Noise analysis of an electro-optic sensor system

Optical Review - This paper describes the noise analysis of an electro-optic (EO) sensor system based on experimental and simulation results. We developed a polarization simulator of the EO sensor...     

Single-pulse stimulated Raman scattering spectroscopy

We demonstrate the acquisition of stimulated Raman scattering spectra with the use of a single femtosecond pulse. High-resolution vibrational spectra are obtained by shifting the phase of a narrow band of frequencies within the input pulse spectrum, using spectral shaping. The vibrational lines are resolved via amplitude features formed in the spectrum after interaction with the sample. Using this technique, low-frequency Raman lines (<100 cm?1) are observed on both the Stokes and anti-Stokes sides.     

On Uniform Connectedness in Nearness Frames

The concept of uniform connectedness is introduced into the theory of nearness frames. Various equivalent conditions of this concept are presented in this setting.     

Non-Expansive Hashing

non-expansive hashing scheme, similar inputs are stored in memory locations which are close. We develop a non-expansive hashing scheme wherein any set of size from a large universe may be stored in a memory of size (any , and ), and where retrieval takes operations. We explain how to use non-expansive hashing schemes for efficient storage and retrieval of noisy data. A dynamic version of this hashing scheme is presented as well. Received: February 5, 1996     

ToF-SIMS characterisation of diterpenoic acids after chromatographic separation

Microcolumn liquid chromatography (μHPLC) coupled on-line with time of flight secondary ion mass spectrometry (ToF-SIMS) was applied for mixture of diterpenoic acids (abietic, gibberellic and kaurenoic) analysis. Chromatographic effluent, with analytes separated, was carried out directly onto different, ToF-SIMS compatible surface substrates, for further ToF-SIMS analysis. Silica gel Si₆₀, aluminium backplate modified Si₆₀, monolithic silica gel and Raman spectroscopy chromatographic thin layers were used as the deposition substrates in this experiment. By ToF-SIMS surface imaging the deposition trace picture has been obtained. Effluent deposition surface area was scanned for diterpenoic acid fragment mass values based on mass spectrometric library. Measured ToF-SIMS dataset of fragment abundance and intensities were used for preliminary fragmentation schemes construction. The lowest substrate background activity has been established for monolithic silica gel thin layer and aluminium backplate modified Si₆₀ thin layer. In the case of Raman spectroscopy pre-treated thin layer or conventional chromatographic thin layer Si₆₀, the both, high background signal intensity and impossibility to construct negative ions surface image, were observed. Diterpenoic acids studied serve the similar mass spectrum but ToF-SIMS coupled with liquid chromatographic separation brings new impact to the positive identification of analytes studied.     

On countable connected locally connected almost regular Urysohn spaces

We construct connected, locally connected, almost regular, countable, Urysohn spaces. This answers a problem of G.X. Ritter. We show that there are 2^c such non-homeomorphic spaces. We also show that there are 2^c non-homeomorphic spaces which are further rigid. We discuss the group of homeomorphisms of such spaces.The following question was raised by G.X. Ritter: Does there exist a countable connected locally connected Urysohn space which is almost regular? We answer this question in the affirmative and in fact, show that not only are there as many as 2^c such spaces but that there are just as many rigid spaces with the same properties. Furthermore we show that every countable Urysohn space is a subspace of such a space. We also prove that every countable group is isomorphic to the group of autohomeomorphisms of some connected locally connected almost regular Urysohn space. Examples are given of groups of order c which can be represented in this manner.     

Linear cover time is exponentially unlikely

We show that the probability that a simple random walk covers a finite, bounded degree graph in linear time is exponentially small. We conjecture that the same holds for any simple graph.     

Multiple-scattering approach to Sn L3-edge X-ray absorption near-edge structure (XANES) analyses for organic tin compounds

We apply multiple-scattering calculations to the analyses of Sn L₃-edge X-ray absorption near-edge structure (XANES) spectra for environmental organotin compounds such as SnCl_4−nMe_n, SnCl_4−nBt_n, and SnCl_4−nPh_n (n = 0–4) where Me = CH₃, Bt = C₄H₉, and Ph = C₆H₅. The XANES peak at 3960 eV has rich information on the local structure. Referring to the optimized structures by density functional theory (DFT) calculations, multiple-scattering calculations well explain the observed spectral changes for different “organic extents”. The present study also supports the widely-used semiempirical rule called ‘Natoli’s rule’ for these environmental compounds, which will be useful to use XANES spectra for the practical analytical tools.     

Preparation of pH-sensitive liposomes retaining SOD mimic and their anticancer effect

We prepared an anticancer drug based on a pH-sensitive liposome retaining Fe-porphyrin as an SOD mimic. The liposomes contained cationic/anionic lipid combinations and were composed of Fe-porphyrin, 1,2-dimyristoyl-sn-glycero-3-phosphatidylcholine, dimethylditetradecylammonium bromide, sodium oleate, and Tween-80. The Fe-porphyrin was released from the liposome at low pH, and the cytotoxicity for cancer cells by the liposome depended on the acidic environments of the endosomes in the cells. Furthermore, although the liposome exhibited an excellent anticancer effect on a gastric cancer cell line, the SOD activity of Fe-porphyrin was shown to have a significant influence on the cytotoxicity toward cancer cells. These findings suggest that the pH-sensitive liposome retaining the Fe-porphyrin as an SOD mimic promises to be a novel anticancer drug for endosomal escape.