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11.
12.
Joaquin Barbera Anne-Marie Levelut Mercedes Marcos Pilar Romero Jose Luis Serrano 《Liquid crystals》1991,10(1):119-126
We present a comparative study of various metallomesogenic complexes, using X-ray diffraction methods. For a given ligand linked to different metal atoms (Cu, Ni, VO), the nature of this central atom influences mainly the magnetic susceptibilities of the mesophases. With different ligands, which keep the close neighbourhood of the metal atom unchanged, the apparent length of the mesogenic unit is longer for short ligands than for longer ones. This unexpected behaviour is qualitatively well explained by taking into account the global shape of the different complexes. 相似文献
13.
Most of the few known examples of compact Riemannian manifolds with positive sectional curvature are the total space of a
Riemannian submersion. In this article we show that this is true for all known examples, if we enlarge the category to orbifold
fibrations. For this purpose we study all almost free isometric circle actions on positively curved Eschenburg spaces, which
give rise to principle orbifold bundle structures, and we examine in detail their geometric properties. In particular, we
obtain a new family of 6-dimensional orbifolds with positive sectional curvature whose singular locus consists of just two
points.
相似文献
14.
A scheme for vehicle density and velocity estimation in a stretch of highway based on a modified cell transmission model [C.
F. Daganzo, Transportation Research, Part B, 28B(4),269–287, 1994. Elsevier is presented. The scheme is intended for use with on-ramp metering control algorithms, providing
local knowledge of densities and velocities that is helpful to improve on-ramp metering control performance. Estimation of
density is obtained by nonlinear estimators, while velocity estimation is obtained by gradient algorithms. There is one density–velocity
estimator for free traffic flow and other for congested traffic flow. Both estimator schemes work in parallel. The final estimation
of density and velocity results from a convex combination of the predictions of the two estimators. This combination depends
on occupancy or density measurements at the boundaries of the stretch and is produced by a fuzzy inference system. Stability
and convergence of the density and velocity estimation scheme is proved by Lyapunov based techniques. Simulation results comparing
measured and estimated traffic data are presented. They confirm good performance of the estimators.
Research sponsored by grants UNAM PAPIIT IN110403 and CONACYT 47583. 相似文献
15.
16.
Ana L. Montero Luis A. Montero Ricardo Martínez S. Spange 《Journal of Molecular Structure》2006,770(1-3):99-106
A quantum chemical model (Abinitio HF-MO and DFT-B3LYP) of polyfurfuryl alcohol crosslinking is shown. Two pathways were considered: (a) a Diels–Alder (D–A) reaction between a dihydrofuran moiety and a furan ring; (b) the addition reaction of electrophilic specimens on conjugated double bonds. The ability for the formation of D–A adducts (dienes and dienophiles) was investigated by the frontier molecular orbital (FMO) theory. Energy gaps between the FMO's of diene and dienophile structures suggest that the occurrence of the D–A reaction is possible. The results suggest that the carbons of the exo double bonds attached to dihydrofuran rings are the sites most likely to be attacked by electrophilic species, while the C3 and C4 atoms display the opposite tendency due to their low HOMO electron densities. Results of a thermochemical approach to these reactions at the MP2 level was in agreement with reactivity modelled by MO predictions. 相似文献
17.
18.
Luiza Amália Moraes Luis Romero Grados 《Journal of Mathematical Analysis and Applications》2003,281(2):575-586
Let Au(BG) be the Banach algebra of all complex valued functions defined on the closed unit ball BG of a complex Banach space G which are uniformly continuous on BG and holomorphic in the interior of BG, endowed with the sup norm. A characterization of the boundaries for Au(BG) is given in case G belongs to a class of Banach spaces that includes the pre-dual of a Lorentz sequence space studied by Gowers in Israel J. Math. 69 (1990) 129-151. The non-existence of the Shilov boundary for Au(BG) is also proved. 相似文献
19.
Jean Dolbeault Maria J Esteban Michael Loss Luis Vega 《Journal of Functional Analysis》2004,216(1):1-21
We prove some sharp Hardy-type inequalities related to the Dirac operator by elementary, direct methods. Some of these inequalities have been obtained previously using spectral information about the Dirac-Coulomb operator. Our results are stated under optimal conditions on the asymptotics of the potentials near zero and near infinity. 相似文献
20.
A program to compute many functions dependent on the electron density ρ(r) from the results of ab initio molecular calculations is presented. The program allows the generation of different one-, two-, and three-dimensional grids for further graphical representation or numerical analysis. Other options like extracting separate atom contributions to the function computed or locating maximum and minimum values are also implemented. A number of illustrative applications regarding different ρ(r)-dependent functions are presented and the performance and portability of the program is discussed. 相似文献