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41.
考虑了Kantorovich-Vertesi有理插值型算子L^*n,s(f,X,x)对L^p[-1,1](1≤p≤∞)空间函数逼近的Jackson型估计。并获得了如下逼近阶:‖L^*n,s(f,X,x)-f(x)‖L^p[-1,1]≤Cp,sw(f,1/n 2)L^p[-1,1] (s>2)。 相似文献
42.
43.
The dataflow language Lucid applies concepts from intensional logic to declarative ISWIM expressions which are intensionalised
relative to the dimension of time, thus introducing the notion of an expression’s history. Lucian, a language derived from
Lucid, embeds dataflow into object-orientation allowing the intensionalisation of objects. Lucian introduces the notion of
a declarative intensional object as the history of an object’s transformations. This paper discusses the embedding relationships
and semantics of conjoining the dataflow and object-oriented paradigms to provide the language Lucian for defining intensional
objects.
相似文献
44.
45.
中低变质程度煤显微组分结构的13 C-NMR研究 总被引:5,自引:1,他引:4
利用13C-NMR核磁共振技术对中低变质程度煤显微组分(镜质组和惰质组)的分子结构进行了研究,计算了5种煤9个显微组分的13C-NMR结构参数,获得了样品的结构特征及变化规律。结果表明,惰质组结构中芳构化程度要高于镜质组;脂碳数量则少于镜质组,芳环上的烷烃侧链也没有镜质组长;随着煤变质程度的提高,煤分子中芳构化程度不断提高,但惰质组的芳香度随变质程度变化的规律明显不如镜质组;在中低变质阶段,对煤化进程起主导作用的的是芳构化作用而不是环缩合作用,但在惰质组中脂碳断裂形成芳环的现象不明显。惰质组中含氧官能团的总量要低于同等变质程度的镜质组。 相似文献
46.
KM Clauwaert Van Bocxlaer JF HJ Major JA Claereboudt WE Lambert Van den Eeckhout EM Van Peteghem CH De Leenheer AP 《Rapid communications in mass spectrometry : RCM》1999,13(14):1540-1545
This paper describes the investigation of the potential of a quadrupole orthogonal acceleration time-of-flight mass spectrometer (Q-TOF) equipped with an atmospheric pressure ionisation interface for quantitative measurements of small molecules separated by reversed phase liquid chromatography. To this end, the detection limits and linear dynamic range in particular were studied in an LC/MS/MS experiment using 3,4-methylenedioxymethamphetamine standards and 3,4-methylenedioxyethylamphetamine for internal standardisation. In a second phase, the experiment was repeated with real biological extracts (whole blood, serum, and vitreous humour). A calibration for 3,4-methylenedioxymethamphetamine and its metabolite 3,4-methylenedioxyamphetamine was prepared in each of these matrices again using 3,4-methylenedioxyethylamphetamine as internal standard. The resulting quantitative data were compared with those obtained by liquid chromatography with fluorescence detection for the same extracts. The Q-TOF results revealed excellent sensitivity and a linear dynamic range of nearly four decades (2-10 000 pg on-column, r(2) = 0.9998, 1/x weighting). Furthermore, all the calibration curves prepared in biological material were superimposable, LC/MS/MS and LC-fluorescence, and the quantitative results for actual samples compared very favourably. It was concluded that the Q-TOF achieves a linear dynamic range for quantitative LC/MS/MS work exceeding that of fluorescence detection and at much better absolute sensitivity. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
47.
Metal 4d photoelectron spectra of the lanthanoid oxides Ln2O3 are reported. The 4d signals are complex, showing subsidiary structure due both to electrostatic interactions within the 4d94?n configurations and to accompanying O 2p → Ln 4? charge-transfer excitations (shake-up). The effects of electrostatic coupling, including configuration interaction in the final state, are analysed in terms of a simple model. 相似文献
48.
R.G. Egdell I. Fragala A.F. Orchard 《Journal of Electron Spectroscopy and Related Phenomena》1978,14(6):467-475
Vapour-phase He I and He II photoelectron spectra of the cyclopentadienides of indium(I) and thallium(I) are reported. The discussion concentrates on the implications of the changes in band intensity that are observed on switching from He I to He II excitation, and on the nature of the additional structure revealed in the He II spectra. 相似文献
49.
P. S. Holden G. A. J. Orchard I. M. Ward 《Journal of Polymer Science.Polymer Physics》1985,23(4):709-731
Measurements of permeability and diffusivity have been undertaken for the gases helium and oxygen in a range of highly oriented polyethylene films. The solubilities deduced for both gases are proportional to the amorphous volume fraction, showing that the noncrystalline regions are the transport medium in all instances. The changes in diffusion coefficient are more complex. A large reduction in diffusion coefficient is observed with increasing draw ratio, and this is particularly marked in the case of the larger oxygen molecule, where significant differences are also observed for different grades of polymer and different drawing conditions. These changes in diffusion coefficient are discussed in the light of previous studies of diffusion in polymers and present knowledge of the changes in structure produced by drawing. 相似文献
50.