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11.
Keidar M. Boyd I.D. Beilis I.I. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2000,28(2):376-385
In this work, we analyze the physical processes of a pulsed discharge in a dielectric (Teflon) cavity. This type of discharge is generated in a coaxial pulsed plasma thruster (PPT) having a central Teflon cavity to produce a high-pressure cloud of ablation products during the discharge pulse. The primary intended role of this model is to provide upstream boundary conditions for particle simulation codes used to study the exhaust plume. The main features of the electrical discharge in the dielectric cavity include Joule heating of the plasma, heat transfer to the dielectric, decomposition of the dielectric followed by partial ionization, and acceleration of the plasma up to the sound speed at the cavity exit. We consider a diffuse type of discharge assuming that all plasma parameters are uniform in the cavity. The system of equations is based on the plasma energy balance, thermal conductivity, dielectric ablation, and mass balance. It is found that most of the energy of the plasma column is carried off by particle convection to the dielectric and by radiation. It is found that during the pulse, the electron density peaks at about 1024 m-3 and decreases to 1021 m-3 toward the end of the pulse, whereas the electron temperature peaks at about 2.2 eV and decays to 1.5 eV. Teflon surface temperature peaks at about 650 K. Predicted plasma temperature and ablated mass are found to be in agreement with available experimental data 相似文献
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Liu Y Young MC Moshe O Cheng Q Hooley RJ 《Angewandte Chemie (International ed. in English)》2012,51(31):7748-7751
Primed for action: Atom-transfer radical polymerization (ATRP) can be promoted at a bilayer-water interface by anchoring initiator molecules (see scheme; red) in a membrane-bound synthetic receptor (yellow). The bilayer is formed on a calcinated nanofilm (gray) on a gold surface. 相似文献
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Cavitands can be smoothly derivatized by CuAAC chemistry to incorporate ligand species at the upper rim. These species can coordinate metal species in a number of different conformations, leading to self-assembly. The metal-coordination confers water solubility on the cavitands, and the iron-bound species are capable of catalytic C-H oxidations of fluorene under mild conditions. 相似文献
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Laura Trapiella-Alfonso Fanny d’Orlyé Anne Varenne 《Analytical and bioanalytical chemistry》2016,408(11):2669-2675
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Interpretation of the curious results of the new quantum formalism of pre- and post-selected systems
The analysis, with the use of two state vectors, of a quantum system, during the time interval between two measurements, leads to some amazing results, which seem to contradict our usual quantum common sense. We explore the questions of compatibility with the conventional quantum theory, uniqueness of pre- and post-selected ensembles, commutativity, simultaneity and reality of strong and weak values in the intermediate time, and the meaning of the weak value. Common criticisms are shown to be unfounded. 相似文献
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Keidar M. Beilis I.I. Boxman R.L. Goldsmith S. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1997,25(4):580-585
The plasma jet focusing and voltage distribution in the interelectrode gap of a vacuum arc with a ring anode and subjected to an axial magnetic field were studied theoretically. A two-dimensional model was developed based on the free plasma jet expansion into vacuum, and the steady-state solution of the fully ionized plasma in the hydrodynamic approximation was analyzed. It was found that the imposition of an axial magnetic field reduces the radial expansion of the plasma jet. The characteristic jet angle decreases from about 40° in the zero magnetic field case and approaches a value of about 20° with a 0.02 T magnetic field. The arc voltage consisting of the cathode drop, the plasma voltage drop, and anode sheath drop increased, with the imposition of a magnetic field, and decreased with the anode length. The model was compared to experimental measurements of the vacuum arc voltage behavior in an axial magnetic field, and good agreement was found 相似文献
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Liron Feldberg Ofir Schuster Eytan Elhanany Orly Laskar Shmuel Yitzhaki Sigalit Gura 《Journal of mass spectrometry : JMS》2020,55(1)
Ricin, a plant‐derived toxin extracted from the seeds of Ricinus communis (castor bean plant), is one of the most toxic proteins known. Ricin's high toxicity, widespread availability, and ease of its extraction make it a potential agent for bioterrorist attacks. Most ricin detection methods are based on immunoassays. These methods may suffer from low efficiency in matrices containing interfering substances, or from false positive results due to antibody cross reactivity, with highly homologous proteins. In this study, we have developed a simple, rapid, sensitive, and selective mass spectrometry assay, for the identification of ricin in complex environmental samples. This assay involves three main stages: (a) Ricin affinity capture by commercial lactamyl‐agarose (LA) beads. (b) Tryptic digestion. (c) LC‐MS/MS (MRM) analysis of tryptic fragments. The assay was validated using 60 diverse environmental samples such as soil, asphalt, and vegetation, taken from various geographic regions. The assay's selectivity was established in the presence of high concentrations of competing lectin interferences. Based on our findings, we have defined strict criteria for unambiguous identification of ricin. Our novel method, which combines affinity capture beads followed by MRM‐based analysis, enabled the identification of 1 ppb ricin spiked into complex environmental matrices. This methodology has the potential to be extended for the identification of ricin in body fluids from individuals exposed (deliberately or accidentally) to the toxin, contaminated food or for the detection of the entire family of RIP‐II toxins, by applying multiplex format. 相似文献
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Johnson AM Moshe O Gamboa AS Langloss BW Limtiaco JF Larive CK Hooley RJ 《Inorganic chemistry》2011,50(19):9430-9442
A series of tetracationic M(2)L(4) palladium-pyridyl complexes with endohedral amine functionality have been synthesized. The complexes were analyzed by NMR techniques (including Diffusion NMR and 2D NOESY), electrospray ionization (ESI) mass spectrometry, and X-ray crystallography. The solid state analysis shows a large change in crystal morphology upon introduction of the endohedral amine groups, caused by deleterious interactions between the amines and the triflate counterions from the coordination process. Combination of different ligands allows analysis of ligand exchange rates via NMR analysis, with half-lives on the order of 3 h, independent of the donor properties of the ligand. Self-sorting behavior is observed, with more electron-rich ligands being favored. The amine-containing and extended complexes are strongly fluorescent, giving quantum yields of up to 83%. 相似文献
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Marie Girardot Fanny d’Orlyé Anne Varenne 《Analytical and bioanalytical chemistry》2014,406(4):1089-1098
With the view of designing new nanoparticle (NP)–aptamer conjugates and proving their suitability as biorecognition tools for miniaturized molecular diagnostics, new maghemite–silica core–shell NP–aptamer conjugates were characterized for the first time in terms of grafting rate and colloidal stability under electrophoretic conditions using capillary electrophoresis. After the grafting rate (on the order of six to 50) of the lysozyme-binding aptamer had been estimated, the electrophoretic stability and peak dispersion of the resulting oligonucleotide–NP conjugates were estimated so as to determine the optimal separation conditions in terms of buffer pH, ionic strength and nature, as well as temperature and electric field strength. The effective surface charge density of the NPs was close to zero for pH lower than 5, which led to some aggregation. The NPs were stable in the pH range from 5 to 9, and an increase in electrophoretic mobility was evidenced with increasing pH. Colloidal stability was preserved at physiological pH for both non-grafted NPs and grafted NPs in the 10–100 mM ionic strength range and in the 15–60 °C temperature range. A strong influence of the nature of the buffer counterion on NP electrophoretic mobility and peak dispersion was evidenced, thus indicating some interactions between buffer components and NP–aptamer conjugates. Whereas an electric field effect (50–900 V cm?1) on NP electrophoretic mobility was evidenced, probably linked to counterion dissociation, temperature seems to have an appreciable effect on the zeta potential and aptamer configuration as well. This information is crucial for estimating the potentialities of such biorecognition tools in electrophoretic systems. 相似文献