全文获取类型
收费全文 | 1957篇 |
免费 | 31篇 |
国内免费 | 23篇 |
专业分类
化学 | 1485篇 |
晶体学 | 15篇 |
力学 | 15篇 |
数学 | 81篇 |
物理学 | 415篇 |
出版年
2022年 | 12篇 |
2021年 | 23篇 |
2020年 | 20篇 |
2019年 | 16篇 |
2018年 | 18篇 |
2017年 | 13篇 |
2016年 | 24篇 |
2015年 | 20篇 |
2014年 | 31篇 |
2013年 | 64篇 |
2012年 | 96篇 |
2011年 | 101篇 |
2010年 | 66篇 |
2009年 | 74篇 |
2008年 | 116篇 |
2007年 | 131篇 |
2006年 | 122篇 |
2005年 | 148篇 |
2004年 | 129篇 |
2003年 | 109篇 |
2002年 | 96篇 |
2001年 | 39篇 |
2000年 | 19篇 |
1999年 | 35篇 |
1998年 | 33篇 |
1997年 | 22篇 |
1996年 | 38篇 |
1995年 | 21篇 |
1994年 | 12篇 |
1993年 | 11篇 |
1992年 | 14篇 |
1991年 | 14篇 |
1990年 | 6篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 16篇 |
1985年 | 17篇 |
1984年 | 24篇 |
1983年 | 9篇 |
1982年 | 24篇 |
1981年 | 23篇 |
1980年 | 14篇 |
1979年 | 23篇 |
1978年 | 19篇 |
1977年 | 23篇 |
1976年 | 15篇 |
1975年 | 15篇 |
1974年 | 13篇 |
1973年 | 14篇 |
1971年 | 5篇 |
排序方式: 共有2011条查询结果,搜索用时 375 毫秒
1.
Katoh Katsumi Fukui Satomi Haba Ayane Higashi Eiko Saburi Tei Okada Ken 《Journal of Thermal Analysis and Calorimetry》2022,147(13):7563-7571
Journal of Thermal Analysis and Calorimetry - Nitrocellulose (NC) is prone to spontaneous decomposition with exothermic heat release and thus is generally evaluated for stability during the storage... 相似文献
2.
HPLC with fluorescence detection assay of perampanel,a novel AMPA receptor antagonist,in human plasma for clinical pharmacokinetic studies
下载免费PDF全文
![点击此处可从《Biomedical chromatography : BMC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Perampanel (Fycompa®), a novel α‐amino‐3‐hydroxy‐5‐methyl‐4‐isoxazolepropionic acid (AMPA) receptor antagonist, is registered for the adjunctive treatment of patients (aged ≥12 years) with refractory partial‐onset seizures. To support therapeutic drug monitoring, a simple high‐performance liquid chromatography (HPLC) assay with fluorescence detection was developed to determine perampanel concentrations in human plasma and validated to support clinical trials. Human plasma samples (1.0 mL) were processed by liquid extraction using diethyl ether, followed by chromatographic separation on a YMC Pack Pro C18 column (150 × 4.6 mm i.d., 5 µm) with isocratic elution of acetonitrile–water–acetic acid–sodium acetate (840:560:3:1.8, v/v/v/w) at a flow rate of 1.0 mL/min. Column eluent was monitored at excitation and emission wavelengths of 290 and 430 nm, respectively. The assay was linear (range 1.0–500 ng/mL) and this could be extended to 25 µg/mL by 50‐fold dilution integrity. No endogenous peaks were detected in the elution of analytes in drug‐free blank human plasma from six individuals and no interference was observed with co‐medications tested. Intra‐ and inter‐batch reproducibility studies demonstrated accuracy and precision within the acceptance criteria of bioanalytical guidelines. Validation data demonstrated that our assay is simple, selective, reproducible and suitable for therapeutic drug monitoring of perampanel. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
Kosuke Morita Kouji Morimoto Daiya Kaji Yu Liang Zhao Atsushi Yoshida Toshimi Suda Akira Yoneda Tetsuya Ohnishi Hiromitsu Haba Eiji Ideguchi Hu Shan Xu Tao Zheng Hisaaki Kudo Keisuke Sueki Kenji Katori Isao Tanihata 《Acta Physica Hungarica A》2004,19(1-2):53-60
A gas-filled type of recoil separator for heavy element research was installed at an experimental hall of RIKEN Linear Accelerator facility to realize getting higher intensity of primary beam and long beam time. Performance of the separator was studied using target recoils and various nuclear reactions. The results show the high performance of the separator for heave element research. As an application of the GARIS, production and identification of an isotope of the 110th element 271[110] have been performed using the 208Pb(64Ni,1n)271[110] reaction. Three decay chains coincide well both in decay times and energies with the ones reported by the group of SHIP experiment at GSI, Germany. Our results provide a confirmation of the synthesis of an isotope 271[110] of element 110. 相似文献
4.
Takashi Yoshitake Ryuji Iizuka Kaoru Fujino Osamu Inoue Kenji Yamagata Hitoshi Nohta Masatoshi Yamaguchi 《Analytical sciences》2004,20(12):1687-1690
An improved high-performance liquid-chromatographic (HPLC) assay for the simultaneous determination of serotonin (5-HT) and 5-hydroxyindole-3-acetic acid (5-HIAA) in human urine is reported. Following the automated precolumn derivatization of urinary 5-HT and 5-HIAA with benzylamine, the derivatives are separated by isocratic elution on a reversed-phase C18 semi-microbore column, and are fluorometrically detected at an excitation wavelength of 345 nm and an emission wavelength of 480 nm. The detection limits of 5-HT and 5-HIAA are 7 and 5 nmol/l in urine (0.7 and 0.5 fmol/20-microl injection). The proposed automatic method permits a highly selective and sensitive determination of 5-HT and 5-HIAA in human urine without any sample purification. 相似文献
5.
Z. Haba 《International Journal of Theoretical Physics》1997,36(7):1585-1600
We discuss the coupling of a quantum system through the angular momentum to the reservoir of quantum harmonic oscillators. In classical mechanics an observation of the oscillator trajectories allows one to determine the system's angular momentum. We discuss the quantum dynamics of the model. We show that the model of an observation of environmental coordinates can be related to some models of angular momentum measurement based on a stochastic Schrödinger equation. 相似文献
6.
Osamu Kobayashi 《Mathematische Zeitschrift》1989,200(2):273-277
Financial support from the FRD is gratefully acknowledged 相似文献
7.
8.
Mark P. WattersonAlison A. Edwards John A. LeachMartin D. Smith Osamu IchiharaGeorge W.J. Fleet 《Tetrahedron letters》2003,44(31):5853-5857
Efficient syntheses of all diastereomers of methyl 2,5-anhydro-3-deoxy-hexonate from mannono- or gulono-lactones provide precursors for C-nucleosides of 2-deoxyribose and for THF-templated γ- and δ-amino acids. 相似文献
9.
Y. Nagame M. Asai H. Haba K. Tsukada I. Nishinaka S. Goto A. Toyoshima K. Akiyama M. Sakama Y. L. Zhao S. Ichikawa H. Nakahara 《Physics of Atomic Nuclei》2003,66(6):1131-1136
The present status of heavy element nuclear chemistry research at JAERI (Japan Atomic Energy Research Institute) is reviewed. Production of the transactinide nuclei 261Rf and 262Db via the reactions of 248Cm(18O,5n) and 248Cm(19F, 5n), respectively, at the JAERI tandem accelerator is reported. Study of the aqueous chemistry of Rf is being carried out with a newly developed rapid ion-exchange separation apparatus. Anion-exchange behavior of Rf in acidic solution is briefly discussed. Recent experimental results on decay studies of neutron-deficient actinide nuclei using the gas-jet coupled JAERI-ISOL are given. We also discuss characteristics of nuclear deformation properties at scission in symmetric and asymmetric fission of actinides. Prospects for studies in the near future are briefly considered. 相似文献
10.
Takafumi Adachi Ichimin Shirotani Junichi Hayashi Osamu Shimomura 《Physics letters. A》1998,250(4-6):389-393
Lanthanide monophosphides LnP (Ln = La, Ce, Pr, Nd, Sm, Gd, Tb, Tm and Yb) with a NaCl-type structure have systematically been prepared at high temperatures. Using synchrotron radiation, X-ray diffractions of LnP have been studied up to 61 GPa at room temperature. The NaCl---CsCl transition for CeP is found at around 25 GPa. First-order phase transitions of LnP (Ln = La, Pr and Nd) with the crystallographic change occur at around 24, 26 and 30 GPa, respectively. The structure of the high pressure phases of these phosphides is a body center tetragonal structure (Ln: 0, 0, 0; P: 1/2, 1/2, 1/2; space group P4/mmm), which can be seen as the distorted CsCl-type structure. The Pr---P distance in the high pressure form of PrP is 2.789 Å. This almost agrees with the sum of covalent radii of Pr and P. The Pr---P bond has the covalent character at very high pressures. Similar results are also obtained for LaP and NdP. The pressure-induced phase transitions of SmP, GdP, TbP, TmP and YbP occur at around 35, 40, 38, 53 and 51 GPa, respectively. The structure of the high pressure phase is unknown. The phase transitions of LnP with many f-electrons are not due to the mechanism of the ordinary NaCl---CsCl transition. The transition pressures of LnP increase with decreasing the lattice constants in the NaCl-type structure, which decrease with increasing atomic number of the lanthanide atoms. 相似文献