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641.
L. Yu. Ukhin L. V. Belousova Zh. I. Orlova S. V. Shishkina O. V. Shishkin 《Russian Chemical Bulletin》2002,51(7):1262-1269
The reactions of aminals, the Mannich bases, and azomethines derived from substituted salicylaldehydes were studied. Derivatives of tetrahydrocyclopenta[b]- and hexahydrocyclohepta[b]chromenes and substituted 2,2"-spirobichromenes were prepared from aminals, and substituted hexahydroxanthenes were synthesized from the Mannich bases. Azomethine derivatives of 5-nitrosalicylaldehyde and aliphatic amines react with cyclohexanone to form 4a-amino-7-nitro-2,3,4,4a-tetrahydro-1H-xanthenes. 4a-Morpholino-7-nitro-9-phenylethynyl-1,2,3,4,9,9a-hexahydroxanthene was studied by X-ray diffraction analysis. 相似文献
642.
Vladimir I. Minkin Ruslan M. Minyaev Galina V. Orlova 《Journal of Molecular Structure》1984,110(3-4):241-253
Ab initio STO-3G, 4-31G and semi-empirical MINDO/3 calculations were performed on a series of C4H4X compounds to analyze the possibility of existence of their nonclassical C4V pyramidal isomeric forms. It was shown that with the four-electron group X (C, N+, P+, O2+, S2+) in an apex, C4V pyramidal structures are indeed stable, i.e., conform to local minima on the corresponding potential energy surfaces. Relative energies, molecular geometries and charge density distribution for various isomeric forms of the C4H4X compounds are presented. The theoretically derived strategies for an experimental trapping of the pyramidane 1, X = C and the C4V pyramidal thiophene dication 1, X = S2+ are discussed. 相似文献
643.
Leonid O. Kononov Anna V. Orlova Boris G. Kimel Vladimir I. Bregadze 《Journal of organometallic chemistry》2005,690(11):2769-2774
A novel 1,2-dicarba-closo-dodecaborane-lactose conjugate 4c, when dissolved in water or methanol, is subject to unexpected deboronation in neutral conditions leading to the formation of the corresponding nido-counterpart (5) as detected by 11B NMR spectroscopy. After heating the aqueous solution of the conjugate 4c at 60 °C for 17 h pure 1,2-dicarba-nido-undecaborane-lactose conjugate 5 was obtained. 相似文献
644.
T. Yu. Orlova Yu. S. Nekrasov P. V. Petrovskii M. G. Ezernitskaya Z. A. Starikova A. I. Yanovsky 《Russian Chemical Bulletin》1998,47(10):2000-2006
The reaction of MeSiCl3 with 3 equivalents of LiC5H4(CO)2Fe(η1,η5-C5H4)Mn(CO)3 afforded the hexanuclear complex MeSi[η1,η5-C5H4(CO)2Fe(η1,η5-C5H5)Mn(CO)3]3. The structure of the resulting complex was established by1H and13C NMR and IR spectroscopy and by X-ray diffraction analysis.
Dedicated to the memory of Academician M. I. Kabachnik on his 90th birthday.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2056–2061, October, 1998. 相似文献
645.
It was found that the 16-C6H5Cr(CO)3 ligand migrates into the cyclopentadienyl ring when the 5-C5H5(CO)2Fe 16-C6H5Cr(CO)3 binuclear complex is metallated with BunLi. Under the same conditions, no migration of the phenyl ligand in the 5-C5H5(CO)2Fe 1-C6H5 complex was observed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 325–326, February, 1994. 相似文献
646.
T. Yu. Orlova Yu. S. Nekrasov P. V. Petrovskii M. G. Ezernitskaya 《Russian Chemical Bulletin》2004,53(9):1938-1941
The complex η5,η5-(CO)3Mn(C5H4-C5H4)(CO)2Fe-η1,η5-C5H4Mn(CO)3 was synthesized by the reaction of η5-Cp(CO)2Fe-η1,η5-C5H4Mn(CO)3 with BunLi (THF, ?78 °C) and then with anhydrous CuCl2. The complex μ-(C≡C)[C5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3]2 was prepared by the reaction of η5-IC5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3 with Me3SnC≡CSnMe3 (2:1) in the presence of Pd(MeCN)2Cl2. 相似文献
647.
T. V. Magdesieva S. V. Milovanov T. Yu. Orlova K. P. Butin 《Russian Chemical Bulletin》1995,44(2):354-358
The redox potentials of new Cr, Mn, and Fe polynuclear ladder complexes, (5-Cp)Fe(CO)2(1,5-C5H4)Fe(CO)2(1,5-C5H4)Mn(CO)3, (5-Cp)Fe(CO)2(1,5-C5H4)Mn(CO)3, (5-Cp)Fe(CO)2(1,6-Ph)Cr(CO)3, (5-Cp)Fe(CO)2(1,5-C5H4)Fe(CO)2CH2Ph, (5-Cp)Fe(CO)2(1,6-CH2Ph)Cr(CO)3, were measured and the mechanism of their electrochemical oxidation and reduction was suggested. It was shown that the - or -bonds of the bridging ligand can be cleaved selectively by applying cathodic or anodic potentials, respectively. On the basis of the obtained electrochemical data, a mechanism is suggested for the rearrangement observed when the complexes are metallated by butyllithium.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 362–366, February, 1995.This work was carried out with financial support from the Russian Foundation for Basic Research (Project No 94-03-08628a). 相似文献
648.
L. V. Shmelev A. V. Kessenikh E. E. Orlova I. N. Polyakova Z. A. Starikova G. N. Lipunova N. B. Ol'khovikova L. I. Rusinova 《Chemistry of Heterocyclic Compounds》1991,27(9):1023-1029
1,3-Diphenyl-5-(2-benzothiazolyl)formazane exists in its crystalline state (based on x-ray crystal structure data) in the E
1,2
Z
2,3
Z
3,4-conformation, which is stabilized by intramolecular hydrogen bonding (IMHB); the proton is localized on the nitrogen atom which is bound to the heterocycle. In chloroform solutions 1(5)-aryl-3-phenyl-5(1)-(2-benzothiazolyl)formazanes exist in the form of equilibrium mixtures of their chelate and open E
1,2
Z
2,3
Z
3,4-forms, in which the first of these forms predominates. Based on their
13
C-NMR spectral data the tautomeric equilibrium involving these forms is shifted in favor of the benzothiazolylhydrazone form. The amount of tautomer containing the benzothiazolidene fragment structure increases in DMSO solution.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1268–1274, September, 1991. 相似文献
649.
T.Yu. Orlova V.N. Setkina V.F. Sizoi D.N. Kursanov 《Journal of organometallic chemistry》1983,252(2):201-204
The cyclopentadienyl ligands in Cp(CO)2FePh, Cp(CO)2FeCH2Ph and [Cp(CO)2Fe]2 were metalated by BuLi in THF at ?78°C. With Cp(CO)2FePh it was possible to employ the reaction for the synthesis of cyclopentadienyl carbonyl complexes substituted on the Cp ligands. 相似文献
650.
O. A. Kost M. A. Orlova N. N. Troshina I. I. Nikol'skaya A. A. Shevchenko S. V. Volkova 《Russian Chemical Bulletin》1996,45(1):215-221
Radiation-induced inactivation of angiotensin-converting enzyme (ACE) in the low-dose range is characterized by the existence of a concentration- and pH-dependent induction period, activation, and inactivation. These effects are probably related to the change in the conformational flexibility of the active center in conjunction with the retention of the autoprotective multistep mechanism of the protection of the entire molecule. The schemes of radiation-induced reactions occurring in ACE are presented. The radiation-chemical yield of inactivation of ACE has a maximum at pH 7.5 independent of the initial concentration of the enzyme, which allows inference of a conformational transition in this pH range.For Part l, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 223–229, January, 1996. 相似文献