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21.
22.
The emission frequency of a diode laser submitted to a frequency-dependent optoelectronic feedback is observed to have more than one stable operation point together with a stable power emission. This is, to our knowledge, the first observation of bistability exclusively in the frequency of an optical system. The experiment was carried out with a semiconductor laser coupled to the cesium D2 line by an orthogonally polarized frequency-sensitive optical feedback. 相似文献
23.
Control of the efficiency of photoisomerization by oxygen was demonstrated for 1,3,5-tristyrylbenzene dendrimers 1-3; the large dendrons do not significantly affect the photochemistry itself due to volume-conserving isomerization mechanisms but may affect the mobility of the molecules. 相似文献
24.
Gil Markovich Stuart Pollack Rina Giniger Ori Cheshnovsky 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,26(1):98-100
We have measured the photoelectron-spectra of I? (H2O)n clusters in the size range n=1–60. We have found that the first six water molecules form a solvation layer with an average 0.35 eV electrostatic stabilization of the anion. At larger cluster sizes the electrostatic stabilization of water does not fit a continuous dielectric solvent. The most stable structures of the clusters consist of internally solvated anions. In the size range n=34–40 we have found evidence for existence of cluster structures with surface solvated anions. 相似文献
25.
Emission decays of triplet metal-to-ligand charge transfer states in anisotropic crystals of [Ru(1 - x)Os(x)(bpy)(3)]X(2) (bpy = 2,2'-bipyridine, X = PF(6)-, ClO(4)-, SbF(6)-, and 0.115 > x > 0.001) at approximately 300 K were measured by means of time-correlated single-photon counting. Rates of excitation hopping calculated on the basis of an interaction between transition dipoles of a donor cation and an acceptor cation are insufficient to simulate the single-exponential decays (x = 0.0099) and the multiexponential decays (x = 0.060 and 0.115) of the PF(6)- salt crystals. A limiting rate of excitation hopping to an imaginary cation at the van der Waals distance via a super-exchange interaction between d orbitals through the bpy ligands was determined to be 0.83 x 10(10) s(-1) on average by means of a step-by-step Monte Carlo simulation, assuming an distance-attenuation factor, beta, of the exchange interaction of 10 nm-1. The total rate of excitation hopping via both a dipole-dipole mechanism and a super-exchange mechanism to the neighboring sites of the cation was calculated to be 5.4 x 10(9) s(-1) for the PF(6)- crystal. Anisotropic diffusion constants estimated from the hopping rates and lengths in the PF(6)- crystal are 9.3 x 10(-6), 9.1 x 10(-6), and 1.4 x 10(-6) cm(2)s(-1) along the a axis, the b axis, and the c axis, respectively, which are compared with an isotropic diffusion constant, 1.3 x 10(-6) cm(2) s(-1), estimated from the pseudo-bimolecular rate constant of excitation transfer to [Os(bpy)(3)](2+), using an isotropic Smoluchowski equation. A multiexponential emission decay of [Ru(0.885)Os(0.115)(bpy)(3)](PF(6))(2) was also simulated to determined the limiting rate of excitation transfer to [Os(bpy)(3)](2+) at the van der Waals distance (2.6 x 10(11) s(-1)). The magnitude of beta determined is 6.5 and 11.5 nm(-1) for the ClO(4)- and the SbF(6)- salt crystals, respectively, on reference to that of beta (10 nm(-1)) for the PF(6)- salt crystal. 相似文献
26.
Ladislav Halás Andrej Oriňák Abubaker Sharif Monika Ádámová Juraj Ladomerský 《Central European Journal of Chemistry》2005,3(3):570-582
Acrylate monomers methylmethacrylate (MMA) and cyclohexylmethacrylate (CHMA) bioaccumulation has been determined in aquatic
organism, algae (Chlorella kessleri). Algae were collected in amount of 0.4 mg and directly injected to the pyrolytical cell. In algae bodies accumulated monomers
were analysed by pyrolysis gas chromatography (Py-GC) and pyrolysis gas chromatography coupled with mass spectrometry (Py-GC/MS).
Traces of the accumulated monomers in algae body can be determined after 1-, 2-, 3-weeks of incubation. Maximum content of
MMA was determined after 3-week of experiment, contrariwise in the case of CHMA after 2-week exposition. Relationship with
pyrolysis temperature has also been studied. 相似文献
27.
Takuya Akatsuka Mayuko Ushiro Shin-ichi Nagamatsu Yoshio Takahashi Takashi Fujikawa 《Polyhedron》2008,27(14):3146-3150
We apply multiple-scattering calculations to the analyses of Sn L3-edge X-ray absorption near-edge structure (XANES) spectra for environmental organotin compounds such as SnCl4−nMen, SnCl4−nBtn, and SnCl4−nPhn (n = 0–4) where Me = CH3, Bt = C4H9, and Ph = C6H5. The XANES peak at 3960 eV has rich information on the local structure. Referring to the optimized structures by density functional theory (DFT) calculations, multiple-scattering calculations well explain the observed spectral changes for different “organic extents”. The present study also supports the widely-used semiempirical rule called ‘Natoli’s rule’ for these environmental compounds, which will be useful to use XANES spectra for the practical analytical tools. 相似文献
28.
Rachel Atzmon Ori Cheshnovsky Baruch Raz Joshua Jortner 《Chemical physics letters》1974,29(3):310-313
We report an experimental study of Xe(3P1) → Xe(3P2) electronic quenching by Ar in Xe/Ar mixtures optically excited by the 1470 Å line of Xe. The quenching process was monitored by the observation of the Xe*2 second emission continuum at low Xe pressures. 相似文献
29.
Conditions for bromination at the C3 and C5 positions of a 1,4-dihydropyridine (DHP) were investigated. The effect of base concentration, base type, reaction temperature, and solvent were examined. DHP derivatives with ester and amide moieties were synthesized and brominated. The bromine atoms can be replaced by other substituents, utilizing Suzuki cross coupling. 相似文献
30.
Tominaga Mai Okajima Mei Yamagishi Mayuko Shinagawa Mitsuru Katsuyama Jun Matsumoto Yoshinori Tomosada Nobuhiro 《Optical Review》2021,28(6):704-715
Optical Review - This paper describes the noise analysis of an electro-optic (EO) sensor system based on experimental and simulation results. We developed a polarization simulator of the EO sensor... 相似文献