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61.
62.
A. I. Bulavchenko A. A. Sap’yanik M. G. Demidova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(3):509-514
Stable organosols of cadmium sulfide are obtained via the ion exchange reaction of cadmium nitrate with sodium sulfide in reversed micellar solutions of Brij-30 in n-decane and are characterized by means of spectrophotometry, luminescence, photon correlation spectroscopy (PCS), and transmission electron microscopy (TEM). It is established that adding anionic surfactant AOT to organosols produces double electric layers on the surfaces of nanoparticles and contributes to an additional 50-fold electrophoretic concentration. Electrophoretic concentrates of cadmium sulfide nanoparticles (0.5 M) are obtained in cells with vertical orientation of the electrodes and periodic changes in polarity. The average diameter of the nanoparticles according to TEM data is 5 nm, considerably less than the hydrodynamic diameter found by PCS (70 nm), testifying to the complex structure of a mixed adsorption layer surrounding a nanoparticle. 相似文献
63.
Zeynep Cetecioglu Bahar Ince Samet Azman Orhan Ince 《Applied biochemistry and biotechnology》2014,172(2):631-640
Five hundred tons of antibiotics are consumed yearly in the world. In this study, the biodegradation characteristics of tetracycline (TET) under nitrate-reducing, sulfate-reducing, and methanogenic conditions were determined by batch tests. Also, effects of TET on mixed microbial cultures were revealed by microbiological analysis. In this scope, gas generation and composition, dissolved organic carbon, and electron acceptor concentrations were monitored during 120 days. Additionally, changes on quantities of specific microbial groups were determined by Q-PCR. TET showed non-biodegradable behavior under nitrate- and sulfate-reducing conditions, whereas slightly biodegradable behavior under methanogenic conditions approximately 46 % degradation. The effects of TET on the abundance of mixed culture varied according to taxonomic units. Sulfate-reducing bacteria were inhibited by TET, while archaeal, bacterial, and methanogenic populations were not affected significantly. 相似文献
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65.
Günseli Turgut Metin Zora Mustafa Odabaolu Cem Cüneyt Ersanl Orhan Büyükgüngr 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(5):o321-o323
The crystal structure of the title compound, C2H10N2O2+·2Cl−, is built up from one 2‐hydroxyethylhydrazinium(2+) cation and two Cl− anions. The molecular structure is stabilized by O—H⋯Cl and N—H⋯Cl hydrogen bonds. The crystal structure is stabilized by one N—H⋯O and three N—H⋯Cl interactions, and the three‐dimensional network of hydrogen bonds stabilizes the crystal packing. All five hydrazinium H atoms are involved in hydrogen bonds to Cl− anions. The Cl⋯H contact distances range from 2.122 (15) to 2.809 (14) Å. 相似文献
66.
Fatma Tezcan Hümeyra Paaolu Okan Z. Yeilel Halis
lmez Hasan Ibudak Orhan Büyükgüngr 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(7):m335-m337
In the crystal structure of the title compound, [Ni(C6H6N2O)2(H2O)2](C7H4NO3S)2·4H2O or [Ni(pia)2(H2O)2](sac)2·4H2O (pia is picolinamide or pyridine‐2‐carboxamide, and sac is the saccharinate anion), the Ni2+ cation, located on a centre of symmetry, is coordinated by two symmetry‐related aqua ligands together with a pair of symmetry‐related bidentate pia molecules and exhibits a distorted octahedral environment. The unique unligated sac anion in the asymmetric unit resides on a general position and has a single negative charge. The coordinated water molecules link the sac ions to the metal complex via O—H⋯O hydrogen bonds. In addition, the sac ions are linked to the metal complex via intermolecular π–π interactions between the benzene ring of the sac ion and the pyridine ring of a pia ligand. Each uncoordinated water molecule is hydrogen bonded to sac moieties through O—H⋯O and O—H⋯N hydrogen bonds. 相似文献
67.
Güneş Süheyla Kürkçüoğlu Dr. Okan Zafer Yeşilel Ilkan Kavlak Orhan Büyükgüngör 《无机化学与普通化学杂志》2009,635(1):175-178
The heteronuclear polymeric complex, [Zn(teta)Ni(μ‐CN)2(CN)2]n (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT‐IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P21/c and in which the ZnII ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the NiII ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30–600 °C in the static air atmosphere. 相似文献
68.
69.
Cengiz Yenikaya Mehmet Poyraz Musa Sar Fatih Demirci Halil lkimen Orhan Büyükgüngr 《Polyhedron》2009,28(16):3526-3532
A novel bridged binuclear Cu(II) complex with mixed ligands, di-μ-(2-aminopyridine(N,N′))-bis[(2,6-pyridinedicarboxylate)aquacopper(II)] tetrahydrate, formulated as [Cu(μ-ap)(dipic)(H2O)]2·4H2O (1) (dipic = 2,6-pyridinedicarboxylate, ap = 2-aminopyridine), has been synthesized and characterized by elemental, spectral (IR and UV–Vis.), thermal analysis, magnetic measurements and single crystal X-ray diffraction analysis. The central Cu(II) ion resides on a centre of symmetry in a distorted square-pyramid coordination environment comprising of two N atoms, one from dipic and one from the ap ring, two carboxylate O atoms from dipic, and one O atom from water. Intermolecular N–HO and O–HO hydrogen bonds and π–π stacking interactions seem to be effective in the stabilization of the crystal structure. The free ligands and the complex were also evaluated for their antimicrobial and radical scavenging activities (DPPH = 1,1-diphenyl-2-picrylhydrazyl hydrate) using in vitro microdilution methods. Antimicrobial screening of the free ligands and their complex showed that the free ligands and the complex possess antifungal activity against Candida sp. 相似文献
70.
Orhan Destanoğlu 《液相色谱法及相关技术杂志》2016,39(9):465-474
The first aim of this study was to develop a selective, sensitive, and reliable method for direct simultaneous determination of cyanate, thiocyanate, and hexavalent chromium by ion chromatography (IC) with conductivity detection. The other target was to successfully determine cyanides by utilizing same chromatographic system. Yet, since cyanides can not be detected by the direct method, free cyanide ions were converted into cyanate with chloramine-T at alkaline pH. In addition, strongly complexed metal cyanides were converted into cyanate by using photo-oxidation following chloramine-T. Total cyanate ion obtained from developed methods were analyzed with IC. The chromatographic separations on anion exchange column were accomplished by optimized multistep gradient eluent program using NaOH as the eluent. Proposed method was applied for the simultaneous determination of cyanide and hexavalent chromium in electroplating bath solutions and in industrial wastewater. Cyanide and hexavalent chromium could be measured in the linear dynamic ranges of 0.6–961.5 and 0.9–118.5 µmol L?1, respectively. The limit of detection and limit of quantification of cyanide were 0.18 and 0.61 µmol L?1, and these values for chromium(VI) were 0.26 and 0.86 µmol L?1, respectively. 相似文献