Direct-on-filter analysis of crystalline silica using photoacoustic Fourier transform-infrared spectroscopy

Photoacoustic Fourier transform-infrared spectroscopy (PA-FT-IR) has been used to perform direct-on-filter (DOF) analysis of crystalline silica using laboratory-generated filter samples. With these samples, the silica particles were embedded in the stable three-dimensional matrix of the filter. In this preliminary study, it was demonstrated that the photoacoustic (PA) signals generated from direct-on-filter measurements were significantly higher than the corresponding signals for equivalent amounts of silica particles placed directly in the photoacoustic detector cup. Studies with Min-U-Sil-5 loaded onto 9 mm filter stubs indicated a limit of detection of less than 10 μg. Additionally, Teflon filters were demonstrated to be more suitable for these measurements than other types. The photoacoustic FT-IR approach seems to be feasible for further development to use with full-sized personal sampling filters.     

A measurement of the energy dependence of the inclusive yield of high-Pt events triggered by a large solid angle calorimeter

Large aperture calorimeter measurements of high transverse momentum events from 100, 200 and 340 GeV pp collisions are reported. Yields are higher by one to two orders of magnitude than the yield expected from uncorrelated statistical fluctuations in multiparticle events. The exponential slopes of the yields versus x_t exhibited a systematic change with $\text{s}\text{(x}{}_{\mathrm{<mtext>t</mtext>}}\text{= 2P}{}_{\mathrm{<mtext>t</mtext>}}\text{/}\text{s}\text{)}$. The events are shown to be more diffuse than pure jets as produced in e⁺e^? collisions. However, these events are consistent with a QCD-inspired 4-jet model.     

A study of the charge-exchange reaction pp → nΔ++(1232) at ISR energies

We report on a study of the charge-exchange reaction pp → nΔ⁺⁺(1232) at the CERN intersecting storage rings (ISR) in the energy range √s = 23 to 53 GeV. From our analysis of the energy dependence of the total cross-section, of the differential cross-section dσ/dt and of the decay angular distributions we find evidence that pion exchange is dominant up to √s = 23 GeV and that (?+A₂) exchange dominates the reaction for √s ? 30 GeV, as described by simple Regge-pole models.     

Methode zur Messung der Torsionssteifheit von Fasern bei erh?hten Temperaturen und Drucken

Ohne Zusammenfassung     

Crystal structure of cyanocalix[4]arene methyl ether

The title compound has been prepared by the addition of bromocalix[4]arene methyl ether to CuCN in N-methylpyrrolidone. The crystals belong to the monoclinic space groupP2₁/n witha=13.591(3),b=24.778(5),c=11.057(3)Å,=93.58(2)°, andD _c=1.09 g cm^–3 forZ=4. Refinement based on 1118 observed reflections led to a finalR value of 0.085. The molecule exhibits the partial cone conformation.     

Isotope dynamic mixing and vibronic structure

Existing theories which deal with the isotope dependence of vibronic structure have neglected the isotope dependence of vibration dynamics. The latter dependence (isotope dynamic mixing) is an adiabatic correction to vibronic structure theory. A theory of vibronic structure, which includes isotope dynamic mixing, is developed. The results of model calculations are presented.     

Self-adaptive, narrowband tuning of a pulsed optical parametric oscillator and a continuous-wave diode laser via phase-conjugate photorefractive cavity reflectors: verification by high-resolution spectroscopy

A dynamic self-adaptive Bragg grating formed in a photorefractive crystal is shown to be a convenient way to attain single-longitudinal-mode (SLM) operation and narrowband tuning both in a pulsed, injection-seeded optical parametric oscillator (OPO) and in a continuous-wave (cw) extended-cavity diode laser. The pulsed OPO cavity comprises a Rh:BaTiO₃ photorefractive (PR) crystal, a periodically poled KTiOPO₄ nonlinear-optical crystal, and a dielectrically-coated end mirror. A continuous-wave seed beam at 820–850 nm from a tunable SLM diode laser traverses firstly the Rh:BaTiO₃ crystal and then is retro-reflected by the end mirror; this creates a wavelength-selective Bragg grating reflector in the PR crystal, thereby completing the OPO cavity. The cavity stays automatically resonant with the seed radiation, with no need to actively control its length or to make any other mechanical adjustment. One form of injection seeder comprises a novel extended-cavity diode laser (ECDL) design incorporating a self-pumped photorefractive phase-conjugate reflector and a compact, high-finesse tunable intracavity ring filter. This combination facilitates robust tunable single-frequency operation with narrow optical bandwidth. The performance characteristics of the OPO and the ECDL are evaluated by recording high-resolution atomic and molecular spectra. Notably, fluorescence-detected sub-Doppler two-photon excitation at 822 nm, of the 8S ←6S transition in atomic Cs, provides a crucial linewidth test.     

Recoupling of chemical-shift anisotropy powder patterns in MAS NMR

A comparison of three different implementations of the chemical-shift recoupling experiment of Tycko et al. [R. Tycko, G. Dabbagh, P.A. Mirau, Determination of chemical-shift-anisotropy lineshapes in a two-dimensional magic-angle-spinning NMR experiment, J. Magn. Reson. 85 (1989) 265-274] is presented. The methods seek to reduce the effects of artefacts resulting from pulse imperfections and residual C-H dipolar coupling in organic solids. An optimised and constant time implementation are shown to give well-defined and artefact free powder pattern lineshapes in the indirectly observed dimension for both sp2 and sp3 carbon sites. Experimental setup is no more demanding than for the original experiment, and can be implemented using standard commercial hardware.     

Chromosomal aberrations resulting from UV exposures to G1 Xenopus cells

Abstract— The dose dependence of chromosomal aberration frequencies induced by UV light in G₁Xenopus cells has been examined. Total aberration frequencies did not exceed control levels until a dose of approximately 7.5 Jm^-2 was administered. Chromatid type aberrations were prevalent throughout the dose range 7.5–25.0 Jm^-2. Chromosome type aberration frequencies were comparatively low but exceeded control levels throughout the range 10.0–25.0 Jm^-2, Results of supporting experiments suggested that most of the chromosome type aberrations observed were in the second mitosis following exposures and were derived from aberrations which normally appear as chromatid types at the first mitosis following exposures.     

Photoneutron cross sections of 121Sb, 123Sb and natSb

The cross sections for the reactions ${}^{121}\text{Sb}\text{(γ,n)}$, ¹²³Sb(γ, χn) and ^natSb(γ, χn) have been measured. The ¹²¹Sb and ¹²³Sb photoneutron reaction cross sections are consistent with collective model predictions for negatively deformed nuclei.