic attenuation. These problems arises when complex mechanical interactions of the solid phase and the fluid phase in the micro-scale are not taken into account. In contrast, the approach proposed by Bernabe does take into account micro-scopic interaction between phases and therefore poses an interesting alternative to Biot's theory. A Wave propagating in a deformable tube saturated with a viscous fluid is a simplified model of a porous material, and therefore the study of this geometry is of great interest. By using this geometry, the results of analytical and numerical results have an easier interpretation and therefore can be compared straightforward. Using a Finite Difference viscoelastic wave propagation code, the transient response was simulated. The wave source was modified with different characteristic frequencies in order to gain information of the dispersion relation. It was found that the P-wave velocities of the simulations at sub-critical frequencies closely match those of Bernabe's solution, but at over-critical frequencies they come closer to Biot's solution. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Personalized Metabolic Profile by Synergic Use of NMR and HRMS

A new strategy that takes advantage of the synergism between NMR and UHPLC–HRMS yields accurate concentrations of a high number of compounds in biofluids to delineate a personalized metabolic profile (SYNHMET). Metabolite identification and quantification by this method result in a higher accuracy compared to the use of the two techniques separately, even in urine, one of the most challenging biofluids to characterize due to its complexity and variability. We quantified a total of 165 metabolites in the urine of healthy subjects, patients with chronic cystitis, and patients with bladder cancer, with a minimum number of missing values. This result was achieved without the use of analytical standards and calibration curves. A patient’s personalized profile can be mapped out from the final dataset’s concentrations by comparing them with known normal ranges. This detailed picture has potential applications in clinical practice to monitor a patient’s health status and disease progression.     

Solute-diffusion-controlled dislocation creep in pure aluminium containing 0.026 at.% Fe

Pure aluminium containing about 200?at.ppm Fe in solution is shown to creep about 10⁶ times slower at 200°C than the same aluminium containing a negligible amount of iron in solution. The high creep resistance of the Al–200?at.ppm?Fe alloy is attributed to the presence of subgrain boundaries containing iron solute atoms. It is proposed that the opposing stress fields from subgrain boundaries and from the piled-up dislocations during creep are cyclically relaxed, by iron solute diffusion, to allow climb of the lead dislocation in the pile-up. The mechanism is a form of mechanical ratcheting. The model is applied to Al–Fe alloys and correctly predicts that the creep rate is controlled by the rate of iron solute diffusion and by a temperature dependence equal to the activation energy for iron diffusion, namely Q _c?=?221?kJ?mol^?1. Basic creep studies on solid-solution alloying with solute atoms that diffuse slowly in the lattice of aluminium (e.g. manganese, chromium, titanium and vanadium) appear worthy of study as a way of enhancing creep strength and of understanding creep mechanisms involving solute-atom-containing subgrain boundaries.     

Leptoquark effects on ν τ propagation in the Earth

The proposal of pilgrim dark energy is based on the idea that phantom dark energy possesses enough resistive force to preclude black hole formation. We work on this proposal by choosing an interacting framework with cold dark matter and three cutoffs such as Hubble as well as event horizon and conformal age of the universe. We present a graphical analysis and focus our study on the pilgrim dark energy as well as interacting parameters. It is found that these parameters play an effective role on the equation of state parameter for exploring the phantom region of the universe. We also make the analysis of ω–ω′ and point out freezing region in the ω–ω′ plane. Finally, it turns out that the ΛCDM is achieved in the statefinders plane for all models.